# Jarvis Island and Nikumaroro Island Coral Trace Metal Data #----------------------------------------------------------------------- # World Data Service for Paleoclimatology, Boulder # and # NOAA Paleoclimatology Program #----------------------------------------------------------------------- # Template Version 4.0 # Encoding: UTF-8 # NOTE: Please cite original publication, NOAA Landing Page URL, dataset and publication DOIs (where available), and date accessed when using downloaded data. # If there is no publication information, please cite investigator, study title, NOAA Landing Page URL, and date accessed. # # Description/Documentation lines begin with '#' followed by a space # Data lines have no '#' # # NOAA_Landing_Page: https://www.ncei.noaa.gov/access/paleo-search/study/38419 # Landing_Page_Description: NOAA Landing Page of this file's parent study, which includes all study metadata. # # Study_Level_JSON_Metadata: https://www.ncei.noaa.gov/pub/data/metadata/published/paleo/json/noaa-coral-38419.json # Study_Level_JSON_Description: JSON metadata of this data file's parent study, which includes all study metadata. # # Data_Type: Corals and Sclerosponges # # Dataset_DOI: 10.25921/dxj1-dt11 # # Science_Keywords: #--------------------------------------- # Resource_Links # # Data_Download_Resource: https://www.ncei.noaa.gov/pub/data/paleo/coral/central_pacific/mollica2023/mollica2023-f4.txt # Data_Download_Description: NOAA Template File; F4 Sr/Ca, U/Ca Data # #--------------------------------------- # Contribution_Date # Date: 2023-08-14 #--------------------------------------- # File_Last_Modified_Date # Date: 2025-04-30 #--------------------------------------- # Title # Study_Name: Jarvis Island and Nikumaroro Island Coral Trace Metal Data #--------------------------------------- # Investigators # Investigators: Mollica, Nathaniel (https://orcid.org/0000-0003-4751-8061); Cohen, Anne (https://orcid.org/0000-0002-5570-780X); Horton, Forrest (https://orcid.org/0000-0001-9524-8874); Oppo, Delia (https://orcid.org/0000-0003-2946-5904); Solow, Andrew; McGee, David #--------------------------------------- # Description_Notes_and_Keywords # Description: Provided Keywords: Sea Surface Temperature Reconstruction #--------------------------------------- # Publication # Authors: Mollica, N.R., A.L. Cohen, F. Horton, Delia W. Oppo, Andrew S. Solow, David McGee # Published_Date_or_Year: 2023 # Published_Title: Capturing Equatorial Pacific Variability with multivariate Sr-U Coral Thermometry # Journal_Name: Paleoceanography and Paleoclimatology # Volume: 38 # Edition: # Issue: 10 # Pages: # Report_Number: e2022PA004508 # DOI: 10.1029/2022PA004508 # Online_Resource: # Full_Citation: # Abstract: Sr-U, a coral-based paleothermometer, corrects for the effects of Rayleigh Fractionation on Sr/Ca by regressing multiple, paired U/Ca and Sr/Ca values. Prior applications of Sr-U captured mean annual sea surface temperatures (SSTs), inter-annual variability, and long-term trends. However, because many Sr/Ca-U/Ca pairs are needed for a single Sr-U value as originally formulated, the temporal resolution of the proxy is typically limited to 1 year. Here, we address this limitation by applying laser ablation inductively coupled plasma mass spectrometry (LA-ICPMS) to three Porites colonies from Jarvis and Nikumaroro Islands in the central equatorial Pacific (CEP), generating ∼25 Sr/Ca-U/Ca pairs per month of skeletal growth. Both Sr/Ca and U/Ca vary significantly over small (sub-mm) length scales and support the calculation of Sr-U values using the original regression method. Over the represented temperature range of 24–31°C, the Sr/Ca-U/Ca-SST relationships are nonlinear, a finding consistent with predictions of the Rayleigh model. To reflect this non-linearity, we developed a calibration using multivariate nonlinear regression. The multivariate, three-coral calibration was applied to 20 years of monthly resolved Sr/Ca and U/Ca of a coral interval not included in the calibration, yielding RMSE = 0.73°C and r2 = 0.85 (p < 0.05; df = 256). The multivariate calibration performed significantly better than Sr/Ca alone (r2 = 0.28). Applying the new calibration to a subfossil Porites from Kiritimati Atoll, CEP (2200 Before Present) yields equivalent phase and amplitude of interannual variability, but water temperatures ~1.6°C cooler than they are in this region today. #--------------------------------------- # Funding_Agency # Funding_Agency_Name: US National Science Foundation # Grant: OCE-MGG 2016133, NSF OCE-BIO 2049567 #--------------------------------------- # Site_Information # Site_Name: Jarvis Island F4 # Location: Central Pacific Ocean # Northernmost_Latitude: 1.8 # Southernmost_Latitude: 1.8 # Easternmost_Longitude: -157.48 # Westernmost_Longitude: -157.48 # Elevation_m: 3 #--------------------------------------- # Data_Collection # Collection_Name: F4 Sr/Ca, U/Ca Mollica2023 # First_Year: 2158 # Last_Year: 2158 # Time_Unit: calendar year before present # Core_Length_m: 0.15 # Parameter_Keywords: trace metals, chemistry # Notes: #--------------------------------------- # Chronology_Information # Chronology: Uranium-Thorium # Chronology_Download_Resource: https://www.ncei.noaa.gov/pub/data/paleo/templates/noaa-wds-paleo-uth-terms.csv # Chronology_Download_Description: Uranium-Thorium terms and definitions. # Chronology_Notes: Reported errors for 238U and 232Th concentrations are estimated to be ±1% due to uncertainties in spike concentration; analytical uncertainties are smaller. # Rejection_Rationale: # 238U_Decay_Constant: 1.55125 x 10-10 yr-1 (Jaffey et al., 1971) # 234U_Decay_Constant: Cheng et al. (2013) # 230Th_Decay_Constant: Cheng et al. (2013) # Initial_230Th/232Th: (4.4±2.2) x 10-6 # Initial_230Th/232Th_Method: # Age_Model_Method: # Missing_Values: na # Chronology_Table: # samp_id 238U_ppb 238U_2s_ppb 232Th_ppt 