{"xmlId":"78338","NOAAStudyId":"37138","studyName":"Amino Acid d13C and d15N Data from Monterey Bay, California from 1998-2004 CE","doi":"https://doi.org/10.25921/27zx-f176","uuid":"eb47d42c-bc4e-46d0-a8f9-85fad4237491","dataPublisher":"NOAA","contactInfo":{"type":"CONTACT INFORMATION","shortName":"DOC/NOAA/NESDIS/NCEI","longName":"National Centers for Environmental Information, NESDIS, NOAA, U.S. Department of Commerce ","address":"325 Broadway, E/NE31","city":"Boulder","state":"CO","postalCode":"80305-3328","country":"USA","dataCenterUrl":"https://www.ncei.noaa.gov/products/paleoclimatology","email":"paleo@noaa.gov","phone":"828-271-4800","fax":null,"constraints":"Please cite original publication, online resource, dataset and publication DOIs (where available), and date accessed when using downloaded data. If there is no publication information, please cite investigator, title, online resource, and date accessed. The appearance of external links associated with a dataset does not constitute endorsement by the Department of Commerce/National Oceanic and Atmospheric Administration of external Web sites or the information, products or services contained therein. For other than authorized activities, the Department of Commerce/NOAA does not exercise any editorial control over the information you may find at these locations. These links are provided consistent with the stated purpose of this Department of Commerce/NOAA Web site."},"dataType":"CORALS AND SCLEROSPONGES","investigators":"Shen, Y.; Guilderson, T.P.; Sherwood, O.A.; Castro, C.G.; Chavez, F.P.; McCarthy, M.D.","investigatorDetails":[{"firstName":"Yuan","lastName":"Shen","initials":"Y.","orcId":null},{"firstName":"Thomas","lastName":"Guilderson","initials":"T.P.","orcId":"0000-0001-9371-7059"},{"firstName":"Owen","lastName":"Sherwood","initials":"O.A.","orcId":"0000-0003-1055-3162"},{"firstName":"Carmen","lastName":"Castro","initials":"C.G.","orcId":null},{"firstName":"Francisco","lastName":"Chavez","initials":"F.P.","orcId":"0000-0002-0691-292X"},{"firstName":"Matthew","lastName":"McCarthy","initials":"M.D.","orcId":null}],"version":"1.0","funding":[{"fundingAgency":"US National Science Foundation","fundingGrant":"OCE 1635527"}],"studyNotes":null,"onlineResourceLink":"https://www.ncei.noaa.gov/access/paleo-search/study/37138","difMetadataLink":"https://www.ncei.noaa.gov/pub/data/metadata/published/paleo/dif/xml/noaa-coral-37138.xml","isoMetadataLink":"https://www.ncei.noaa.gov/pub/data/metadata/published/paleo/iso/xml/noaa-coral-37138.xml","originalSource":null,"dataTypeInformation":"https://www.ncei.noaa.gov/products/paleoclimatology/coral-sclerosponge","studyCode":null,"scienceKeywords":null,"reconstruction":"N","contributionDate":"2022-12-07","entryId":"noaa-coral-37138","earliestYearBP":-48,"mostRecentYearBP":-54,"earliestYearCE":1998,"mostRecentYearCE":2004,"publication":[{"author":{"name":"Yuan Shen, Thomas P. Guilderson, Owen A. Sherwood, Carmen G. Castro, Francisco P. Chavez, Matthew D. McCarthy"},"pubYear":2021,"title":"Amino acid d13C and d15N patterns from sediment trap time series into deep-sea corals: implications for biogeochemical and ecological reconstructions in paleoarchives","journal":"Geochimica et Cosmochimica Acta","volume":"297","edition":null,"issue":null,"pages":"288-307","reportNumber":null,"citation":"Yuan Shen, Thomas P. Guilderson, Owen A. Sherwood, Carmen G. Castro, Francisco P. Chavez, Matthew D. McCarthy. 2021. Amino acid d13C and d15N patterns from sediment trap time series into deep-sea corals: implications for biogeochemical and ecological reconstructions in paleoarchives. Geochimica et Cosmochimica Acta, 297, 288-307. doi: 10.1016/j.gca.2020.12.012","type":"publication","identifier":{"type":"doi","id":"10.1016/j.gca.2020.12.012","url":"http://dx.doi.org/10.1016/j.gca.2020.12.012"},"abstract":"Recent implementation of compound-specific stable isotopes of amino acids (CSI-AA) to proteinaceous deep-sea corals opens a new realm of high-fidelity reconstructions of biogeochemical and ecological changes in the ocean. However, underlying these CSI-AA paleoceanographic applications are a series of fundamental assumptions, which hold first that baseline-proxy AA isotope values fixed at the base of food webs represent integrated d13C and d15N values of primary production, and second they stay