# Seawater Sr/Ca in Florida and Around the World between 2016-2020 CE #----------------------------------------------------------------------- # World Data Service for Paleoclimatology, Boulder # and # NOAA Paleoclimatology Program #----------------------------------------------------------------------- # Template Version 4.0 # Encoding: UTF-8 # NOTE: Please cite original publication, NOAA Landing Page URL, dataset and publication DOIs (where available), and date accessed when using downloaded data. # If there is no publication information, please cite investigator, study title, NOAA Landing Page URL, and date accessed. # # Description/Documentation lines begin with '#' followed by a space # Data lines have no '#' # # NOAA_Landing_Page: https://www.ncei.noaa.gov/access/paleo-search/study/41080 # Landing_Page_Description: NOAA Landing Page of this file's parent study, which includes all study metadata. # # Study_Level_JSON_Metadata: https://www.ncei.noaa.gov/pub/data/metadata/published/paleo/json/noaa-coral-41080.json # Study_Level_JSON_Description: JSON metadata of this data file's parent study, which includes all study metadata. # # Data_Type: Corals and Sclerosponges # # Dataset_DOI: 10.25921/jd8r-nc90 # # Science_Keywords: biogeochemical cycles #--------------------------------------- # Resource_Links # # Data_Download_Resource: https://www.ncei.noaa.gov/pub/data/paleo/coral/multiregion/kilbourne2025/kilbourne2025-flgrid-srca.txt # Data_Download_Description: NOAA Template File; Florida Grid Sr/Ca Data # #--------------------------------------- # Contribution_Date # Date: 2025-03-13 #--------------------------------------- # File_Last_Modified_Date # Date: 2025-09-12 #--------------------------------------- # Title # Study_Name: Seawater Sr/Ca in Florida and Around the World between 2016-2020 CE #--------------------------------------- # Investigators # Investigators: Kilbourne, K.H.; Schijf, Johan; Hughes, Hunter P.; Khare, Agraj #--------------------------------------- # Description_Notes_and_Keywords # Description: Seawater Sr/Ca to complement coral-based paleoclimate efforts. The study spanned 2016-2020 in the Middle Florida Keys with the grid extending from shore to the forereef area about 6km offshore, along about 11km of coastline. Samples in Khare et al., 2022 were sampled collected by hand from the surface and at the bottom by diver in the winter and summer in the Florida Keys. Samples of opportunity were collected by hand from a variety of locations in the Pacific, Indian and Atlantic Oceans. Samples from Hughes et al., 2025 were collected at 4 sites in the Florida Keys spanning across the shelf from Florida Bay to the forereef area via osmotic pumps into teflon tubing that was subsequently subsampled and analyzed in the laboratory. OSMO sampler dates are based on known days of pump deployment and retrieval, sample volume and pump rates. Other samples were collected on known dates indicated. # Provided Keywords: strontium, trace element, seawater chemistry, Sr/Ca #--------------------------------------- # Publication # Authors: Hughes, Hunter P., Johan Schijf, K. Halimeda Kilbourne # Published_Date_or_Year: 2025 # Published_Title: High-resolution annual cycles of the Sr/Ca ratio in Florida Bay seawater sampled with osmotic pumps # Journal_Name: Paleoceanography and Paleoclimatology # Volume: 40 # Edition: # Issue: 9 # Pages: # Report_Number: e2025PA005168 # DOI: 10.1029/2025PA005168 # Online_Resource: # Full_Citation: # Abstract: Coral skeletal Sr/Ca ratios are a commonly used paleotemperature proxy that relies on stable seawater Sr/Ca ratios (Rsw). Recent observations call this assumption into question at some locations, particularly in the Florida Keys, USA. We collected Rsw time series data for 4 years from the Middle Keys with about weekly resolution, as well as several 24-hr time series from coral reef sites throughout the Caribbean, to quantify the magnitude and mode of Rsw variability and to assess its likely impact on coral Sr/Ca-based