Partial pressure (or fugacity) of carbon dioxide, dissolved inorganic carbon, pH, alkalinity, temperature, salinity and other variables collected from Surface underway, discrete sample and profile observations using Alkalinity titrator, CTD and other instruments from PELICAN in the Coastal Waters of Louisiana, Coastal Waters of Texas and Gulf of Mexico from 2013-09-09 to 2013-09-22 (NCEI Accession 0157461)
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title: Partial pressure (or fugacity) of carbon dioxide, dissolved inorganic carbon, pH, alkalinity, temperature, salinity and other variables collected from Surface underway, discrete sample and profile observations using Alkalinity titrator, CTD and other instruments from PELICAN in the Coastal Waters of Louisiana, Coastal Waters of Texas and Gulf of Mexico from 2013-09-09 to 2013-09-22 (NCEI Accession 0157461)
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Anchor: https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/person/details/5154 Joseph E. Salisbury
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abstract: This dataset includes Surface underway, chemical, discrete sample, meteorological, physical and profile data collected from PELICAN in the Coastal Waters of Louisiana, Coastal Waters of Texas and Gulf of Mexico from 2013-09-09 to 2013-09-22. These data include BAROMETRIC PRESSURE, CONDUCTIVITY, DISSOLVED INORGANIC CARBON (DIC), Partial pressure (or fugacity) of carbon dioxide - atmosphere, Partial pressure (or fugacity) of carbon dioxide - water, SALINITY, TOTAL ALKALINITY (TA), WATER TEMPERATURE and pH. The instruments used to collect these data include Alkalinity titrator, CTD, Carbon dioxide (CO2) gas analyzer, Non-dispersive infrared (NDIR) dissolved inorganic carbon (DIC) analyzer, Shower head chamber equilibrator for autonomous carbon dioxide (CO2) measurement, bottle and pH sensors. These data were collected by Antonio Mannino of US NASA; Goddard Space Flight Center and Dr. Joseph Salisbury and Christopher Hunt of University of New Hampshire as part of the Coastal_GOMEX2013_BOT and Coastal_GOMEX2013_UW data set. CDIAC associated the following cruise ID(s) with this data set: 32PE20130909 and GOMEX2013 The Global Coastal Carbon Data Project data includes the bottle (discrete) and surface (underway) carbon-related measurements from coastal research cruises, the data from time series cruises and coastal moorings. The coastal regions data are very important for the understanding of carbon cycle on the continental margins.
purpose: This dataset is available to the public for a wide variety of uses including scientific research and analysis.
credit: Funding Information: NASA NNX13AM38G
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Anchor: https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/datatype/details/38 BAROMETRIC PRESSURE
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title: Global Change Master Directory (GCMD) Location Keywords
date: (CI_Date)
date: 2023
dateType: (CI_DateTypeCode) revision
edition: 17
citedResponsibleParty: (CI_ResponsibleParty)
organisationName: Earth Science Data and Information System, Earth Science Projects Division, Goddard Space Flight Center (GSFC), National Aeronautics and Space Administration (NASA)
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city: Greenbelt
administrativeArea: MD
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linkage: https://forum.earthdata.nasa.gov/app.php/tag/GCMD%2BKeywords
protocol: HTTPS
name: GCMD Keyword Forum Page
description: Global Change Master Directory (GCMD). 2023. GCMD Keywords, Version 17. Greenbelt, MD: Earth Science Data and Information System, Earth Science Projects Division, Goddard Space Flight Center (GSFC), National Aeronautics and Space Administration (NASA). URL (GCMD Keyword Forum Page): https://forum.earthdata.nasa.gov/app.php/tag/GCMD+Keywords
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descriptiveKeywords: (MD_Keywords)
keyword: Gulf of Mexico
type: (MD_KeywordTypeCode) place
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title: Provider Geographic Names
date: (inapplicable)
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otherConstraints: Cite as: Salisbury, Joseph E.; Hunt, Christopher W.; Mannino, Antonio (2016). Partial pressure (or fugacity) of carbon dioxide, dissolved inorganic carbon, pH, alkalinity, temperature, salinity and other variables collected from Surface underway, discrete sample and profile observations using Alkalinity titrator, CTD and other instruments from PELICAN in the Coastal Waters of Louisiana, Coastal Waters of Texas and Gulf of Mexico from 2013-09-09 to 2013-09-22 (NCEI Accession 0157461). [indicate subset used]. NOAA National Centers for Environmental Information. Dataset. https://doi.org/10.25921/9hjg-m865. Accessed [date].