unaltered during subsequent export and incorporation from particles into corals. Here, we explore the first long-term d13C and d15N CSI-AA data on a sediment trap time series together with contemporaneous deep-sea bamboo corals (Isidella sp.) in the California margin to for the first time directly test these assumptions. We found that the isotope values of essential (d13CEAA) and source AAs (d15NPhe) in sinking particles can quantitatively track bulk d13C and d15N values of export and primary production. These CSI-AA baseline proxies varied independently of carbon flux, trophic position (TPCSI-AA), and microbial degradation and resynthesis, suggesting good preservation in sinking particles. Paired comparisons between sinking particles and deep-sea corals revealed only small elevations of d13CEAA (~2 per mil) and d15NPhe (~1 per mil) in the coral skeletons, near the magnitude of analytical uncertainty. We hypothesize the difference in d13CEAA is due to the geographic offset in d13C values of primary production expected between the (more offshore) sediment trap site and (more onshore) coral specimens, whereas the d15NPhe offset is more likely related to a minor trophic fractionation. Using the derived empirical models, we demonstrated that CSI-AA applied to proteinaceous deep-sea corals can reconstruct bulk d15N values of export and primary production, baseline nitrogen d15N, and exported TPCSI-AA values with remarkable fidelity. Together, these findings improve our understanding of AA isotope behaviors in modern and paleoarchives and provide a strong field support for applying the rapidly evolving CSI-AA-based tools to paleoceanographic studies.","pubRank":"1"}],"site":[{"NOAASiteId":"59661","siteName":"Monterey Bay Station M2","siteCode":null,"mappable":"Y","locationName":"Ocean>Pacific Ocean>North Pacific Ocean","geo":{"geoType":"Feature","geometry":{"type":"POINT","coordinates":["36.697","-122.378"]},"properties":{"southernmostLatitude":"36.697","northernmostLatitude":"36.697","westernmostLongitude":"-122.378","easternmostLongitude":"-122.378","minElevationMeters":"-1200","maxElevationMeters":"-1200"}},"paleoData":[{"dataTableName":"sedTrap_shen2021","NOAADataTableId":"49820","earliestYear":1998,"mostRecentYear":2004,"timeUnit":"CE","earliestYearBP":-48,"mostRecentYearBP":-54,"earliestYearCE":1998,"mostRecentYearCE":2004,"coreLengthMeters":null,"dataTableNotes":"Deep-sea corals were live-collected using an ROV in 2007. Based on average radial growth rate, section of skeleton was selected to be contemporaneous with sediment trap samples. Sediment trap at Station M2: 36.697N 122.378W and positioned at 1200m water depth.Coral samples collected at 36.747N 122.022W at 915m and 835m water depth","species":[],"dataFile":[{"fileUrl":"https://www.ncei.noaa.gov/pub/data/paleo/coral/north_pacific/shen2021/sedtrap_shen2021.txt","urlDescription":"NOAA Template File","linkText":"Sediment Trap Geochemical Data","variables":[{"cvDataType":"CORALS AND SCLEROSPONGES","cvWhat":"sampling metadata>sample identification","cvMaterial":null,"cvError":null,"cvUnit":null,"cvSeasonality":null,"cvDetail":null,"cvMethod":null,"cvAdditionalInfo":"Sample ID","cvFormat":"Character","cvShortName":"Trap_ID"},{"cvDataType":"CORALS AND SCLEROSPONGES","cvWhat":"sampling metadata>collection date","cvMaterial":null,"cvError":null,"cvUnit":null,"cvSeasonality":null,"cvDetail":null,"cvMethod":null,"cvAdditionalInfo":"Trap Open date","cvFormat":"Character","cvShortName":"Initial"},{"cvDataType":"CORALS AND SCLEROSPONGES","cvWhat":"sampling metadata>collection date","cvMaterial":null,"cvError":null,"cvUnit":null,"cvSeasonality":null,"cvDetail":null,"cvMethod":null,"cvAdditionalInfo":"Trap Close Date","cvFormat":"Character","cvShortName":"Final"},{"cvDataType":"CORALS AND SCLEROSPONGES","cvWhat":"chemical composition>isotope>isotope ratio>delta 13C","cvMaterial":"chemical composition>compound>organic compound>organooxygen compound>amino acid>glycine","cvError":null,"cvUnit":"concentration unit>parts per notation unit>parts per thousand>per mil>per mil VPDB","cvSeasonality":null,"cvDetail":null,"cvMethod":"laboratory method>chromatography>gas chromatography|laboratory method>spectroscopy>mass spectrometry>isotope ratio mass spectrometry","cvAdditionalInfo":"d13C of Glycine; 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