paleoclimate reconstructions. Continuous seawater samples were collected with four bottom-mounted osmotic pumps placed on a transect from inside Florida Bay to approximately 10 km offshore. In Florida Bay, Rsw displays annual cycles with high values in the summer and an amplitude of 0.4–0.5 mmol/mol that attenuates and becomes less periodic with increasing distance from the coast. We propose that this seawater Sr/Ca cycle may be due to a seasonal biogeochemical process related to the precipitation and dissolution of CaCO3 in Florida Bay, with the signal carried onto the shelf through mixing. The annual Rsw cycle can explain the low Sr/Ca–SST slopes that have been reported in local corals. Pseudo-coral Sr/Ca calculations indicate that Rsw causes enhanced uncertainty in reconstructed SST, even at the site 10 km offshore. The 24-hr time series show smaller diurnal variability in seawater Sr/Ca that appears to reflect local tides and hydrography, suggesting a similar potential for aberrant coral Sr/Ca–SST calibrations at other reef locations. #--------------------------------------- # Publication # Authors: Agraj Khare, Hunter P. Hughes, K. Halimeda Kilbourne, and Johan Schijf # Published_Date_or_Year: 2022 # Published_Title: Seasonal variations of the seawater Sr/Ca ratio across the Florida Keys Reef Tract # Journal_Name: Geochemistry, Geophysics, Geosystems # Volume: 24 # Edition: # Issue: 3 # Pages: # Report_Number: e2022GC010728 # DOI: 10.1029/2022GC010728 # Online_Resource: # Full_Citation: # Abstract: A surface seawater Sr/Ca ratio dataset was assembled across a section of the Florida Keys Reef Tract, to uncover variability that might explain previously reported anomalies in local calibrations of the coral aragonite Sr/Ca paleotemperature proxy. Samples were collected twice per year on a grid of 54 sites, from September of 2016 until January of 2020. The ~325 km2 grid extended from the shore out to the forereef and from the east end of Long Key to the west end of Marathon. Seawater Sr/Ca ratios were measured using a newly designed ICP-AES method with a long-term precision of better than 0.2%, with data normalized against an in-house seawater reference, quantified by ICP-MS. #--------------------------------------- # Publication # Authors: Agraj Khare, Hunter P. Hughes, K. Halimeda Kilbourne, and Johan Schijf # Published_Date_or_Year: 2021 # Published_Title: An ICP-AES method for routine high-precision measurement of seawater Sr/Ca ratios to validate coral paleothermometry calibrations # Journal_Name: Limnology and Oceanography Methods # Volume: 19 # Edition: # Issue: # Pages: 416-430 # Report_Number: # DOI: 10.1002/lom3.10434 # Online_Resource: # Full_Citation: # Abstract: A new ICP-AES method is presented for rapid and routine analysis of Sr/Ca molar ratios in seawater, with a long-term precision of <0.2%. It is an adaptation of a method widely employed for the analysis of coral aragonite Sr/Ca ratios in marine paleothermometry studies, which are based on the assumption that the seawater Sr/Ca ratio is constant in space and time. While prior studies have shown variations of up to 1% with depth, smaller variations at the ocean surface are generally accounted for via empirical, species-specific calibrations of coral Sr/Ca vs. temperature. We found Sr/Ca variations in some coastal waters to be even larger, with distinct periodicity, complicating this approach. Whereas the high precision necessary for measurements of seawater Sr/Ca has previously relied on advanced mass spectrometry, long analysis times, and expensive isotopic spikes, our method uses more accessible instrumentation and is both time- and cost-saving. The intricate composition of seawater, relative to coral aragonite solutions, requires an intensity ratio calibration technique combined with rigorous normalization to a suitable seawater standard. Key aspects of our method are discussed, including choice of wavelengths, instrumental parameters, accuracy, precision, and matrix effects. Special