resourceConstraints: (MD_LegalConstraints)
useLimitation: Distribution liability: NOAA and NCEI make no warranty, expressed or implied, regarding these data, nor does the fact of distribution constitute such a warranty. NOAA and NCEI cannot assume liability for any damages caused by any errors or omissions in these data. If appropriate, NCEI can only certify that the data it distributes are an authentic copy of the records that were accepted for inclusion in the NCEI archives.
resourceConstraints: (MD_LegalConstraints)
accessConstraints: (MD_RestrictionCode) otherRestrictions
otherConstraints: Use liability: NOAA and NCEI cannot provide any warranty as to the accuracy, reliability, or completeness of furnished data. Users assume responsibility to determine the usability of these data. The user is responsible for the results of any application of this data for other than its intended purpose.
aggregationInfo: (MD_AggregateInformation)
aggregateDataSetName: (CI_Citation)
title: Salisbury, J., C. Hunt and A. Mannino (2015). Discrete and surface CO2 data obtained during the R/V Pelican GOMEX2013 cruise in the Gulf of Mexico (September 9 - 22, 2013). Carbon Dioxide Information Analysis Center, Oak Ridge National Laboratory, Oak Ridge, Tennessee, Coastal_GOMEX2013_BOT, Coastal_GOMEX2013_UW.
date: (CI_Date)
date: 2015
dateType: (CI_DateTypeCode) publication
identifier: (MD_Identifier)
code: Coastal_GOMEX2013_BOT
identifier: (MD_Identifier)
code: Coastal_GOMEX2013_UW
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individualName: Salisbury, J., C. Hunt and A. Mannino
role: (CI_RoleCode) author
citedResponsibleParty: (CI_ResponsibleParty)
organisationName:
Anchor: https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/institution/details/179 Carbon Dioxide Information Analysis Center (CDIAC)
contactInfo: (CI_Contact)
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linkage: http://cdiac.ornl.gov
protocol: HTTP
name: Carbon Dioxide Information Analysis Center website
description: Institution web page
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series: (CI_Series)
name: Ocean CO2
otherCitationDetails: [retrieved from https://cdiac.ess-dive.lbl.gov/ftp/oceans/GOMEX2013/]
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title: NOAA National Centers for Environmental Information (2022). Ocean Carbon and Acidification Data System (OCADS). NOAA National Centers for Environmental Information. https://www.ncei.noaa.gov/products/ocean-carbon-acidification-data-system
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date: 2022-04
dateType: (CI_DateTypeCode) publication
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linkage: https://www.ncei.noaa.gov/products/ocean-carbon-acidification-data-system
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description: OCADS website
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Anchor: https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/institution/details/1730 NOAA National Centers for Environmental Information
role: (CI_RoleCode) author
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Anchor: https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/institution/details/1730 US DOC; NOAA; NESDIS; National Centers for Environmental Information (NCEI)
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otherCitationDetails: [accessed 2024-02-08]
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language:
LanguageCode: eng; USA
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topicCategory: (MD_TopicCategoryCode) environment
topicCategory: (MD_TopicCategoryCode) oceans
topicCategory: (MD_TopicCategoryCode) climatologyMeteorologyAtmosphere
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westBoundLongitude: -94.979
eastBoundLongitude: -89.257049
southBoundLatitude: 28.052969
northBoundLatitude: 29.83465
temporalElement: (EX_TemporalExtent)
extent:
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beginPosition: 2013-09-09
endPosition: 2013-09-22
supplementalInformation: These data were acquired by NCEI from the Carbon Dioxide Information Analysis Center (CDIAC) in accordance with an archival submission agreement between CDIAC and NCEI.
