# Equatorial Pacific Trace Metal and CaCO3 Data during the last 4,500 years #----------------------------------------------------------------------- # World Data Service for Paleoclimatology, Boulder # and # NOAA Paleoclimatology Program #----------------------------------------------------------------------- # Template Version 3.0 # Encoding: UTF-8 # NOTE: Please cite original publication, online resource and date accessed when using this data. # If there is no publication information, please cite Investigator, title, online resource and date accessed. # # Description/Documentation lines begin with # # Data lines have no # # # Online_Resource: https://www.ncdc.noaa.gov/paleo/study/28335 # Description: NOAA Landing Page # Online_Resource: https://www1.ncdc.noaa.gov/pub/data/paleo/contributions_by_author/rongstad2019/rongstad2019-ruber.txt # Description: NOAA location of the template # # Data_Type: Paleoceanography # # Dataset_DOI: # # Parameter_Keywords: trace metals in carbonate #--------------------------------------- # Contribution_Date # Date: 2019-11-21 #--------------------------------------- # File_Last_Modified_Date # Date: 2019-11-21 #--------------------------------------- # Title # Study_Name: Equatorial Pacific Trace Metal and CaCO3 Data during the last 4,500 years #--------------------------------------- # Investigators # Investigators: Rongstad, Brigitta L.; Marchitto, Thomas M.; Serrato Marks, Gabriela; Koutavas, Athanasios; Mekik, Figen; Ravelo, Ana Christina #--------------------------------------- # Description_Notes_and_Keywords # Description: Sites used: ERDC 92Bx, MGL1208-26MC, MGL1208-14MC, PLDS 72Bx, KNR195-5 MC-42A, RC13-140, KNR195-5 MC-11A, OC73-1-2, RC23-22 # Provided Keywords: individual foraminifera, ENSO, Mg/Ca #--------------------------------------- # Publication # Authors: Brigitta L. Rongstad, Thomas M. Marchitto, Gabriela Serrato Marks, Athanasios Koutavas, Figen Mekik, and Ana Christina Ravelo # Published_Date_or_Year: 2019 # Published_Title: Investigating ENSO-related temperature variability in equatorial Pacific core-tops using Mg/Ca in individual planktic foraminifera # Journal_Name: Paleoceanography and Paleoclimatology # Volume: # Edition: # Issue: # Pages: # Report_Number: # DOI: 10.1029/2019PA003774 # Online_Resource: # Full_Citation: # Abstract: El NiƱo Southern Oscillation (ENSO) is the largest source of interannual climate variability on Earth today; however, future ENSO remains difficult to predict. Evaluation of paleo-ENSO may help improve our basic understanding of the phenomenon and help resolve discrepancies among models tasked with simulating future climate. Individual foraminifera analysis (IFA) allows continuous down-core records of ENSO-related temperature variability through the construction and comparison of paleotemperature distributions; however, there has been little focus on calibrating this technique to modern conditions. Here, we present data from individual measurements of Mg/Ca in two species of planktic foraminifera, surface dwelling Globigerinoides ruber and thermocline dwelling Neogloboquadrina dutertrei, from nine core-tops across the equatorial Pacific (n 70 per core). Population variance, kernel probability density functions, and quantile-quantile analyses are used to evaluate the shape of each Mg/Ca-temperature distribution and to compare them to modern conditions using monthly temperatures from the Simple Ocean Data Assimilation. We show that populations of individual Mg/Ca measurements in both G. ruber and N. dutertrei reflect site-specific temperature distribution shapes and variances across the equatorial Pacific when accounting for regional differences in depth habitats. Individual measurements of both taxa capture zonal increases in population variance from the western equatorial Pacific to the central equatorial Pacific, and a spatially heterogeneous eastern equatorial Pacific, consistent with modern conditions. Lastly, we show that populations of individual Mg/Ca measurements are able to recover meaningful differences in temperature variability between sites within the eastern equatorial Pacific, lending support to this tool's application for paleo-ENSO reconstructions. #--------------------------------------- # Funding_Agency # Funding_Agency_Name: NSF # Grant: OCE-1603023 #--------------------------------------- # Site_Information # Site_Name: Equatorial Pacific Rongstad2019 Site Set # Location: Pacific Ocean # Country: # Northernmost_Latitude: 2.87 # Southernmost_Latitude: -7.28 # Easternmost_Longitude: -83.62 # Westernmost_Longitude: 159.98 # Elevation: #--------------------------------------- # Data_Collection # Collection_Name: Equatorial Pacific G.ruber metals Rongstad2019 # First_Year: 4516 # Last_Year: 377 # Time_Unit: cal yr BP # Core_Length: # Notes: Sites used: ERDC 92Bx, MGL1208-26MC, MGL1208-14MC, PLDS 72Bx, KNR195-5 MC-42A, RC13-140, KNR195-5 MC-11A, OC73-1-2, RC23-22 #--------------------------------------- # Chronology_Information # Chronology: # # Labcode sample identification used by 14C laboratory (AMS accession number) # Sample_ID core name # depth_top Depth top of sample interval (cm) # depth_bottom Depth bottom of sample interval (cm) # mat_dated Material Dated # 14C.raw conventional radiocarbon age, years before 1950AD # 14C.raw_err radiocarbon age, standard error # datemeth Dating method # delta-R Deviation from global mean reservoir correction # calib.14C Calibrated age # calib.14C_1sig_lo Calibrated age, 1-sigma lower confidence bound # calib.14C_1sig_up Calibrated age, 1-sigma upper confidence bound # calib_method Calibration method # notes Notes # # Labcode Sample_ID depth_top depth_bottom mat_dated 14C.raw 14C.raw_error datemeth delta-R calib.14C calib.14C_1sig_lo calib.14C_1sig_up calib_method notes # NSRL-35985 OC73-1-2 0 1 Neogloboquadrina dutertrei 4560 15 AMS 109 4516 4419 4582 CALIB7.1 two calibration rages: 1. 4419-4582 (0.94 relative probability), 2. 