232Th_2s_ppt d234U_meas_permil d234U_meas_2s_permil 230Th_238U_act 230Th_238U_act_2s 230Th_232Th_atom_ppm 230Th_232Th_atom_2s_ppm age_uncorr_BM age_uncorr_2s_yr age_corr_BM age_corr_2s_yr d234U_init_permil d234U_init_2s_permil age_corr_BP1950 age_corr_2s_yr # F4 2389 48 191 6 146 2 0.0232 0.00015 4599 102 2229 15 2227 15 147 2 2158 15 #--------------------------------------- # Variables # PaST_Thesaurus_Download_Resource: https://www.ncei.noaa.gov/access/paleo-search/skos/past-thesaurus.rdf # PaST_Thesaurus_Download_Description: Paleoenvironmental Standard Terms (PaST) Thesaurus terms, definitions, and relationships in SKOS format. # # Data variables follow that are preceded by "##" in columns one and two. # Variables list, one per line, shortname-tab-var components: what, material, error, units, seasonality, data type, detail, method, C or N for Character or Numeric data) # ## samp_num sample identification,,,,,corals and sclerosponges,,,N,Sample Number ## Offset notes,,,millimeter,,corals and sclerosponges,,,N,Distance from track center; submonthly ## Depth depth,,,millimeter,,corals and sclerosponges,,,N,depth from core top; submonthly ## Sr/Ca strontium/calcium,Porites sp.,,mole per mole,,corals and sclerosponges,,laser ablation; inductively-coupled plasma mass spectrometry,N,submonthly ## Sr/Ca_err strontium/calcium,Porites sp.,unspecified error,mole per mole,,corals and sclerosponges,,laser ablation; inductively-coupled plasma mass spectrometry,N,strontium/calcium measurement error; submonthly ## U/Ca uranium/calcium,Porites sp.,,mole per mole,,corals and sclerosponges,,laser ablation; inductively-coupled plasma mass spectrometry,N,submonthly ## U/Ca_err uranium/calcium,Porites sp.,unspecified error,mole per mole,,corals and sclerosponges,,laser ablation; inductively-coupled plasma mass spectrometry,N,uranium/calcium measurement error; submonthly #------------------------ # Data: # Data lines follow (have no #) # Data line format - tab-delimited text, variable short name as header # Missing_Values: NA samp_num Offset Depth Sr/Ca Sr/Ca_err U/Ca U/Ca_err 1 -0.0588 0.0000 9.58E-03 5.29E-04 1.60E-06 8.29E-08 2 0.2656 0.0539 9.22E-03 6.11E-04 1.38E-06 9.39E-08 3 1.4817 0.1213 9.21E-03 6.41E-04 1.30E-06 7.66E-08 4 -1.1605 0.1477 9.52E-03 5.07E-04 1.51E-06 7.19E-08 5 -0.0380 0.2335 9.53E-03 4.29E-04 1.48E-06 6.85E-08 6 1.7608 0.2404 9.34E-03 5.63E-04 1.42E-06 7.99E-08 7 0.2091 0.2734 9.30E-03 6.33E-04 1.43E-06 1.24E-07 8 1.4527 0.2791 9.14E-03 3.67E-04 1.37E-06 5.98E-08 9 -1.2205 0.3443 9.35E-03 7.26E-04 1.34E-06 7.95E-08 10 -1.1097 0.4145 9.50E-03 6.67E-04 1.23E-06 1.05E-07 11 1.4366 0.4756 9.31E-03 3.86E-04 1.47E-06 5.98E-08 12 -0.1802 0.5022 9.47E-03 3.79E-04 1.47E-06 8.75E-08 13 -1.2361 0.5197 9.20E-03 5.37E-04 1.19E-06 8.01E-08 14 1.1420 0.6550 9.01E-03 5.03E-04 1.24E-06 8.33E-08 15 -1.2925 0.6662 9.34E-03 5.14E-04 1.45E-06 7.27E-08 16 -0.1337 0.6821 9.33E-03 5.48E-04 1.30E-06 1.13E-07 17 1.6999 0.7651 