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distributionInfo: (MD_Distribution)
distributor: (MD_Distributor)
distributorContact: (CI_ResponsibleParty)
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Anchor: https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/institution/details/1730 NOAA National Centers for Environmental Information
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address: (CI_Address)
electronicMailAddress: NCEI.Info@noaa.gov
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distributionOrderProcess: (MD_StandardOrderProcess)
fees: In most cases, electronic downloads of the data are free. However, fees may apply for custom orders, data certifications, copies of analog materials, and data distribution on physical media.
orderingInstructions: Contact NCEI for other distribution options and instructions.
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linkage: https://doi.org/10.25921/9hjg-m865
protocol: HTTPS
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description: Navigate directly to the URL for a descriptive web page with download links.
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linkage: https://www.ncei.noaa.gov/archive/accession/oas/157461
protocol: HTTPS
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description: Navigate directly to the URL for a descriptive web page with download links.
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linkage: https://www.ncei.noaa.gov/archive/accession/download/157461
protocol: HTTPS
applicationProfile: Web browser
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description: Navigate directly to the URL for data access and direct download.
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linkage: ftp://ftp-oceans.ncei.noaa.gov/nodc/archive/arc0101/0157461/
protocol: FTP
applicationProfile: Any FTP client
name: FTP
description: These data are available through the File Transfer Protocol (FTP). FTP is no longer supported by most internet browsers. You may copy and paste the FTP link to the data into an FTP client (e.g., FileZilla or WinSCP).
function: (CI_OnLineFunctionCode) download
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dataQualityInfo: (DQ_DataQuality)
scope: (DQ_Scope)
level: (MD_ScopeCode) dataset
lineage: (LI_Lineage)
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description: NCEI Accession 0157461 v1.1 was published.
dateTime:
DateTime: 2016-12-11T19:59:09Z
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title: NCEI Accession 0157461 v1.1
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linkage: https://www.ncei.noaa.gov/archive/accession/0157461/1.1
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name: NCEI Accession 0157461 v1.1
description: published 2016-12-11T19:59:09Z
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dataQualityInfo: (DQ_DataQuality)
scope: (DQ_Scope)
level: (MD_ScopeCode) dataset
lineage: (LI_Lineage)
processStep: (LE_ProcessStep)
description: Parameter or Variable: Dissolved Inorganic Carbon; Abbreviation: DIC; Observation type: discrete; In-situ / Manipulation / Response variable: In-situ observation; Measured or calculated: Calculated; Detailed sampling and analyzing information: DIC of unfiltered water was determined using an automated analyzer built by Apollo SciTech (Bogart, GA). Immediately after opening the sample bottle, a digital syringe withdrew a small amount of sample (0.5 mL), acidified it with 10 % phosphoric acid and subsequently measured the evolved CO2 with a Li-Cor 6262 non-dispersive infrared gas analyzer (similar to the method described by Cai and Wang 1998).; Standardization description: Certified seawater reference materials from Dr. A. Dickson were used to determine DIC concentration by preparing a calibration curve covering the range of DIC from 200 to 2000 μmol kg−1 (Dickson et al. 2003), with a resulting precision ranging from 0.05 to 0.5 % (or 0.1-10 μmol kg−1), with an average of ∼0.1 % (2 μmol kg−1).; CRM batch number: 131 136.