4451-4459 (0.06 relative probability) # NSRL-35986 KNR195-5 MC-11A 2 3 Neogloboquadrina dutertrei 1810 15 AMS 125 1251 1230 1273 CALIB7.1 NaN # # ERDC 92Bx and PLDS 72Bx (Berger and Killingley 1982), MGL1208-26MC and MGL1208-14MC (White et al. 2018), KNR195-5 MC-42A (Rustic et al. 2015), RC13-140 and RC23-22 (Doss and Marchitto 2013), KNR195-5 MC-11A and OC73-1-2 # #--------------------------------------- # Variables # Data variables follow that are preceded by "##" in columns one and two. # Variables list, one per line, shortname-tab-longname components (9 components: what, material, error, units, seasonality, archive, detail, method, C or N for Character or Numeric data) ## core_ID sample identification,,,,,paleoceanography,,,C,Core name ## depth_cm depth,,,centimeter,,paleoceanography,,,N, ## age age,,,calendar year before present,,paleoceanography,,,N,see chronology ## latitude latitude,,,degree north,,paleoceanography,,,N, ## longitude longitude,,,degree east,,paleoceanography,,,N, ## water_depth depth,,,meter,,paleoceanography,,,N,water depth ## Mg/Ca_ruber magnesium/calcium,Globigerinoides ruber,,millimole per mole,,paleoceanography,,inductively-coupled plasma mass spectrometry,N,magnetic sector inductively coupled plasma mass spectrometry; individual foraminifera; samples run at University of Colorado Boulder in Dr. Thomas Marchitto's trace metal lab ## Mn/Ca_ruber manganese/calcium,Globigerinoides ruber,,micromole per mole,,paleoceanography,,inductively-coupled plasma mass spectrometry,N,magnetic sector inductively coupled plasma mass spectrometry; individual foraminifera ## Sr/Ca_ruber strontium/calcium,Globergerinoides ruber,,millimole per mole,,paleoceanography,,inductively-coupled plasma mass spectrometry,N,magnetic sector inductively coupled plasma mass spectrometry; individual foraminifera ## Al/Ca_ruber aluminum/calcium,Globigerinoides ruber,,micromole per mole,,paleoceanography,,inductively-coupled plasma mass spectrometry,N,magnetic sector inductively coupled plasma mass spectrometry; individual foraminifera ## Fe/Ca_ruber iron/calcium,Globigerinoides ruber,,micromole per mole,,paleoceanography,,inductively-coupled plasma mass spectrometry,N,magnetic sector inductively coupled plasma mass spectrometry; individual foraminifera ## CaCO3_ruber calcium carbonate,Globigerinoides ruber,,microgram,,paleoceanography,,inductively-coupled plasma mass spectrometry,N,magnetic sector inductively coupled plasma mass spectrometry; individual foraminifera ## notes notes,,,,,paleoceanography,,,C, #------------------------ # Data: # Data lines follow (have no #) # Data line format - tab-delimited text, variable short name as header # Missing_Values: -999 core_ID depth_cm age latitude longitude water_depth Mg/Ca_ruber Mn/Ca_ruber Sr/Ca_ruber Al/Ca_ruber Fe/Ca_ruber CaCO3_ruber notes ERDC 92Bx 0-0.5 4309 -2.217 159.983 1598 4.82 5.32 1.51 107.30 -999 0.71 ERDC 92Bx 0-0.5 4309 -2.217 159.983 1598 4.88 7.76 1.54 15.25 0.18 4.37 ERDC 92Bx 0-0.5 4309 -2.217 159.983 1598 5.71 4.93 1.52 -999 12.44 6.26 ERDC 92Bx 0-0.5 4309 -2.217 159.983 1598 4.68 2.81 1.47 -999 -999 5.02 ERDC 92Bx 0-0.5 4309 -2.217 159.983 1598 4.64 4.39 1.46 -999 2.77 4.19 ERDC 92Bx 0-0.5 4309 -2.217 159.983 1598 5.89 10.12 1.56 10.30 4.10 6.61 ERDC 92Bx 0-0.5 4309 -2.217 159.983 1598 5.82 4.53 1.55 -999 -999 7.87 ERDC 92Bx 0-0.5 4309 -2.217 159.983 1598 5.42 6.43 1.50 47.17 19.81 4.30 ERDC 92Bx 0-0.5 4309 -2.217 159.983 1598 35.23 82.97 1.43 -999 383.73 2.08 sample discarded, high Mg (>10 mmol/mol) ERDC 92Bx 0-0.5 4309 -2.217 159.983 1598 4.96 6.97 1.57 1771.48 48.85 3.96 sample discarded, high Al (>1000 micromol/mol) ERDC 92Bx 0-0.5 4309 -2.217 159.983 1598 12.02 -999 1.33 -999 -999 0.07 sample discarded, mass CaCO3 less than 0.1 micrograms ERDC 92Bx 0-0.5 4309 -2.217 159.983 1598 5.67 8.84 1.56 -999 0.72 2.70 ERDC 92Bx 0-0.5 4309 -2.217 159.983 1598 5.80 14.18 1.54 102.89 -999 6.03 ERDC 92Bx 0-0.5 4309 -2.217 159.983 1598 5.60 7.35 1.42 -999 5.35 4.15 ERDC 92Bx 0-0.5 4309 -2.217 159.983 1598 6.27 12.03 1.56 94.42 35.02 7.53 ERDC 92Bx 0-0.5 4309 -2.217 159.983 1598 4.77 4.83 1.48 -999 10.23 7.08 ERDC 92Bx 0-0.5 4309 -2.217 159.983 1598 4.11 6.28 1.48 -999 13.54 5.23 ERDC 92Bx 0-0.5 4309 -2.217 159.983 1598 4.09 21.01 1.48 -999 4.95 4.38 ERDC 92Bx 0-0.5 4309 -2.217 159.983 1598 4.44 5.87 1.49 -999 6.99 5.71 ERDC 92Bx 0-0.5 4309 -2.217 159.983 1598 3.11 13.55 1.51 -999 5.31 3.69 ERDC 92Bx 0-0.5 4309 -2.217 159.983 1598 4.88 5.99 1.54 -999 4.11 6.41 ERDC 92Bx 0-0.5 4309 -2.217 159.983 1598 4.26 20.85 1.51 -999 7.71 3.78 ERDC 92Bx 0-0.5 4309 -2.217 159.983 1598 4.25 4.45 1.50 5.35 5.92 5.49 ERDC 92Bx 0-0.5 4309 -2.217 159.983 1598 5.74 5.87 1.46 2.95 14.41 6.59 ERDC 92Bx 0-0.5 4309 -2.217 159.983 1598 4.46 4.19 1.55 -999 5.80 5.39 ERDC 92Bx 0-0.5 4309 -2.217 159.983 1598 5.17 19.11 1.52 -999 1.83 5.71 ERDC 92Bx 0-0.5 4309 -2.217 159.983 1598 6.40 2.59 1.47 13.14 14.75 4.04 ERDC 92Bx 0-0.5 4309 -2.217 159.983 1598 4.68 6.84 1.52 43.85 43.94 10.66 ERDC 92Bx 0-0.5 4309 -2.217 159.983 1598 5.00 4.31 1.50 -999 15.32 6.15 ERDC 92Bx 0-0.5 4309 -2.217 159.983 1598 5.04 9.02 1.49 -999 14.79 5.56 ERDC 92Bx 0-0.5 4309 -2.217 159.983 1598 6.07 16.95 1.53 90.05 22.77 2.36 ERDC 92Bx 0-0.5 4309 -2.217 159.983 1598 3.67 17.19 1.51 14.57 20.46 6.22 ERDC 92Bx 0-0.5 4309 -2.217 159.983 1598 4.99 19.31 1.41 23.10 54.97 7.19 ERDC 92Bx 0-0.5 4309 -2.217 159.983 1598 5.13 4.34 1.51 222.17 22.51 2.56 ERDC 92Bx 0-0.5 4309 -2.217 159.983 1598 4.89 10.19 1.48 -999 21.80 4.38 ERDC 92Bx 0-0.5 4309 -2.217 159.983 1598 4.46 3.64 1.47 -999 24.40 7.10 ERDC 92Bx 0-0.5 4309 -2.217 159.983 1598 4.77 5.19 1.49 55.76 17.70 5.29 ERDC 92Bx 0-0.5 4309 -2.217 159.983 1598 4.82 6.73 1.59 -999 18.08 5.39 ERDC 92Bx 0-0.5 4309 -2.217 159.983 1598 4.92 3.41 1.52 -999 11.54 2.16 ERDC 92Bx 0-0.5 4309 -2.217 159.983 1598 5.41 8.91 1.50 33.15 20.62 5.93 ERDC 92Bx 0-0.5 4309 -2.217 159.983 1598 4.94 19.07 1.51 19.10 21.24 4.28 ERDC 92Bx 0-0.5 4309 -2.217 159.983 1598 5.23 9.72 1.48 8.44 14.39 3.96 ERDC 92Bx 0-0.5 4309 -2.217 159.983 1598 4.90 3.95 1.48 -999 14.43 5.50 ERDC 92Bx 0-0.5 4309 -2.217 159.983 1598 3.36 28.29 1.42 -999 11.90 2.51 ERDC 92Bx 0-0.5 4309 -2.217 159.983 1598 4.51 15.66 1.49 -999 25.32 6.36 