9.28E-03 4.86E-04 1.41E-06 6.55E-08 18 2.0242 0.7709 9.34E-03 5.62E-04 1.41E-06 8.13E-08 19 -0.1790 0.8313 9.39E-03 4.68E-04 1.45E-06 5.83E-08 20 2.0220 0.8810 9.30E-03 4.75E-04 1.29E-06 7.98E-08 21 1.7602 0.8926 9.19E-03 5.54E-04 1.28E-06 9.64E-08 22 -1.2946 0.9023 9.63E-03 3.98E-04 1.46E-06 1.09E-07 23 -0.2264 0.9365 8.87E-03 5.68E-04 1.16E-06 6.60E-08 24 -1.3018 1.0115 9.15E-03 4.80E-04 1.20E-06 7.55E-08 25 1.4565 1.0293 8.84E-03 4.43E-04 1.12E-06 6.83E-08 26 2.1073 1.0539 9.06E-03 4.98E-04 1.11E-06 6.26E-08 27 1.7124 1.1009 9.25E-03 5.69E-04 1.25E-06 7.63E-08 28 -0.2490 1.1091 9.22E-03 6.29E-04 1.17E-06 7.79E-08 29 -1.6164 1.2325 9.04E-03 5.01E-04 1.06E-06 7.76E-08 30 0.5386 1.2444 9.14E-03 6.45E-04 1.09E-06 7.62E-08 31 -1.3407 1.2566 9.23E-03 4.77E-04 1.17E-06 8.00E-08 32 -0.2048 1.2751 9.16E-03 4.12E-04 1.16E-06 7.33E-08 33 0.4280 1.3812 8.72E-03 5.49E-04 1.03E-06 6.14E-08 34 -0.3448 1.3996 9.12E-03 4.18E-04 1.13E-06 7.24E-08 35 -1.8779 1.4141 9.48E-03 4.23E-04 1.36E-06 6.84E-08 36 1.9197 1.4278 8.99E-03 5.16E-04 9.85E-07 1.01E-07 37 -1.6852 1.4803 9.29E-03 4.60E-04 1.21E-06 6.93E-08 38 -1.1989 1.6051 9.22E-03 5.59E-04 1.17E-06 7.06E-08 39 1.6322 1.6120 9.02E-03 3.50E-04 1.11E-06 4.91E-08 40 -1.9258 1.6184 9.40E-03 5.34E-04 1.35E-06 6.26E-08 41 0.4692 1.6253 9.46E-03 6.23E-04 1.33E-06 6.48E-08 42 -1.7507 1.7400 9.42E-03 4.52E-04 1.28E-06 6.52E-08 43 0.0204 1.8376 9.22E-03 5.61E-04 1.16E-06 7.89E-08 44 0.2596 1.8436 9.35E-03 4.02E-04 1.28E-06 6.79E-08 45 1.5978 1.8740 9.27E-03 6.04E-04 1.22E-06 6.72E-08 46 -1.7683 1.9516 9.54E-03 3.88E-04 1.39E-06 7.81E-08 47 -0.0223 2.0507 9.27E-03 4.86E-04 1.32E-06 6.19E-08 48 -0.3828 2.0738 9.21E-03 5.48E-04 1.20E-06 7.47E-08 49 1.5721 2.0857 9.31E-03 5.07E-04 1.40E-06 7.12E-08 50 -1.8013 2.1514 9.15E-03 4.87E-04 1.19E-06 6.90E-08 51 -0.0408 2.1912 9.42E-03 6.35E-04 1.28E-06 7.74E-08 52 -2.0768 2.2154 9.07E-03 3.69E-04 1.17E-06 4.85E-08 53 1.7484 2.3744 9.44E-03 5.81E-04 1.32E-06 1.07E-07 54 -0.5977 2.4423 9.28E-03 5.04E-04 1.22E-06 9.34E-08 55 -1.4997 2.4500 9.26E-03 4.09E-04 1.30E-06 4.98E-08 56 -0.0944 2.4857 9.33E-03 7.04E-04 1.21E-06 1.15E-07 57 1.9628 2.5490 9.30E-03 5.25E-04 1.26E-06 8.00E-08 58 1.4051 2.5660 9.37E-03 6.50E-04 1.19E-06 8.23E-08 59 1.7172 2.5672 9.45E-03 6.70E-04 1.32E-06 1.21E-07 60 -1.4898 2.6088 9.09E-03 4.16E-04 1.17E-06 8.53E-08 61 -0.6268 2.6751 9.04E-03 3.96E-04 1.26E-06 6.84E-08 62 -1.5589 2.6825 9.28E-03 5.75E-04 1.26E-06 7.77E-08 63 1.7579 2.7522 9.02E-03 4.28E-04 1.07E-06 5.31E-08 64 -1.5076 2.8153 9.26E-03 3.82E-04 1.23E-06 7.87E-08 65 -0.6248 2.8331 9.18E-03 4.99E-04 1.28E-06 1.11E-07 66 -1.5933 2.9485 9.30E-03 4.50E-04 1.26E-06 6.46E-08 67 1.8484 2.9710 9.21E-03 5.90E-04 1.31E-06 9.04E-08 68 -0.7227 3.0396 9.34E-03 5.39E-04 1.27E-06 6.22E-08 69 -1.5660 3.1178 9.34E-03 4.31E-04 1.28E-06 6.74E-08 70 1.9384 3.1278 9.28E-03 6.07E-04 1.23E-06 8.00E-08 71 -0.3665 3.1637 9.41E-03 4.62E-04 1.40E-06 7.12E-08 72 -0.6142 3.1770 9.15E-03 