processStep: (LE_ProcessStep)
description: Parameter or Variable: Total alkalinity; Abbreviation: TA; Observation type: discrete; In-situ / Manipulation / Response variable: In-situ observation; Measured or calculated: Measured; Type of titration: Gran; Cell type (open or closed): open; Curve fitting method: AT and pH of unfiltered water were simultaneously measured by the same instrument (Apollo SciTech AS-2), and thus pH and AT measurements are both based on the same pH electrode. The pH electrode used in the AT titration (Orion 3-Star, Thermo Fisher Inc.) was calibrated using three low ionic strength pH buffers certified on the U.S. National Bureau of Standards (NBS) scale to ±0.01, and the initial reading before the addition of acid titrant was taken as the sample pHNBS (pH on the NBS scale, hereafter simply referred to as pH). AT was measured by Gran titration (Gran 1952) with 0.1 N HCl using an automated titrator. This method adds an initial aliquot of acid to the sample in an open cell, generally lowering the sample pHNBS below 3, and then adds subsequent aliquots of titrant until the pHNBS changes linearly with the volume of acid added. The AT endpoint is then obtained from linear regression of the change of pHNBS against the volume of acid added, according to a Gran transformation.; Uncertainty: Multiple analyses of the Dickson reference material resulted in a calculated precision of this method of about 0.1 % (or ∼±2 μmol kg−1). The accuracy of the AT automated system, also calibrated with multiple batches of the Dickson CRM as discussed above, was ±3-4 μmol kg−1; Method reference: DOE (U.S. Department of Energy). 1994. Handbook of Methods for the Analysis of the Various Parameters of the Carbon Dioxide System in Seawater. Version 2.0. ORNL/CDIAC-74. Ed. A. G. Dickson and C. Goyet. Carbon Dioxide Information Analysis Center, Oak Ridge National Laboratory, Oak Ridge, Tenn. Gran, G. 1952. Determination of the equivalence point in potentiometric titrations. Part II. Analyst 77: 661-671 Hunt, C.W., J.E. Salisbury and D. Vandemark. (2013) CO2 Input Dynamics and Air-Sea Exchange in a Large New England Estuary. Estuaries and Coasts 37(5): 1078-1091..
processStep: (LE_ProcessStep)
description: Parameter or Variable: pH; Abbreviation: pH; pH scale: NBS; Observation type: discrete; In-situ / Manipulation / Response variable: In-situ observation; Measured or calculated: Measured; Temperature of pH measurement: 24.4; Detailed sampling and analyzing information: Orion 3-Star, Thermo Fisher Inc..
processStep: (LE_ProcessStep)
description: Parameter or Variable: CTDTMP; Abbreviation: CTDTMP; Unit: DEG_C; Controlled vocabulary name: WATER TEMPERATURE; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: CTDSAL; Abbreviation: CTDSAL; Controlled vocabulary name: SALINITY; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: ALKALI; Abbreviation: ALKALI; Unit: UMOL/KG; Controlled vocabulary name: total alkalinity; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: PH_NBS; Abbreviation: PH_NBS; Unit: @24.4 Deg C; Controlled vocabulary name: pH; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: TCARBN; Abbreviation: TCARBN; Unit: UMOL/KG; Controlled vocabulary name: DISSOLVED INORGANIC CARBON (DIC); In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: SHIP_DIR; Abbreviation: SHIP_DIR; Unit: DEG; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: SHIP_SPEED; Abbreviation: SHIP_SPEED; Unit: M/C; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: SSS; Abbreviation: SSS; Unit: Sea surface salinity; Controlled vocabulary name: SALINITY; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: ATM_PRE; Abbreviation: ATM_PRE; Unit: MBAR; Controlled vocabulary name: BAROMETRIC PRESSURE; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: FCO2_WAT; Abbreviation: FCO2_WAT; Unit: UATM; Controlled vocabulary name: partial pressure of carbon dioxide - water; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: FCO2_AIR; Abbreviation: FCO2_AIR; Unit: UATM; Controlled vocabulary name: Partial pressure (or fugacity) of carbon dioxide - atmosphere; In-situ / Manipulation / Response variable: in-situ .