ERDC 92Bx 0-0.5 4309 -2.217 159.983 1598 5.34 7.18 1.57 -999 15.11 2.75 ERDC 92Bx 0-0.5 4309 -2.217 159.983 1598 4.88 20.36 1.57 749.46 275.80 11.08 ERDC 92Bx 0-0.5 4309 -2.217 159.983 1598 4.50 9.53 1.54 -999 12.39 11.75 ERDC 92Bx 0-0.5 4309 -2.217 159.983 1598 5.60 6.45 1.44 -999 5.69 6.05 ERDC 92Bx 0-0.5 4309 -2.217 159.983 1598 5.62 7.93 1.55 21.44 3.30 3.79 ERDC 92Bx 0-0.5 4309 -2.217 159.983 1598 4.15 4.89 1.51 66.99 16.82 8.45 ERDC 92Bx 0-0.5 4309 -2.217 159.983 1598 4.44 24.94 1.41 95.35 14.33 0.62 ERDC 92Bx 0-0.5 4309 -2.217 159.983 1598 4.84 4.50 1.57 21.43 3.18 2.51 ERDC 92Bx 0-0.5 4309 -2.217 159.983 1598 3.57 4.30 1.49 57.97 20.96 3.57 ERDC 92Bx 0-0.5 4309 -2.217 159.983 1598 5.33 9.48 1.52 6.60 10.71 3.36 ERDC 92Bx 0-0.5 4309 -2.217 159.983 1598 4.44 7.75 1.50 -999 10.28 4.05 ERDC 92Bx 0-0.5 4309 -2.217 159.983 1598 5.31 26.72 1.49 15.32 14.67 4.02 ERDC 92Bx 0-0.5 4309 -2.217 159.983 1598 5.52 2.06 1.61 133.70 12.27 1.13 ERDC 92Bx 0-0.5 4309 -2.217 159.983 1598 7.13 0.82 1.50 228.33 34.67 0.60 ERDC 92Bx 0-0.5 4309 -2.217 159.983 1598 5.29 3.76 1.61 117.21 19.35 3.27 ERDC 92Bx 0-0.5 4309 -2.217 159.983 1598 5.51 10.20 1.51 33.49 14.01 2.04 ERDC 92Bx 0-0.5 4309 -2.217 159.983 1598 4.83 6.86 1.51 38.51 27.46 3.67 ERDC 92Bx 0-0.5 4309 -2.217 159.983 1598 15.92 18.97 1.50 734.77 223.02 5.12 sample discarded, high Mg (>10 mmol/mol) ERDC 92Bx 0-0.5 4309 -2.217 159.983 1598 5.20 6.74 1.52 33.56 6.36 4.39 ERDC 92Bx 0-0.5 4309 -2.217 159.983 1598 4.23 12.35 1.50 14.23 10.42 3.86 ERDC 92Bx 0-0.5 4309 -2.217 159.983 1598 4.37 2.51 1.50 4.17 9.20 3.33 ERDC 92Bx 0-0.5 4309 -2.217 159.983 1598 4.90 4.33 1.43 75.70 9.55 8.32 ERDC 92Bx 0-0.5 4309 -2.217 159.983 1598 4.75 5.70 1.51 6.15 3.99 4.74 ERDC 92Bx 0-0.5 4309 -2.217 159.983 1598 5.33 4.47 1.47 -999 9.40 5.95 ERDC 83Bx 0-1.5 4309 -2.217 159.983 1598 5.46 9.15 1.54 99.72 57.72 5.42 ERDC 92Bx 0-0.6 4309 -2.217 159.983 1598 4.24 13.39 1.43 13.40 6.39 7.30 ERDC 83Bx 0-1.6 4309 -2.217 159.983 1598 3.64 4.05 1.47 23.26 6.49 4.30 ERDC 92Bx 0-0.7 4309 -2.217 159.983 1598 2.82 43.76 1.33 13.66 24.06 5.25 MGL1208-14MC 0-1 4030 -0.220 -155.961 3049 4.43 0.99 1.31 228.54 12.49 1.06 MGL1208-14MC 0-1 4030 -0.220 -155.961 3049 4.06 4.01 1.41 212.25 12.36 0.94 MGL1208-14MC 0-1 4030 -0.220 -155.961 3049 4.73 1.14 1.45 300.44 33.49 0.52 MGL1208-14MC 0-1 4030 -0.220 -155.961 3049 3.92 0.51 1.39 326.61 20.17 0.65 MGL1208-14MC 0-1 4030 -0.220 -155.961 3049 3.78 8.61 1.45 279.93 24.26 0.93 MGL1208-14MC 0-1 4030 -0.220 -155.961 3049 3.26 5.03 1.38 50.87 45.80 2.09 MGL1208-14MC 0-1 4030 -0.220 -155.961 3049 3.76 1.54 1.39 81.93 19.35 0.69 MGL1208-14MC 0-1 4030 -0.220 -155.961 3049 6.04 17.70 1.40 326.72 381.97 0.44 MGL1208-14MC 0-1 4030 -0.220 -155.961 3049 64.81 346.28 1.45 8124.29 3125.71 0.04 sample discarded, high Mg (>10 mmol/mol) MGL1208-14MC 0-1 4030 -0.220 -155.961 3049 3.84 5.16 1.43 19.65 27.08 1.52 MGL1208-14MC 0-1 4030 -0.220 -155.961 3049 3.48 11.29 1.38 33.51 35.87 1.72 MGL1208-14MC 0-1 4030 -0.220 -155.961 3049 -999 -999 -999 836660.10 83129.90 0.00 sample discarded, mass CaCO3 less than 0.1 micrograms MGL1208-14MC 0-1 4030 -0.220 -155.961 3049 3.84 0.56 1.42 12.61 11.54 1.78 MGL1208-14MC 0-1 4030 -0.220 -155.961 3049 3.88 3.10 1.47 618.95 38.63 0.31 MGL1208-14MC 0-1 4030 -0.220 -155.961 3049 6.62 8.62 1.39 216.06 135.82 0.61 MGL1208-14MC 0-1 4030 -0.220 -155.961 3049 5.19 5.28 1.38 231.78 130.75 0.69 MGL1208-14MC 0-1 4030 -0.220 -155.961 3049 3.73 1.67 1.36 31.39 15.27 1.62 MGL1208-14MC 0-1 4030 -0.220 -155.961 3049 4.25 10.97 1.41 18.47 34.13 0.61 MGL1208-14MC 0-1 4030 -0.220 -155.961 3049 4.48 3.12 1.49 665.54 35.02 0.68 MGL1208-14MC 0-1 4030 -0.220 -155.961 3049 4.20 1.39 1.47 -999 22.90 1.97 MGL1208-14MC 0-1 4030 -0.220 -155.961 3049 4.74 10.53 1.39 26.92 22.35 1.48 MGL1208-14MC 0-1 4030 -0.220 -155.961 3049 2.99 7.66 1.43 4.58 38.77 2.67 MGL1208-14MC 0-1 4030 -0.220 -155.961 3049 3.81 -999 1.38 -999 20.80 0.59 MGL1208-14MC 0-1 4030 -0.220 -155.961 3049 4.87 -999 1.41 84.57 41.42 0.28 MGL1208-14MC 0-1 4030 -0.220 -155.961 3049 4.80 -999 1.40 70.54 19.81 0.45 MGL1208-14MC 0-1 4030 -0.220 -155.961 3049 3.53 -999 1.42 19.39 15.29 1.34 MGL1208-14MC 0-1 4030 -0.220 -155.961 3049 3.66 4.75 1.38 7.07 14.94 4.55 MGL1208-14MC 0-1 4030 -0.220 -155.961 3049 10.53 -999 1.48 533.99 274.25 0.05 sample discarded, high Mg (>10 mmol/mol) MGL1208-14MC 0-1 4030 -0.220 -155.961 3049 4.45 5.14 1.44 134.12 104.66 1.58 MGL1208-14MC 0-1 4030 -0.220 -155.961 3049 2.88 2.05 1.39 152.79 16.65 2.09 MGL1208-14MC 0-1 4030 -0.220 -155.961 3049 4.45 1.43 1.42 54.85 21.81 0.37 MGL1208-14MC 0-1 4030 -0.220 -155.961 3049 4.26 1.58 1.43 13.09 8.52 3.03 MGL1208-14MC 0-1 4030 -0.220 -155.961 3049 5.12 1.58 1.32 7.62 10.52 3.84 MGL1208-14MC 0-1 4030 -0.220 -155.961 3049 3.29 1.59 1.38 26.99 30.41 3.33 MGL1208-14MC 0-1 4030 -0.220 -155.961 3049 2.45 19.66 1.36 -999 64.99 5.83 MGL1208-14MC 0-1 4030 -0.220 -155.961 3049 3.56 15.10 1.30 12.22 23.06 1.87 MGL1208-14MC 0-1 4030 -0.220 -155.961 3049 3.69 -999 1.36 275.34 43.03 0.20 MGL1208-14MC 0-1 4030 -0.220 -155.961 3049 4.03 0.29 1.35 93.62 18.41 2.48 MGL1208-14MC 0-1 4030 -0.220 -155.961 3049 10.20 27.73 1.32 3113.77 419.61 0.82 sample discarded, high Mg (>10 mmol/mol) MGL1208-14MC 0-1 4030 -0.220 -155.961 3049 9.26 23.86 1.47 2694.22 251.17 0.11 sample discarded, high Al (>1000 micromol/mol) MGL1208-14MC 0-1 4030 -0.220 -155.961 3049 3.34 3.67 1.43 15.62 22.58 4.00 MGL1208-14MC 0-1 4030 -0.220 -155.961 3049 9.01 5.38 1.43 440.39 11.61 0.14 sample discarded, temperature >3 standard deviations away from mean MGL1208-14MC 0-1 4030 -0.220 -155.961 3049 10.05 36.17 1.44 2186.32 135.43 0.06 sample discarded, high Mg (>10 mmol/mol) MGL1208-14MC 0-1 4030 -0.220 -155.961 3049 3.26 3.90 1.45 88.38 20.36 0.58 MGL1208-14MC 0-1 4030 -0.220 -155.961 3049 3.17 19.66 1.36 47.67 29.89 0.40 MGL1208-14MC 0-1 4030 -0.220 -155.961 3049 11.36 52.62 1.40 3794.55 411.98 0.04 sample discarded, high Mg (>10 mmol/mol) MGL1208-14MC 0-1 4030 -0.220 -155.961 3049 3.14 3.10 1.43 28.49 14.49 2.05 MGL1208-14MC 0-1 4030 -0.220 -155.961 3049 3.94 4.89 1.40 232.63 32.58 