4.67E-04 1.17E-06 6.38E-08 73 -1.6785 3.2597 9.40E-03 4.54E-04 1.42E-06 9.65E-08 74 1.8457 3.2622 9.35E-03 5.41E-04 1.44E-06 8.58E-08 75 1.4948 3.3880 9.28E-03 5.41E-04 1.32E-06 8.75E-08 76 -0.7078 3.3944 9.02E-03 2.26E-04 1.20E-06 7.13E-08 77 1.8546 3.4170 9.02E-03 5.63E-04 1.06E-06 1.29E-07 78 -1.6456 3.4519 9.28E-03 3.96E-04 1.30E-06 7.02E-08 79 1.8308 3.5827 9.57E-03 5.17E-04 1.47E-06 8.30E-08 80 -1.6999 3.6004 9.56E-03 3.43E-04 1.45E-06 7.30E-08 81 -1.0014 3.6108 9.31E-03 2.80E-04 1.31E-06 8.07E-08 82 1.9177 3.6605 8.80E-03 4.42E-04 1.05E-06 6.24E-08 83 -1.7303 3.7032 9.25E-03 5.93E-04 1.30E-06 8.57E-08 84 -0.2586 3.7542 9.67E-03 6.12E-04 1.37E-06 1.00E-07 85 -1.0398 3.8339 9.48E-03 2.69E-04 1.35E-06 6.93E-08 86 1.3791 3.9191 9.38E-03 3.19E-04 1.41E-06 5.39E-08 87 1.7744 3.9662 9.32E-03 5.10E-04 1.44E-06 9.38E-08 88 -1.2893 3.9782 9.14E-03 7.45E-04 1.17E-06 1.14E-07 89 -1.0415 4.0069 9.39E-03 4.13E-04 1.26E-06 9.44E-08 90 -1.7172 4.0279 9.47E-03 4.39E-04 1.29E-06 8.77E-08 91 -0.3166 4.0738 9.50E-03 3.66E-04 1.51E-06 6.90E-08 92 -1.8360 4.1159 8.87E-03 4.36E-04 1.00E-06 4.57E-08 93 -1.0940 4.2263 9.07E-03 3.93E-04 1.12E-06 6.03E-08 94 -1.3488 4.2357 9.54E-03 4.08E-04 1.26E-06 6.32E-08 95 -0.5530 4.2578 9.66E-03 5.66E-04 1.37E-06 9.21E-08 96 -1.7368 4.2825 9.30E-03 3.30E-04 1.17E-06 4.61E-08 97 1.2701 4.3190 9.70E-03 4.96E-04 1.39E-06 1.00E-07 98 -0.1423 4.3235 9.52E-03 1.96E-04 1.52E-06 6.96E-08 99 1.9614 4.3636 8.93E-03 6.16E-04 1.08E-06 7.15E-08 100 1.3689 4.4315 9.36E-03 6.62E-04 1.07E-06 1.07E-07 101 -1.3887 4.4398 9.42E-03 4.12E-04 1.39E-06 5.74E-08 102 -1.8848 4.5243 9.11E-03 4.51E-04 1.10E-06 5.09E-08 103 -1.7185 4.5741 9.30E-03 4.41E-04 1.17E-06 1.01E-07 104 1.7677 4.5766 8.90E-03 3.82E-04 1.08E-06 4.93E-08 105 1.9244 4.6026 9.35E-03 4.87E-04 1.25E-06 6.66E-08 106 -0.8183 4.6495 9.12E-03 4.58E-04 1.14E-06 6.49E-08 107 0.0227 4.7184 9.24E-03 3.96E-04 1.35E-06 5.97E-08 108 -0.9002 4.8527 9.35E-03 4.79E-04 1.14E-06 7.99E-08 109 1.9638 4.8547 9.32E-03 5.81E-04 1.26E-06 7.15E-08 110 -1.4845 4.8884 9.52E-03 5.59E-04 1.27E-06 9.03E-08 111 -0.0568 4.9385 9.59E-03 5.15E-04 1.32E-06 8.25E-08 112 2.1143 4.9930 9.32E-03 4.63E-04 1.20E-06 8.96E-08 113 1.7662 4.9947 9.31E-03 7.14E-04 1.36E-06 1.14E-07 114 -0.8284 5.0809 9.52E-03 3.84E-04 1.36E-06 6.69E-08 115 1.9575 5.0820 9.37E-03 4.46E-04 1.31E-06 8.40E-08 116 -1.7457 5.1620 9.43E-03 3.05E-04 1.30E-06 5.60E-08 117 0.1112 5.1734 9.43E-03 2.79E-04 1.27E-06 7.78E-08 118 1.7028 5.2984 9.41E-03 4.08E-04 1.35E-06 8.98E-08 119 -1.4997 5.3979 9.22E-03 4.41E-04 9.61E-07 8.94E-08 120 0.1793 5.4147 9.62E-03 6.84E-04 1.43E-06 7.37E-08 121 -1.7512 5.4612 9.43E-03 4.14E-04 1.16E-06 1.09E-07 122 1.7279 5.4618 9.50E-03 4.46E-04 1.45E-06 7.35E-08 123 0.0697 5.5545 9.28E-03 4.94E-04 1.12E-06 6.07E-08 124 1.6649 5.5805 9.62E-03 4.12E-04 1.38E-06 9.99E-08 125 -1.7756 5.6849 9.18E-03 5.75E-04 1.15E-06 7.91E-08 126 0.1552 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