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metadataMaintenance: (MD_MaintenanceInformation)
maintenanceAndUpdateFrequency: (MD_MaintenanceFrequencyCode) asNeeded
maintenanceNote: Metadata are developed, maintained and distributed by NCEI. Updates are performed as needed to maintain currentness.
contact: (CI_ResponsibleParty)
organisationName: NOAA National Centers for Environmental Information
role: (CI_RoleCode) custodian
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acquisitionInformation: (MI_AcquisitionInformation)
instrument: (MI_Instrument)
identifier: (MD_Identifier)
code: bottle
type: bottle
description: any type of water bottle sampling device Generic name for water collection device; usually used to determine temperature, salinity and provide water aliquots for measurement of a wide range of parameters; often referred to by a specific type of water sampling bottle, such as a Nansen or Niskin bottle.
instrument: (MI_Instrument)
identifier: (MD_Identifier)
code: carbon dioxide (CO2) gas analyzer
type: carbon dioxide (CO2) gas analyzer
description: measures gaseous carbon dioxide Carbon dioxide gas analyzer has often been referred to as LI-COR, because a lot of researchers choose to use products manufactured by LI-COR incorporation for their carbon dioxide measurement. The main component of a carbon dioxide analyzer is a nondispersive infrared (NDIR) spectroscopic sensors to detect CO2 in a gaseous environment by its characteristic absorption. Carbon dioxide (CO2) gas analyzer works together with carbon dioxide (CO2) equilibrator (insttypes_id 184) to measure carbon dioxide in the water. To measure water carbon dioxide, water needs to be continuously supplied to a showerhead inside an equilibrator. As the water flows through the equilibrator chamber, dissolved carbon dioxide exchanges quickly with air in the headspace. This air is then sampled by the carbon dioxide analyzer to determine the mole fraction of CO2 in water.
instrument: (MI_Instrument)
identifier: (MD_Identifier)
code: CTD
type: CTD
description: Conductivity-Temperature-Depth probe
instrument: (MI_Instrument)
identifier: (MD_Identifier)
code: Non-dispersive infrared (NDIR) dissolved inorganic carbon (DIC) analyzer
type: Non-dispersive infrared (NDIR) dissolved inorganic carbon (DIC) analyzer
description: A known amount of seawater is dispensed into a stripping chamber where it is acidified and purged with an inert gas. The amount of CO2 in the resulting gas stream is determined with a non-dispersive infrared (NDIR) carbon dioxide analyzer.
instrument: (MI_Instrument)
identifier: (MD_Identifier)
code: pH sensor
type: pH sensor
description: generic meter used to measure pH Any of a class of instruments used to quantify pH in a water or other type of sample.
instrument: (MI_Instrument)
identifier: (MD_Identifier)
code: showerhead equilibrator
type: showerhead equilibrator
description: extracts dissolved CO2 from water A carbon dioxide equilibrator is usually in the shape of a vertical tube, with a showerhead on the top, some headspace, a lot of beads to increase the surface exchange area between water and air, a water seal device at the bottom to allow water to overflow, but prevents air exchange between inside and outside. Carbon dioxide (CO2) equilibrator works together with carbon dioxide (CO2) gas analyzer (insttypes_id 183) to measure carbon dioxide in the water. To measure water carbon dioxide, water needs to be continuously supplied to a showerhead inside an equilibrator. As the water flows through the equilibrator chamber, dissolved carbon dioxide exchanges quickly with air in the headspace. This air is then sampled by the carbon dioxide analyzer to determine the mole fraction of CO2 in water.
instrument: (MI_Instrument)
identifier: (MD_Identifier)
code: titrator
type: titrator
description: titrator
platform: (MI_Platform)
identifier: (MD_Identifier)
code: R/V Pelican
description: Flag: United States Title: R/V Vessel Type: Research Survey IMO: 8517009 DOB: 198505 Institution: LUMCON/UNOLS
instrument: (missing)