0.36 MGL1208-14MC 0-1 4030 -0.220 -155.961 3049 2.50 3.47 1.39 187.47 24.77 1.81 MGL1208-14MC 0-1 4030 -0.220 -155.961 3049 3.23 0.42 1.50 64.35 5.61 0.66 MGL1208-14MC 0-1 4030 -0.220 -155.961 3049 5.94 6.26 1.37 346.07 36.16 2.69 MGL1208-14MC 0-1 4030 -0.220 -155.961 3049 4.59 -999 1.40 187.60 9.89 0.48 MGL1208-14MC 0-1 4030 -0.220 -155.961 3049 2.09 39.52 1.42 12.61 65.60 6.05 MGL1208-14MC 0-1 4030 -0.220 -155.961 3049 3.49 0.86 1.41 205.95 15.86 0.52 MGL1208-14MC 0-1 4030 -0.220 -155.961 3049 3.17 8.85 1.44 17.56 32.93 4.53 MGL1208-14MC 0-1 4030 -0.220 -155.961 3049 2.93 -999 1.39 67.99 5.46 0.75 MGL1208-14MC 0-1 4030 -0.220 -155.961 3049 5.03 0.43 1.48 67.36 9.68 1.13 MGL1208-14MC 0-1 4030 -0.220 -155.961 3049 4.14 3.39 1.44 63.06 14.89 1.19 MGL1208-14MC 0-1 4030 -0.220 -155.961 3049 4.21 -999 1.38 443.72 10.76 0.19 MGL1208-14MC 0-1 4030 -0.220 -155.961 3049 6.21 -999 1.45 132.33 6.96 2.55 MGL1208-14MC 0-1 4030 -0.220 -155.961 3049 3.42 5.75 1.32 191.05 36.75 0.47 MGL1208-14MC 0-1 4030 -0.220 -155.961 3049 2.95 4.33 1.40 48.00 13.78 0.54 MGL1208-14MC 0-1 4030 -0.220 -155.961 3049 4.79 -999 1.37 553.12 27.17 0.13 MGL1208-14MC 0-1 4030 -0.220 -155.961 3049 4.17 0.46 1.42 21.10 12.49 1.04 MGL1208-14MC 0-1 4030 -0.220 -155.961 3049 2.94 2.84 1.36 120.50 17.76 1.84 MGL1208-14MC 0-1 4030 -0.220 -155.961 3049 3.54 21.43 1.36 10.36 21.47 2.26 MGL1208-14MC 0-1 4030 -0.220 -155.961 3049 3.49 63.07 1.43 73.28 103.67 1.99 MGL1208-14MC 0-1 4030 -0.220 -155.961 3049 3.87 9.34 1.42 198.37 149.04 1.28 MGL1208-14MC 0-1 4030 -0.220 -155.961 3049 3.46 33.02 1.36 36.77 29.64 3.01 MGL1208-14MC 0-1 4030 -0.220 -155.961 3049 3.80 6.31 1.42 11.15 27.55 4.00 MGL1208-14MC 0-1 4030 -0.220 -155.961 3049 18.89 4.12 4.02 19576.42 298.02 0.03 sample discarded, mass CaCO3 less than 0.1 micrograms MGL1208-14MC 0-1 4030 -0.220 -155.961 3049 17.41 -999 0.17 1098.52 -999 0.03 sample discarded, mass CaCO3 less than 0.1 micrograms MGL1208-14MC 0-1 4030 -0.220 -155.961 3049 3.58 0.40 1.38 -999 13.95 1.29 MGL1208-14MC 0-1 4030 -0.220 -155.961 3049 3.03 5.07 1.43 -999 0.71 1.00 MGL1208-14MC 0-1 4030 -0.220 -155.961 3049 3.69 3.40 1.34 67.73 2.67 2.45 MGL1208-14MC 0-1 4030 -0.220 -155.961 3049 4.37 -999 1.28 -999 3.06 0.76 MGL1208-14MC 0-1 4030 -0.220 -155.961 3049 5.12 -999 1.14 -999 -999 0.14 MGL1208-14MC 0-1 4030 -0.220 -155.961 3049 3.64 0.47 1.36 -999 14.50 1.04 MGL1208-14MC 0-1 4030 -0.220 -155.961 3049 3.60 0.41 1.33 -999 15.80 0.78 MGL1208-14MC 0-1 4030 -0.220 -155.961 3049 5.86 6.21 1.37 625.92 131.60 0.65 MGL1208-14MC 0-1 4030 -0.220 -155.961 3049 4.62 3.90 1.39 534.29 24.80 1.57 MGL1208-14MC 0-1 4030 -0.220 -155.961 3049 4.30 11.47 1.30 -999 19.87 0.55 KNR195-5 MC-42A 2-3 377 -1.253 -89.686 615 3.03 3.50 1.35 32.80 15.46 3.47 KNR195-5 MC-42A 2-3 377 -1.253 -89.686 615 2.57 5.80 1.40 10.50 37.79 12.86 KNR195-5 MC-42A 2-3 377 -1.253 -89.686 615 3.44 7.11 1.48 7.69 52.23 8.80 KNR195-5 MC-42A 2-3 377 -1.253 -89.686 615 4.19 4.15 1.42 15.16 27.49 7.67 KNR195-5 MC-42A 2-3 377 -1.253 -89.686 615 4.57 17.72 1.38 368.71 83.48 3.73 KNR195-5 MC-42A 2-3 377 -1.253 -89.686 615 3.41 6.42 1.35 5.63 43.20 7.29 KNR195-5 MC-42A 2-3 377 -1.253 -89.686 615 3.73 2.61 1.41 17.51 32.74 5.82 KNR195-5 MC-42A 2-3 377 -1.253 -89.686 615 4.20 9.04 1.44 14.82 46.46 5.48 KNR195-5 MC-42A 2-3 377 -1.253 -89.686 615 5.18 3.76 1.45 25.74 30.30 5.56 KNR195-5 MC-42A 2-3 377 -1.253 -89.686 615 3.91 3.41 1.35 18.84 48.66 5.71 KNR195-5 MC-42A 2-3 377 -1.253 -89.686 615 3.50 6.15 1.40 265.33 36.37 2.68 KNR195-5 MC-42A 2-3 377 -1.253 -89.686 615 3.96 6.09 1.45 40.22 44.76 8.51 KNR195-5 MC-42A 2-3 377 -1.253 -89.686 615 2.85 8.09 1.44 10.59 48.67 10.23 KNR195-5 MC-42A 2-3 377 -1.253 -89.686 615 4.36 6.96 1.38 195.39 113.85 4.02 KNR195-5 MC-42A 2-3 377 -1.253 -89.686 615 3.20 9.69 1.45 12.23 67.57 8.27 KNR195-5 MC-42A 2-3 377 -1.253 -89.686 615 3.28 7.89 1.41 233.12 161.38 6.72 KNR195-5 MC-42A 2-3 377 -1.253 -89.686 615 5.04 5.09 1.46 40.16 36.41 4.83 KNR195-5 MC-42A 2-3 377 -1.253 -89.686 615 7.28 7.11 1.43 1595.63 67.64 0.19 sample discarded, high Al (>1000 micromol/mol) KNR195-5 MC-42A 2-3 377 -1.253 -89.686 615 3.96 5.49 1.45 17.88 64.64 6.52 KNR195-5 MC-42A 2-3 377 -1.253 -89.686 615 3.43 8.58 1.48 41.75 43.45 6.86 KNR195-5 MC-42A 2-3 377 -1.253 -89.686 615 3.70 6.77 1.50 116.64 57.26 1.86 KNR195-5 MC-42A 2-3 377 -1.253 -89.686 615 3.76 8.28 1.46 37.47 67.55 4.86 KNR195-5 MC-42A 2-3 377 -1.253 -89.686 615 4.07 4.93 1.36 17.02 45.29 9.76 KNR195-5 MC-42A 3-4 377 -1.253 -89.686 615 3.83 4.80 1.46 12.84 12.00 7.97 KNR195-5 MC-42A 3-4 377 -1.253 -89.686 615 2.64 3.17 1.42 26.04 18.25 7.31 KNR195-5 MC-42A 3-4 377 -1.253 -89.686 615 3.24 5.63 1.45 36.98 39.11 12.27 KNR195-5 MC-42A 3-4 377 -1.253 -89.686 615 3.22 7.17 1.47 14.23 47.59 11.20 KNR195-5 MC-42A 3-4 377 -1.253 -89.686 615 3.03 3.45 1.43 17.48 21.12 6.04 KNR195-5 MC-42A 3-4 377 -1.253 -89.686 615 2.78 2.44 1.28 86.69 20.08 1.30 KNR195-5 MC-42A 3-4 377 -1.253 -89.686 615 3.29 1.79 1.44 119.69 8.34 1.26 KNR195-5 MC-42A 3-4 377 -1.253 -89.686 615 3.64 5.86 1.38 23.59 35.11 7.78 KNR195-5 MC-42A 3-4 377 -1.253 -89.686 615 4.80 1.75 1.44 68.76 10.95 1.48 KNR195-5 MC-42A 3-4 377 -1.253 -89.686 615 3.66 6.51 1.42 23.84 46.21 6.83 KNR195-5 MC-42A 3-4 377 -1.253 -89.686 615 3.98 6.37 1.48 575.58 399.06 4.62 KNR195-5 MC-42A 3-4 377 -1.253 -89.686 615 3.97 4.75 1.42 33.10 27.07 6.65 KNR195-5 MC-42A 3-4 377 -1.253 -89.686 615 3.26 5.43 1.37 19.86 31.57 10.68 KNR195-5 MC-42A 3-4 377 -1.253 -89.686 615 3.58 8.10 1.39 63.13 38.49 3.29 KNR195-5 MC-42A 3-4 377 -1.253 -89.686 615 3.72 6.83 1.37 0.51 43.21 14.26 KNR195-5 MC-42A 3-4 377 -1.253 -89.686 615 3.10 6.94 1.46 86.73 41.06 7.93 KNR195-5 MC-42A 3-4 377 -1.253 -89.686 615 2.38 4.32 1.34 24.13 26.17 6.23 KNR195-5 MC-42A 3-4 377 -1.253 -89.686 615 3.17 9.13 1.37 16.07 59.53 8.69 KNR195-5 MC-42A 3-4 377 -1.253 -89.686 615 3.71 6.09 1.40 240.40 56.90 1.15 KNR195-5 MC-42A 3-4 377 -1.253 -89.686 615 2.78 4.23 1.42 113.39 19.29 1.13 KNR195-5 MC-42A 3-4 377 -1.253 -89.686 615 2.50 4.52 1.39 12.07 31.64 9.03 KNR195-5 MC-42A 3-4 377 -1.253 -89.686 615 2.65 4.53 1.41 16.14 28.74 5.79 KNR195-5 MC-42A 3-4 377 -1.253 -89.686 615 3.49 12.80 1.30 382.31 30.03 0.38 KNR195-5 MC-42A 4-5 377 -1.253 -89.686 615 3.34 1.70 1.33 115.87 13.21 0.67 KNR195-5 MC-42A 4-5 377 -1.253 -89.686 615 2.72 2.68 1.42 27.91 16.86 2.93 KNR195-5 MC-42A 4-5 377 -1.253 -89.686 615 3.40 6.47 1.40 -999 50.92 9.78 KNR195-5 MC-42A 4-5 377 -1.253 -89.686 615 3.46 5.47 1.37 15.98 35.58 3.58 KNR195-5 MC-42A 4-5 377 -1.253 -89.686 615 3.81 2.45 1.40 70.34 10.82 4.17 KNR195-5 MC-42A 4-5 377 -1.253 -89.686 615 3.13 2.97 1.43 78.45 18.45 0.69 KNR195-5 MC-42A 4-5 377 -1.253 -89.686 615 3.27 6.24 1.38 0.16 40.11 14.81 KNR195-5 MC-42A 4-5 377 -1.253 -89.686 615 2.59 5.15 1.43 -999 39.30 11.18 KNR195-5 MC-42A 4-5 377 -1.253 -89.686 615 3.01 4.62 1.29 15.93 26.63 3.65 KNR195-5 MC-42A 4-5 377 -1.253 -89.686 615 2.62 6.99 1.37 -999 38.43 7.52 KNR195-5 MC-42A 4-5 377 -1.253 -89.686 615 3.75 9.08 1.45 48.65 64.40 13.00 KNR195-5 MC-42A 4-5 377 -1.253 -89.686 615 3.24 4.99 1.41 7.57 18.12 4.51 KNR195-5 MC-42A 4-5 377 -1.253 -89.686 615 2.67 5.67 1.47 59.64 24.47 1.09 KNR195-5 MC-42A 4-5 377 -1.253 -89.686 615 3.19 5.19 1.34 326.74 63.11 2.33 KNR195-5 MC-42A 4-5 377 -1.253 -89.686 615 4.10 2.05 1.37 29.63 17.74 3.75 KNR195-5 MC-42A 4-5 377 -1.253 -89.686 615 2.99 4.78 1.37 17.96 40.68 7.83 KNR195-5 MC-42A 4-5 377 -1.253 -89.686 615 2.74 5.48 1.36 117.38 42.63 4.49 KNR195-5 MC-42A 4-5 377 -1.253 -89.686 615 2.95 8.23 1.42 5.43 43.31 5.78 KNR195-5 MC-42A 4-5 377 -1.253 -89.686 615 4.13 5.28 1.38 40.97 21.59 1.60 KNR195-5 MC-42A 4-5 377 -1.253 -89.686 615 3.02 3.45 1.37 122.91 6.64 0.84 KNR195-5 MC-42A 4-5 377 -1.253 -89.686 615 2.42 5.67 1.37 349.31 31.61 5.91 KNR195-5 MC-42A 4-5 377 -1.253 -89.686 615 3.56 8.80 1.40 237.85 576.88 3.76 KNR195-5 MC-42A 4-5 377 -1.253 -89.686 615 3.20 4.77 1.35 -999 39.83 6.65 KNR195-5 MC-42A 5-6 377 -1.253 -89.686 615 4.79 2.90 1.52 18.15 13.52 9.33 KNR195-5 MC-42A 5-6 377 -1.253 -89.686 615 3.04 -999 1.39 -999 9.60 0.48 KNR195-5 MC-42A 5-6 377 -1.253 -89.686 615 3.16 9.41 1.42 29.11 60.14 10.36 KNR195-5 MC-42A 5-6 377 -1.253 -89.686 615 2.56 4.74 1.38 12.62 28.45 6.37 KNR195-5 MC-42A 5-6 377 -1.253 -89.686 615 6.25 3.59 1.45 -999 18.37 2.46 sample discarded, temperature >3 standard deviations away from mean KNR195-5 MC-42A 5-6 377 -1.253 -89.686 615 2.11 8.90 1.40 37.57 56.00 5.16 KNR195-5 MC-42A 5-6 377 -1.253 -89.686 615 2.93 3.93 1.44 12.94 19.39 9.28 KNR195-5 MC-42A 5-6 377 -1.253 -89.686 615 2.67 6.82 1.39 65.83 54.25 9.04 KNR195-5 MC-42A 5-6 377 -1.253 -89.686 615 2.87 4.28 1.44 17.16 12.20 7.71 KNR195-5 MC-42A 5-6 377 -1.253 -89.686 615 2.80 4.47 1.41 67.21 19.26 0.90 KNR195-5 MC-42A 5-6 377 -1.253 -89.686 615 3.27 4.22 1.41 81.51 16.64 9.81 KNR195-5 MC-42A 5-6 377 -1.253 -89.686 615 4.10 1.92 1.48 87.01 8.62 2.15 KNR195-5 MC-42A 5-6 377 -1.253 -89.686 615 4.90 4.94 1.38 157.91 35.19 2.55 KNR195-5 MC-42A 5-6 377 -1.253 -89.686 615 2.65 2.16 1.41 89.11 12.24 0.57 KNR195-5 MC-42A 5-6 377 -1.253 -89.686 615 3.06 10.08 1.36 122.96 38.79 7.75 KNR195-5 MC-42A 5-6 377 -1.253 -89.686 615 -999 -999 -999 -999 23170.82 0.00 sample discarded, mass CaCO3 less than 0.1 micrograms KNR195-5 MC-42A 5-6 377 -1.253 -89.686 615 2.80 6.32 1.44 205.57 26.46 8.69 KNR195-5 MC-42A 5-6 377 -1.253 -89.686 615 3.35 2.60 1.57 273.93 9.72 1.31 KNR195-5 MC-42A 5-6 377 -1.253 -89.686 615 3.01 5.35 1.41 9.74 30.11 11.05 KNR195-5 MC-42A 5-6 377 -1.253 -89.686 615 5.18 3.45 1.47 26.54 14.16 5.08 KNR195-5 MC-42A 5-6 377 -1.253 -89.686 615 3.45 3.06 1.48 3.82 14.83 11.64 KNR195-5 MC-42A 5-6 377 -1.253 -89.686 615 4.13 6.22 1.44 11.66 20.85 9.52 KNR195-5 MC-42A 5-6 377 -1.253 -89.686 615 3.19 3.95 1.36 59.37 18.78 4.29 RC13-140 0-1 1260 2.87 -87.75 2246 1.68 164.32 1.42 31.63 12.87 8.77 RC13-140 0-1 1260 2.87 -87.75 2246 2.69 92.77 2.93 49.32 27.85 2.12 RC13-140 0-1 1260 2.87 -87.75 2246 4.63 3500.37 1.41 176.61 270.46 0.59 sample discarded, high Mn (>1500 micromol/mol) RC13-140 0-1 1260 2.87 -87.75 2246 4.32 242.90 1.37 258.69 17.91 0.38 RC13-140 0-1 1260 2.87 -87.75 2246 2.29 335.82 1.38 -999 19.67 10.07 RC13-140 0-1 1260 2.87 -87.75 2246 2.66 57.37 1.39 8.00 7.79 2.28 RC13-140 0-1 1260 2.87 -87.75 2246 5.13 324.83 1.39 453.22 80.61 0.18 RC13-140 0-1 1260 2.87 -87.75 2246 8.47 156.56 1.39 518.13 238.33 0.49 sample discarded, temperature >3 standard deviations away from mean RC13-140 0-1 1260 2.87 -87.75 2246 -999 1310.34 0.88 495168.44 1518.74 0.00 sample discarded, mass CaCO3 less than 0.1 micrograms RC13-140 0-1 1260 2.87 -87.75 2246 4.58 1515.30 1.37 285.22 56.28 0.52 sample discarded, high Mn (>1500 micromol/mol) RC13-140 0-1 1260 2.87 -87.75 2246 1749.96 -999 0.83 341888.82 3785.03 0.00 sample discarded, mass CaCO3 less than 0.1 micrograms RC13-140 0-1 1260 2.87 -87.75 2246 5.81 1025.46 1.42 617.41 72.44 0.25 RC13-140 0-1 1260 2.87 -87.75 2246 2.61 96.15 1.38 68.63 8.43 1.79 RC13-140 0-1 1260 2.87 -87.75 2246 5.04 3353.97 4.23 60.53 37.09 2.82 sample discarded, high Mn (>1500 micromol/mol) RC13-140 0-1 1260 2.87 -87.75 2246 3.06 213.82 1.39 159.63 27.55 0.68 RC13-140 0-1 1260 2.87 -87.75 2246 3.12 530.59 1.41 79.76 28.46 1.50 RC13-140 0-1 1260 2.87 -87.75 2246 3.80 118.30 1.41 517.80 61.06 0.97 RC13-140 1-2 1260 2.87 -87.75 2246 10.18 10036.77 1.33 1941.15 259.85 0.30 sample discarded, high Mg (>10 mmol/mol) RC13-140 1-2 1260 2.87 -87.75 2246 11.04 114.65 1.34 1136.37 54.70 0.29 sample discarded, high Mg (>10 mmol/mol) RC13-140 1-2 1260 2.87 -87.75 2246 2.26 281.41 1.38 -999 45.09 6.44 RC13-140 1-2 1260 2.87 -87.75 2246 2.21 75.82 1.37 19.93 4.72 2.49 RC13-140 1-2 1260 2.87 -87.75 2246 3.73 48.56 1.48 209.44 30.00 0.94 RC13-140 1-2 1260 2.87 -87.75 2246 4.18 69.65 1.34 134.83 16.19 1.51 RC13-140 1-2 1260 2.87 -87.75 2246 6.68 234.70 1.36 692.57 44.80 0.34 RC13-140 1-2 1260 2.87 -87.75 2246 2.57 142.82 1.28 157.48 16.93 1.28 RC13-140 1-2 1260 2.87 -87.75 2246 2.43 57.29 1.40 38.18 5.64 6.82 RC13-140 1-2 1260 2.87 -87.75 2246 2.22 77.94 1.35 35.29 11.35 7.26 RC13-140 1-2 1260 2.87 -87.75 2246 2.32 465.72 1.37 44.66 46.02 7.76 RC13-140 1-2 1260 2.87 -87.75 2246 4.56 468.48 1.35 447.77 10.35 0.46 RC13-140 1-2 1260 2.87 -87.75 2246 2.32 92.08 1.40 69.74 12.76 2.00 RC13-140 1-2 1260 2.87 -87.75 2246 3.32 240.04 1.35 126.25 21.01 0.58 RC13-140 1-2 1260 2.87 -87.75 2246 3.08 291.74 1.39 163.47 1.47 0.63 RC13-140 1-2 1260 2.87 -87.75 2246 1.90 36.76 1.39 -999 1.95 2.64 RC13-140 1-2 1260 2.87 -87.75 2246 2.69 227.26 1.51 -999 201.86 9.91 RC13-140 1-2 1260 2.87 -87.75 2246 3.71 42.86 1.42 181.60 1.42 0.71 RC13-140 1-2 1260 2.87 -87.75 2246 4.72 469.28 1.44 341.37 18.80 0.55 RC13-140 1-2 1260 2.87 -87.75 2246 2.31 98.95 1.50 -999 15.09 9.89 RC13-140 1-2 1260 2.87 -87.75 2246 3.35 49.53 1.45 399.49 3.74 0.45 RC13-140 1-2 1260 2.87 -87.75 2246 2.82 94.15 1.32 -999 6.73 5.98 RC13-140 1-2 1260 2.87 -87.75 2246 3.86 609.89 1.43 114.07 126.96 7.84 RC13-140 1-2 1260 2.87 -87.75 2246 2.62 143.18 1.38 70.94 29.68 0.91 RC13-140 1-2 1260 2.87 -87.75 2246 4.18 114.52 1.39 124.92 16.92 0.27 RC13-140 1-2 1260 2.87 -87.75 2246 4.14 1370.92 1.32 815.88 41.89 0.60 RC13-140 1-2 1260 2.87 -87.75 2246 2.80 76.74 1.40 -999 17.90 1.34 RC13-140 1-2 1260 2.87 -87.75 2246 5.07 2557.38 1.39 -999 13.06 0.20 sample discarded, high Mn (>1500 micromol/mol) RC13-140 1-2 1260 2.87 -87.75 2246 4.47 763.80 1.42 344.51 13.67 3.98 RC13-140 1-2 1260 2.87 -87.75 2246 2.45 80.73 1.37 95.68 8.07 1.97 RC13-140 1-2 1260 2.87 -87.75 2246 4.41 49.43 1.41 432.01 -999 0.16 RC13-140 1-2 1260 2.87 -87.75 2246 2.58 232.87 1.40 55.68 21.76 1.02 RC13-140 1-2 1260 2.87 -87.75 2246 3.15 71.94 1.41 202.58 17.69 0.31 RC13-140 1-2 1260 2.87 -87.75 2246 5.77 139.28 1.40 248.02 -999 0.07 sample discarded, mass CaCO3 less than 0.1 micrograms RC13-140 1-2 1260 2.87 -87.75 2246 2.73 41.70 1.39 18.35 2.50 2.23 RC13-140 1-2 1260 2.87 -87.75 2246 2.85 51.55 1.41 32.30 5.09 1.54 RC13-140 1-2 1260 2.87 -87.75 2246 3.25 34.18 1.35 67.27 6.64 0.75 RC13-140 1-2 1260 2.87 -87.75 2246 -999 4810.71 -999 571965.75 35034.80 0.00 sample discarded, mass CaCO3 less than 0.1 micrograms RC13-140 1-2 1260 2.87 -87.75 2246 2.75 317.41 1.39 269.80 53.16 0.22 RC13-140 1-2 1260 2.87 -87.75 2246 2.81 131.88 1.43 8.61 18.43 4.53 RC13-140 1-2 1260 2.87 -87.75 2246 3.26 226.79 1.42 61.75 77.67 2.06 RC13-140 1-2 1260 2.87 -87.75 2246 2.37 196.90 1.46 40.91 27.09 2.07 RC13-140 1-2 1260 2.87 -87.75 2246 2.48 69.36 1.35 33.75 26.29 0.71 RC13-140 1-2 1260 2.87 -87.75 2246 3.00 144.02 1.40 21.10 21.59 2.93 RC13-140 1-2 1260 2.87 -87.75 2246 14.67 25.28 1.29 2728.88 22.41 0.02 sample discarded, mass CaCO3 less than 0.1 micrograms RC13-140 1-2 1260 2.87 -87.75 2246 10.72 195.60 1.37 1039.74 85.95 0.78 sample discarded, high Mg (>10 mmol/mol) RC13-140 1-2 1260 2.87 -87.75 2246 3.05 415.90 1.34 10.45 17.35 4.34 RC13-140 1-2 1260 2.87 -87.75 2246 11.06 67.73 1.34 1663.98 131.36 0.10 sample discarded, mass CaCO3 less than 0.1 micrograms RC13-140 1-2 1260 2.87 -87.75 2246 3.79 448.15 1.44 85.37 80.94 3.42 RC13-140 1-2 1260 2.87 -87.75 2246 2090.76 237.26 4.98 353396.05 20721.72 0.00 sample discarded, mass CaCO3 less than 0.1 micrograms RC13-140 1-2 1260 2.87 -87.75 2246 8.92 60.51 1.36 1262.38 106.16 0.06 sample discarded, mass CaCO3 less than 0.1 micrograms RC13-140 1-2 1260 2.87 -87.75 2246 2272.35 12039.34 1.40 2200547.35 35643.86 0.00 sample discarded, mass CaCO3 less than 0.1 micrograms RC13-140 1-2 1260 2.87 -87.75 2246 8.40 9223.58 1.43 210.06 177.83 3.17 sample discarded, high Mn (>1500 micromol/mol) RC13-140 1-2 1260 2.87 -87.75 2246 719.10 6620.01 1.94 412567.67 106962.17 0.00 sample discarded, mass CaCO3 less than 0.1 micrograms RC13-140 1-2 1260 2.87 -87.75 2246 2.40 67.50 1.40 30.13 15.71 1.59 RC13-140 1-2 1260 2.87 -87.75 2246 176.86 197.22 1.09 6924.18 3277.49 0.01 sample discarded, mass CaCO3 less than 0.1 micrograms RC13-140 1-2 1260 2.87 -87.75 2246 1775.87 2974.77 1.00 -999 -999 0.00 sample discarded, mass CaCO3 less than 0.1 micrograms RC13-140 1-2 1260 2.87 -87.75 2246 3.78 354.67 1.36 155.54 80.34 2.49 RC13-140 2-3 1260 2.87 -87.75 2246 50.73 38.94 -999 58842.07 -999 0.01 sample discarded, mass CaCO3 less than 0.1 micrograms RC13-140 2-3 1260 2.87 -87.75 2246 2.50 75.98 1.32 -999 2.95 3.77 RC13-140 2-3 1260 2.87 -87.75 2246 3.50 788.86 1.34 5.13 22.23 2.51 RC13-140 2-3 1260 2.87 -87.75 2246 3.33 326.28 1.36 -999 13.24 1.46 RC13-140 2-3 1260 2.87 -87.75 2246 1518.45 8.03 -999 368944.47 4013.51 0.00 sample discarded, mass CaCO3 less than 0.1 micrograms RC13-140 2-3 1260 2.87 -87.75 2246 4.01 2587.02 1.40 1682.95 101.33 1.37 sample discarded, high Al (>1000 micromol/mol) RC13-140 2-3 1260 2.87 -87.75 2246 3.66 944.16 1.41 6.63 42.56 3.18 RC13-140 2-3 1260 2.87 -87.75 2246 4.26 2036.84 1.39 22.11 71.18 0.97 sample discarded, high Mn (>1500 micromol/mol) RC13-140 2-3 1260 2.87 -87.75 2246 5.57 3478.71 1.35 266.02 52.06 0.34 sample discarded, high Mn (>1500 micromol/mol) RC13-140 2-3 1260 2.87 -87.75 2246 3.63 1741.84 1.25 -999 24.77 0.41 sample discarded, high Mn (>1500 micromol/mol) RC13-140 2-3 1260 2.87 -87.75 2246 2.49 85.05 1.27 -999 201.15 0.24 RC13-140 2-3 1260 2.87 -87.75 2246 5.09 152.54 1.29 905.83 56.51 0.24 RC13-140 2-3 1260 2.87 -87.75 2246 4.82 2224.25 1.36 183.11 31.80 0.64 sample discarded, high Mn (>1500 micromol/mol) RC13-140 2-3 1260 2.87 -87.75 2246 185.42 316.39 1.17 31330.35 3502.50 0.06 sample discarded, mass CaCO3 less than 0.1 micrograms RC13-140 2-3 1260 2.87 -87.75 2246 2.83 2614.23 1.39 140.52 45.95 1.60 sample discarded, high Mn (>1500 micromol/mol) RC13-140 2-3 1260 2.87 -87.75 2246 9.62 55.89 1.37 1728.47 9.49 0.13 sample discarded, high Al (>1000 micromol/mol) RC13-140 1-2 1260 2.87 -87.75 2246 5.02 766.50 1.44 389.07 934.56 7.17 RC13-140 1-2 1260 2.87 -87.75 2246 841.96 2930.91 1.30 234317.12 9366.18 0.00 sample discarded, mass CaCO3 less than 0.1 micrograms RC13-140 1-2 1260 2.87 -87.75 2246 4.79 51.23 1.39 570.15 67.55 0.32 RC13-140 1-2 1260 2.87 -87.75 2246 3.72 229.83 1.28 418.75 58.31 0.50 RC13-140 1-2 1260 2.87 -87.75 2246 15.26 78.91 1.34 2880.87 22.25 0.08 sample discarded, mass CaCO3 less than 0.1 micrograms RC13-140 1-2 1260 2.87 -87.75 2246 8.16 7757.07 1.37 1445.57 137.47 0.90 sample discarded, high Al (>1000 micromol/mol) RC13-140 1-2 1260 2.87 -87.75 2246 6.59 15.37 1.36 439.30 -999 0.23 RC13-140 1-2 1260 2.87 -87.75 2246 12.14 78.69 1.35 3041.63 67.00 0.08 sample discarded, mass CaCO3 less than 0.1 micrograms RC13-140 1-2 1260 2.87 -87.75 2246 4.48 334.92 1.42 230.65 11.79 1.83 RC13-140 1-2 1260 2.87 -87.75 2246 2.15 265.03 1.36 56.41 41.34 2.84 RC13-140 1-2 1260 2.87 -87.75 2246 9.06 50.79 1.42 1423.68 138.58 0.13 sample discarded, high Al (>1000 micromol/mol) RC13-140 1-2 1260 2.87 -87.75 2246 3.27 96.32 1.46 57.82 23.22 5.39 RC13-140 1-2 1260 2.87 -87.75 2246 3.11 101.07 1.39 59.74 16.52 4.17 OC73-1-2 0-1 4516 -7.28 -86.12 3200 3.14 2.58 1.43 12.89 18.79 0.46 OC73-1-2 0-1 4516 -7.28 -86.12 3200 3.03 2.70 1.42 47.20 42.70 1.31 OC73-1-2 0-1 4516 -7.28 -86.12 3200 3.52 1.51 1.50 27.51 27.88 1.40 OC73-1-2 0-1 4516 -7.28 -86.12 3200 3.79 5.40 1.33 48.91 21.43 0.50 OC73-1-2 0-1 4516 -7.28 -86.12 3200 2.49 1.23 1.46 181.27 27.42 1.12 OC73-1-2 0-1 4516 -7.28 -86.12 3200 3.29 0.52 1.45 7.26 20.48 2.41 OC73-1-2 0-1 4516 -7.28 -86.12 3200 4.65 1.15 1.46 7.03 13.05 0.81 OC73-1-2 0-1 4516 -7.28 -86.12 3200 3.44 2.26 1.44 31.97 24.17 3.50 OC73-1-2 0-1 4516 -7.28 -86.12 3200 4.10 2.68 1.50 645.59 133.16 2.42 OC73-1-2 0-1 4516 -7.28 -86.12 3200 2.79 -999 1.43 235.49 57.67 0.37 OC73-1-2 0-1 4516 -7.28 -86.12 3200 9.15 -999 1.46 809.74 62.22 0.06 sample discarded, mass CaCO3 less than 0.1 micrograms OC73-1-2 0-1 4516 -7.28 -86.12 3200 13.19 -999 1.47 1587.39 165.45 0.02 sample discarded, mass CaCO3 less than 0.1 micrograms OC73-1-2 0-1 4516 -7.28 -86.12 3200 3.74 -999 1.36 112.89 61.17 1.30 OC73-1-2 0-1 4516 -7.28 -86.12 3200 4.58 0.29 1.42 1656.84 94.10 1.05 sample discarded, high Al (>1000 micromol/mol) OC73-1-2 0-1 4516 -7.28 -86.12 3200 3.52 3.99 1.44 19.68 36.16 4.28 OC73-1-2 0-1 4516 -7.28 -86.12 3200 2.63 -999 1.37 31.67 10.77 0.37 OC73-1-2 0-1 4516 -7.28 -86.12 3200 4.06 -999 1.48 -999 -999 0.24 OC73-1-2 0-1 4516 -7.28 -86.12 3200 2.28 1.54 1.40 41.29 55.90 3.10 OC73-1-2 0-1 4516 -7.28 -86.12 3200 2.77 -999 1.40 79.53 889.55 0.35 OC73-1-2 0-1 4516 -7.28 -86.12 3200 6.84 -999 1.45 3462.42 -999 0.06 sample discarded, mass CaCO3 less than 0.1 micrograms OC73-1-2 0-1 4516 -7.28 -86.12 3200 3.57 -999 1.35 410.87 8.14 0.12 OC73-1-2 0-1 4516 -7.28 -86.12 3200 3.44 9.82 1.43 21.59 74.31 5.77 OC73-1-2 0-1 4516 -7.28 -86.12 3200 2.81 1.10 1.47 42.66 36.42 2.21 OC73-1-2 0-1 4516 -7.28 -86.12 3200 16.89 53.55 1.37 72.25 280.10 1.26 sample discarded, high Mg (>10 mmol/mol) OC73-1-2 0-1 4516 -7.28 -86.12 3200 2.83 -999 1.39 53.97 15.87 1.43 OC73-1-2 0-1 4516 -7.28 -86.12 3200 3.46 1.48 1.40 50.55 20.68 1.67 OC73-1-2 0-1 4516 -7.28 -86.12 3200 3.58 1.00 1.33 49.07 13.33 1.84 OC73-1-2 0-1 4516 -7.28 -86.12 3200 3.20 10.96 1.43 -999 107.00 7.05 OC73-1-2 0-1 4516 -7.28 -86.12 3200 2.65 0.50 1.43 35.68 40.07 5.18 OC73-1-2 0-1 4516 -7.28 -86.12 3200 2.83 -999 1.44 56.90 42.47 5.65 OC73-1-2 0-1 4516 -7.28 -86.12 3200 -999 -999 1.04 -999 -999 0.01 sample discarded, mass CaCO3 less than 0.1 micrograms OC73-1-2 0-1 4516 -7.28 -86.12 3200 6.33 58.38 1.39 539.77 71.63 0.07 sample discarded, mass CaCO3 less than 0.1 micrograms OC73-1-2 0-1 4516 -7.28 -86.12 3200 4.23 2.47 1.45 261.37 35.80 0.96 OC73-1-2 0-1 4516 -7.28 -86.12 3200 2.79 9.12 1.46 12.31 149.31 5.13 OC73-1-2 0-1 4516 -7.28 -86.12 3200 6.12 58.14 1.37 996.30 224.29 0.04 sample discarded, mass CaCO3 less than 0.1 micrograms OC73-1-2 0-1 4516 -7.28 -86.12 3200 3.16 8.15 1.37 69.03 83.43 3.67 OC73-1-2 0-1 4516 -7.28 -86.12 3200 9.91 27.00 1.36 927.34 178.36 0.23 sample discarded, temperature >3 standard deviations away from mean OC73-1-2 0-1 4516 -7.28 -86.12 3200 7.35 27.22 1.31 4917.83 370.55 0.15 sample discarded, high Al (>1000 micromol/mol) OC73-1-2 0-1 4516 -7.28 -86.12 3200 3.53 3.02 1.43 11.95 41.78 4.54 OC73-1-2 0-1 4516 -7.28 -86.12 3200 3.80 0.11 1.40 13.36 37.58 2.98 OC73-1-2 0-1 4516 -7.28 -86.12 3200 2.28 0.27 1.39 8.12 68.65 2.91 OC73-1-2 0-1 4516 -7.28 -86.12 3200 2.33 -999 1.35 156.94 27.25 0.64 OC73-1-2 0-1 4516 -7.28 -86.12 3200 3.12 0.65 1.43 -999 35.08 1.95 OC73-1-2 0-1 4516 -7.28 -86.12 3200 3.37 1.12 1.39 1.19 60.52 1.47 OC73-1-2 0-1 4516 -7.28 -86.12 3200 1.76 6.48 1.40 23.35 143.22 1.60 OC73-1-2 0-1 4516 -7.28 -86.12 3200 -999 41.53 1.86 -999 372.96 0.00 sample discarded, mass CaCO3 less than 0.1 micrograms OC73-1-2 0-1 4516 -7.28 -86.12 3200 3.75 24.65 1.38 69.47 56.85 2.35 OC73-1-2 0-1 4516 -7.28 -86.12 3200 3.17 3.64 1.45 93.03 20.22 1.53 OC73-1-2 0-1 4516 -7.28 -86.12 3200 -999 -999 0.32 -999 -999 0.00 sample discarded, mass CaCO3 less than 0.1 micrograms OC73-1-2 0-1 4516 -7.28 -86.12 3200 2.37 6.72 1.43 38.80 27.85 4.34 OC73-1-2 0-1 4516 -7.28 -86.12 3200 2206.46 594.72 1.50 -999 -999 0.00 sample discarded, mass CaCO3 less than 0.1 micrograms OC73-1-2 0-1 4516 -7.28 -86.12 3200 4.96 12.25 1.39 578.40 21.72 0.39 OC73-1-2 0-1 4516 -7.28 -86.12 3200 2.49 5.41 1.47 36.94 23.53 4.46 OC73-1-2 0-1 4516 -7.28 -86.12 3200 3.15 5.22 1.36 46.78 20.66 2.47 OC73-1-2 0-1 4516 -7.28 -86.12 3200 3.75 5.84 1.40 263.36 19.13 0.60 OC73-1-2 0-1 4516 -7.28 -86.12 3200 3.92 22.42 1.43 38.41 25.98 5.71 OC73-1-2 0-1 4516 -7.28 -86.12 3200 8.28 11.13 1.31 1844.78 131.30 0.08 sample discarded, mass CaCO3 less than 0.1 micrograms OC73-1-2 0-1 4516 -7.28 -86.12 3200 2.79 1.24 1.34 211.83 10.58 0.86 OC73-1-2 0-1 4516 -7.28 -86.12 3200 3.50 27.10 1.46 304.26 58.03 3.22 OC73-1-2 0-1 4516 -7.28 -86.12 3200 3.81 19.99 1.45 338.72 19.74 4.62 OC73-1-2 0-1 4516 -7.28 -86.12 3200 3.53 17.31 1.50 300.76 21.34 0.60 OC73-1-2 0-1 4516 -7.28 -86.12 3200 2.80 8.38 1.43 92.21 37.55 4.98 OC73-1-2 0-1 4516 -7.28 -86.12 3200 5.09 1.67 1.42 399.99 30.97 0.48 OC73-1-2 0-1 4516 -7.28 -86.12 3200 4780.81 3455.57 2.12 -999 -999 0.00 sample discarded, mass CaCO3 less than 0.1 micrograms OC73-1-2 0-1 4516 -7.28 -86.12 3200 4.50 5.53 1.43 51.82 23.55 4.07 OC73-1-2 0-1 4516 -7.28 -86.12 3200 3.11 20.56 1.38 47.43 70.62 4.98 OC73-1-2 0-1 4516 -7.28 -86.12 3200 3.24 161.86 1.45 79.15 83.59 1.65 OC73-1-2 0-1 4516 -7.28 -86.12 3200 3.88 6.04 1.44 119.16 12.41 1.28 OC73-1-2 0-1 4516 -7.28 -86.12 3200 5.25 -999 1.45 870.10 14.69 0.36 OC73-1-2 0-1 4516 -7.28 -86.12 3200 3.46 3.83 1.44 41.17 5.54 2.22 OC73-1-2 0-1 4516 -7.28 -86.12 3200 4.00 20.03 1.37 30.56 20.73 1.66 OC73-1-2 0-1 4516 -7.28 -86.12 3200 2.52 12.26 1.41 3.89 12.74 4.39 OC73-1-2 0-1 4516 -7.28 -86.12 3200 3.46 5.92 1.43 20.44 8.44 2.08 OC73-1-2 0-1 4516 -7.28 -86.12 3200 4.11 33.38 1.43 80.95 18.13 0.96 OC73-1-2 0-1 4516 -7.28 -86.12 3200 2.81 -999 1.37 146.57 34.15 0.38 OC73-1-2 0-1 4516 -7.28 -86.12 3200 3.35 4.48 1.53 33.45 10.05 4.63 OC73-1-2 0-1 4516 -7.28 -86.12 3200 3.52 55.65 1.41 33.94 21.43 2.89 OC73-1-2 0-1 4516 -7.28 -86.12 3200 7.31 1.56 1.40 2188.37 1371.90 0.58 sample discarded, high Al (>1000 micromol/mol) OC73-1-2 0-1 4516 -7.28 -86.12 3200 3.13 4.26 1.53 10.51 25.86 3.71 OC73-1-2 0-1 4516 -7.28 -86.12 3200 4.10 -999 1.37 1815.86 10.90 1.40 sample discarded, high Al (>1000 micromol/mol) OC73-1-2 0-1 4516 -7.28 -86.12 3200 3.32 -999 1.36 75.79 21.57 1.22 OC73-1-2 0-1 4516 -7.28 -86.12 3200 3.03 -999 1.37 208.91 21.93 1.58 OC73-1-2 0-1 4516 -7.28 -86.12 3200 4.36 -999 1.43 554.22 15.92 1.55 OC73-1-2 0-1 4516 -7.28 -86.12 3200 4.64 -999 1.44 125.36 22.99 2.53 OC73-1-2 0-1 4516 -7.28 -86.12 3200 3.08 8.82 1.36 -999 45.80 5.37 OC73-1-2 0-1 4516 -7.28 -86.12 3200 3.43 -999 1.35 116.68 12.71 1.29 OC73-1-2 0-1 4516 -7.28 -86.12 3200 2.18 5.93 1.39 49.49 36.81 3.73 OC73-1-2 0-1 4516 -7.28 -86.12 3200 2.62 7.96 1.37 42.80 47.10 8.61 OC73-1-2 0-1 4516 -7.28 -86.12 3200 3.14 31.20 1.36 15.19 122.15 3.61 OC73-1-2 0-1 4516 -7.28 -86.12 3200 3.21 -999 1.35 34.18 4.73 1.89 OC73-1-2 0-1 4516 -7.28 -86.12 3200 4.15 2.81 1.45 63.67 14.44 1.56 OC73-1-2 0-1 4516 -7.28 -86.12 3200 10.18 70.41 1.47 18317.80 4745.06 0.12 sample discarded, high Mg (>10 mmol/mol) RC23-22 0-1 2020 1 -83.62 3215 3.14 523.59 1.48 119.79 8.51 1.47 RC23-22 0-1 2020 1 -83.62 3215 3.45 1143.10 1.34 4105.04 31.35 0.17 sample discarded, high Al (>1000 micromol/mol) RC23-22 0-1 2020 1 -83.62 3215 2.86 1148.78 1.39 542.18 0.45 0.42 RC23-22 2-3 2020 1 -83.62 3215 4.22 459.38 1.44 -999 1.60 8.18 RC23-22 2-3 2020 1 -83.62 3215 3.87 473.68 1.43 20.14 8.61 12.16 RC23-22 2-3 2020 1 -83.62 3215 3.00 689.07 1.40 0.34 4.59 6.38 RC23-22 2-3 2020 1 -83.62 3215 3.28 223.74 1.40 14.24 5.87 6.09 RC23-22 2-3 2020 1 -83.62 3215 2.77 902.80 1.46 25.58 10.68 4.81 RC23-22 2-3 2020 1 -83.62 3215 3.12 1105.70 1.42 62.39 10.93 7.01 RC23-22 2-3 2020 1 -83.62 3215 2.28 646.89 1.48 71.84 3.87 2.13 RC23-22 2-3 2020 1 -83.62 3215 4.27 657.57 1.43 107.14 12.48 0.69 RC23-22 2-3 2020 1 -83.62 3215 3.02 652.40 1.39 320.87 9.12 1.23 RC23-22 2-3 2020 1 -83.62 3215 3.78 677.33 1.38 32.15 7.78 1.62 RC23-22 2-3 2020 1 -83.62 3215 3.04 1121.17 1.45 236.95 18.24 1.30 RC23-22 2-3 2020 1 -83.62 3215 3.22 603.64 1.44 9.38 4.60 12.99 RC23-22 2-3 2020 1 -83.62 3215 3.01 743.99 1.41 129.44 6.35 3.44 RC23-22 2-3 2020 1 -83.62 3215 3.53 850.40 1.42 157.78 13.24 2.31 RC23-22 2-3 2020 1 -83.62 3215 4.61 359.10 1.42 364.09 6.60 0.28 RC23-22 2-3 2020 1 -83.62 3215 7.60 1052.62 1.44 5.88 6.11 1.68 sample discarded, temperature >3 standard deviations away from mean RC23-22 2-3 2020 1 -83.62 3215 3.26 767.01 1.42 129.54 5.66 3.12 RC23-22 2-3 2020 1 -83.62 3215 3.33 803.53 1.42 34.97 9.16 7.18 RC23-22 2-3 2020 1 -83.62 3215 3.16 461.18 1.39 17.83 11.10 4.57 RC23-22 2-3 2020 1 -83.62 3215 3.56 461.14 1.34 22.91 6.61 1.49 RC23-22 2-3 2020 1 -83.62 3215 3.21 526.90 1.45 20.58 14.33 6.50 RC23-22 2-3 2020 1 -83.62 3215 3.05 706.18 1.40 27.48 9.24 8.66 RC23-22 2-3 2020 1 -83.62 3215 3.41 346.77 1.32 28.27 2.41 1.11 RC23-22 2-3 2020 1 -83.62 3215 4.47 612.17 1.51 172.90 136.53 6.86 RC23-22 2-3 2020 1 -83.62 3215 3.47 791.81 1.44 242.18 35.83 4.19 RC23-22 2-3 2020 1 -83.62 3215 3.22 706.22 1.39 22.12 20.62 9.20 RC23-22 2-3 2020 1 -83.62 3215 2.89 729.33 1.36 182.09 3.31 0.62 RC23-22 2-3 2020 1 -83.62 3215 3.72 230.04 1.38 8.42 4.50 6.63 RC23-22 2-3 2020 1 -83.62 3215 2.73 625.69 1.38 21.97 9.60 2.88 RC23-22 2-3 2020 1 -83.62 3215 2.51 1560.49 1.38 30.70 23.30 1.46 sample discarded, high Mn (>1500 micromol/mol) RC23-22 2-3 2020 1 -83.62 3215 3.99 2071.15 1.41 1506.29 59.03 0.20 sample discarded, high Al (>1000 micromol/mol) RC23-22 2-3 2020 1 -83.62 3215 2.80 706.67 1.38 28.76 3.19 1.63 RC23-22 2-3 2020 1 -83.62 3215 2.71 356.01 1.44 57.35 3.58 3.39 RC23-22 2-3 2020 1 -83.62 3215 3.60 643.11 1.46 101.26 4.81 1.80 RC23-22 2-3 2020 1 -83.62 3215 4.24 92.00 1.43 32.20 18.14 10.95 RC23-22 2-3 2020 1 -83.62 3215 3.88 880.10 1.46 1.36 6.70 19.56 RC23-22 2-3 2020 1 -83.62 3215 4.44 98.82 1.38 119.98 15.09 2.39 RC23-22 2-3 2020 1 -83.62 3215 3.20 704.69 1.35 50.53 1.35 0.57 RC23-22 2-3 2020 1 -83.62 3215 -999 374.93 0.62 -999 2493.63 0.00 sample discarded, mass CaCO3 less than 0.1 micrograms RC23-22 2-3 2020 1 -83.62 3215 3.73 1288.02 1.40 651.53 1.53 0.29 RC23-22 2-3 2020 1 -83.62 3215 3.42 326.78 1.38 10.02 3.58 8.03 RC23-22 2-3 2020 1 -83.62 3215 4.13 1034.26 1.36 11.27 12.22 2.50 RC23-22 2-3 2020 1 -83.62 3215 3.88 223.22 1.45 56.67 6.12 6.85 RC23-22 0-1 2020 1 -83.62 3215 2.60 190.02 1.36 99.22 7.08 1.73 RC23-22 0-1 2020 1 -83.62 3215 2.59 158.67 1.38 34.87 -999 3.11 RC23-22 1-2 2020 1 -83.62 3215 3.19 201.07 1.44 15.55 0.29 9.02 RC23-22 1-2 2020 1 -83.62 3215 3.12 217.39 1.42 48.81 3.48 6.10 RC23-22 1-2 2020 1 -83.62 3215 3.21 139.91 1.49 29.21 0.04 5.18 RC23-22 1-2 2020 1 -83.62 3215 3.91 109.92 1.48 57.07 0.29 2.75 RC23-22 2-3 2020 1 -83.62 3215 3.44 231.96 1.45 96.40 60.03 1.54 RC23-22 2-3 2020 1 -83.62 3215 3.06 190.42 1.39 170.92 0.22 0.81 RC23-22 2-3 2020 1 -83.62 3215 2.90 459.56 1.42 27.14 1.44 8.07 RC23-22 2-3 2020 1 -83.62 3215 3.60 362.22 1.44 244.96 11.98 1.43 RC23-22 2-3 2020 1 -83.62 3215 3.98 176.63 1.44 32.33 3.13 6.41 RC23-22 2-3 2020 1 -83.62 3215 3.76 396.60 1.46 276.19 22.40 1.77 RC23-22 2-3 2020 1 -83.62 3215 3.30 200.06 1.42 146.80 -999 1.13 RC23-22 2-3 2020 1 -83.62 3215 4.15 581.00 1.48 339.55 25.13 3.17 RC23-22 2-3 2020 1 -83.62 3215 3.76 665.40 1.39 78.78 5.05 1.64 RC23-22 2-3 2020 1 -83.62 3215 2.82 684.35 1.38 129.66 11.36 1.41 RC23-22 2-3 2020 1 -83.62 3215 8.74 4560.76 1.38 2172.26 190.30 0.46 sample discarded, high Al (>1000 micromol/mol)