attention is given to the need for a certified seawater Sr/Ca reference standard, which does not presently exist. Analytical validation is provided by concurrent sharp gradients in Sr/Ca and d18O, coinciding with the Florida landfall of hurricane Irma, as recorded at near-daily resolution in a continuous seawater sample collected with an osmotic pump. #--------------------------------------- # Funding_Agency # Funding_Agency_Name: US National Science Foundation # Grant: OCE 1459636, OCE 1829385 #--------------------------------------- # Site_Information # Site_Name: Middle Florida Keys # Location: Caribbean Sea # Northernmost_Latitude: 24.83205 # Southernmost_Latitude: 24.59678333 # Easternmost_Longitude: -80.7653833333333 # Westernmost_Longitude: -81.1219 # Elevation_m: #--------------------------------------- # Data_Collection # Collection_Name: FL Grid Sr/Ca Kilbourne2025 # First_Year: 2016 # Last_Year: 2020 # Time_Unit: year Common Era # Core_Length_m: # Parameter_Keywords: trace metals # Notes: Filtered water samples taken by syringe with a 0.2 micron filter into low density polyethylene bottles and kept in the cool dark (sample refrigerator) before analysis via ICP-OES. All samplingin the Florida Keys National Marine Santuary was performed under permits FKNMS-2016-099, FKNMS-2016-099-A2 and FKNMS-2016-099-A3 issued by the National Oceanic and Atmospheric Administration, Office of National Marine Sanctuaries #--------------------------------------- # Chronology_Information # Chronology: # OSMO sampler dates are based on known days of pump deployment and retrieval, sample volume and pump rates. Other samples were collected on known dates indicated. #--------------------------------------- # Variables # PaST_Thesaurus_Download_Resource: https://www.ncei.noaa.gov/access/paleo-search/skos/past-thesaurus.rdf # PaST_Thesaurus_Download_Description: Paleoenvironmental Standard Terms (PaST) Thesaurus terms, definitions, and relationships in SKOS format. # # Data variables follow that are preceded by "##" in columns one and two. # Variables list, one per line, shortname-tab-var components: what, material, error, units, seasonality, data type, detail, method, C or N for Character or Numeric data) # ## StationID sample identification,,,,,instrumental,,,C, ## Latitude latitude,,,degree north,,instrumental,,,N, ## Longitude longitude,,,degree west,,instrumental,,,N, ## Samp_Depth depth,,,meter,,instrumental,,,N,this is the depth in the water column at which the water sample is taken ## Date collection date,,,day of year,,instrumental,,,C, ## Sr/Ca strontium/calcium,sea water,,millimole per mole,,instrumental,,inductively-coupled plasma atomic emission spectroscopy,N,See Khare et al 2021(L and O Methods) ## Sr/Ca_SE strontium/calcium,sea water,one standard error,millimole per mole,,instrumental,,inductively-coupled plasma atomic emission spectroscopy,N,replicates are part of the method; this is the standard error of at least 5 replicate measurements during analysis ## Bot_depth collection water depth,,,meter,,instrumental,,,N,this is the depth of the water at this location ## SST sea surface temperature,sea water,,degree Celsius,,instrumental,,,N,taken from shipboard instrumentation #------------------------ # Data: # Data lines follow (have no #) # Data line format - tab-delimited text, variable short name as header # Missing_Values: -9999 StationID Latitude Longitude Samp_Depth Date Sr/Ca Sr/Ca_SE Bot_depth SST 1A 24.83216667 -80.7748 0 09/16/16 8.686 0.017 4.0 -9999 1B 24.80726667 -80.7721 0 09/16/16 8.679 0.008 4.0 -9999 1C 24.78235 -80.7698 0 09/16/16 8.666 0.007 6.2 29.3 1D 24.7575 -80.7672 0 09/16/16 8.657 0.016 7.0 -9999 1D "stag party" 24.75841667 -80.7657 0 09/16/16 8.669 0.011 7.9 -9999 1E 24.74038333 -80.7654 0 09/16/16 8.660 0.010 35.2 -9999 2A 24.80871667 -80.808 0 09/16/16 8.657 0.012 1.5 -9999 2B 24.7878 -80.806 0 09/16/16 8.669 0.007 5.0 -9999 2C 24.76698333 -80.804 0 09/16/16 8.662 0.002 7.6 -9999 2D 24.74628333 -80.802 0 09/16/16 8.669 0.012 7.6 -9999.0 2E 24.72673333 -80.7993 0 09/16/16 8.650 0.013 32.3 -9999.0 3A 24.80191667 -80.8443 0 09/16/16 8.665 0.005 1.8 -9999.0 3B 24.77701667 -80.8415 0 09/16/16 8.685 0.009 5.5 30.0 3C 24.75218333 -80.8384 0 09/16/16 8.655 0.013 7.3 29.4 3D 24.72726667 -80.8356 0 09/16/16 8.657 0.010 7.0 29.2 3E 24.70248333 -80.8326 0 09/16/16 8.626 0.016 44.5 29.4 4A 24.79198333 -80.8783 0 09/16/16 8.706 0.011 3.0 30.6 4B 24.76711667 -80.8754 0 09/16/16 8.663 0.006 4.6 30.3 4C 24.74235 -80.8727 0 09/16/16 8.667 0.010 7.9 29.7 4D 24.71741667 -80.87 0 09/16/16 8.651 0.009 7.6 29.6 4E 24.69266667 -80.867 0 09/16/16 8.648 0.009 39.9 29.4 5A 24.76368333 -80.9149 0 09/16/16 8.699 0.006 1.5 -9999.0 5B 24.7389 -80.9124 0 09/16/16 8.671 0.011 7.6 30.4 5C 24.71423333 -80.9096 0 09/16/16 8.667 0.010 9.4 29.8 5D 24.68935 -80.9069 0 09/16/16 8.650 0.013 20.4 -9999.0 5E 24.66445 -80.9042 0 09/16/16 8.665 0.015 63.7 -9999.0 6A 24.7579 -80.9514 0 09/17/16 8.702 0.008 1.8 -9999.0 6B 24.73291667 -80.9484 0 09/17/16 8.672 0.009 6.1 30.4 6C 24.70836667 -80.9458 0 09/17/16 8.654 0.006 10.4 -9999.0 6C patch reef 24.71193333 -80.9475 0 09/17/16 8.653 0.010 4.6 29.7 6D 24.68318333 -80.9432 0 09/17/16 8.644 0.012 7.0 -9999.0 6E 24.65875 -80.9415 0 09/17/16 8.638 0.006 47.2 29.4 7A 24.7274 -80.9851 0 09/17/16 8.693 0.009 2.4 -9999.0 7B 24.70158333 -80.9826 0 09/17/16 8.694 0.010 11.6 30.1 7C 24.6766 -80.9799 0 09/17/16 8.670 0.020 6.7 30.0 7D 24.65221667 -80.9776 0 09/17/16 8.651 0.015 37.8 30.0 7E 24.62695 -80.975 0 09/17/16 8.652 0.017 76.2 29.9 8A 24.71583333 -80.0179 0 09/17/16 8.718 0.015 1.8 -9999.0 8B 24.69093333 -80.0152 0 09/17/16 8.698 0.013 8.5 30.3 8C 24.66601667 -80.0126 0 09/17/16 8.688 0.011 5.5 29.9 8D 24.64135 -80.0102 0 09/17/16 8.669 0.009 39.0 29.9 8E 24.61743333 -80.0076 0 09/17/16 8.662 0.012 75.6 30.0 9A 24.71086667 -80.0526 0 09/17/16 8.719 0.006 1.4 31.2 9B 24.68843333 -80.0508 0 09/17/16 8.692 0.009 6.4 -9999.0 9C 24.66343333 -80.0485 0 09/17/16 8.695 0.009 11.6 30.4 9D 24.63845 -80.0469 0 09/17/16 8.649 0.016 21.6 30.3 9E 24.6141 -80.0444 0 09/17/16 8.657 0.012 67.1 30.4 10A 24.6864 -80.0868 0 09/17/16 8.707 0.011 2.4 31.0 10AA 24.68711667 -80.0779 0 09/17/16 8.700 0.014 1.6 31.3 10B 24.66123333 -80.087 0 09/17/16 8.677 0.009 9.8 30.6 10C 24.6363 -80.0862 0 09/17/16 8.666 0.006 4.3 30.0 10D 24.61183333 -80.0854 0 09/17/16 8.648 0.009 48.8 30.0 11A 24.69566667 -80.122 0 09/17/16 8.718 0.010 2.6 30.9 11B 24.67161667 -80.1214 0 09/17/16 8.693 0.009 4.6 30.4 11C 24.64648333 -80.1219 0 09/17/16 8.673 0.005 10.7 30.3 11D 24.62151667 -80.1216 0 09/17/16 8.664 0.011 8.8 30.5 11E 24.59676667 -80.1218 0 09/17/16 8.670 0.006 59.4 30.4 1A 24.83216667 -80.7748 0 01/21/17 8.596 0.009 3.5 22.9 1B 24.80726667 -80.7721 0 01/21/17 8.677 0.010 3.7 23.3 1C 24.78235 -80.7698 0 01/21/17 8.649 0.006 6.1 24.3 1D 24.7575 -80.7672 0 01/21/17 8.679 0.009 5.9 24.3 1D "stag party" 24.75841667 -80.7657 0 01/21/17 8.646 0.007 5.7 24.2 1E 24.74038333 -80.7654 0 01/21/17 8.665 0.010 34.7 24.5 2A 24.80871667 -80.808 0 01/21/17 8.583 0.011 1.3 22.8 2B 24.7878 -80.806 0 01/21/17 8.641 0.006 4.9 23.6 2C 24.76698333 -80.804 0 01/21/17 8.643 0.009 7.6 24.2 2D 24.74628333 -80.802 0 01/21/17 8.648 0.003 7.6 23.9 2E 24.72673333 -80.7993 0 01/21/17 8.672 0.015 32.0 24.4 3A 24.80191667 -80.8443 0 01/21/17 8.613 0.002 -9999.0 -9999.0 3B 24.77701667 -80.8415 0 01/21/17 8.658 0.009 5.2 24.2 3C 24.75218333 -80.8384 0 01/21/17 8.663 0.015 7.3 24.3 3D 24.72726667 -80.8356 0 01/21/17 8.665 0.014 7.0 24.4 3E 24.70248333 -80.8326 0 01/21/17 8.659 0.006 44.5 24.5 4A 24.79198333 -80.8783 0 01/21/17 8.609 0.009 3.0 23.1 4B 24.76711667 -80.8754 0 01/21/17 8.643 0.012 4.7 23.6 4C 24.74235 -80.8727 0 01/21/17 8.640 0.014 8.2 24.4 4D 24.71741667 -80.87 0 01/21/17 8.650 0.011 7.9 24.1 4E 24.69266667 -80.867 0 01/21/17 8.644 0.008 40.8 24.2 5A 24.76368333 -80.9149 0 01/21/17 8.605 0.006 1.8 23.8 5B 24.7389 -80.9124 0 01/21/17 8.632 0.008 7.9 24.6 5C 24.71423333 -80.9096 0 01/21/17 8.641 0.006 9.8 24.7 5D 24.68935 -80.9069 0 01/21/17 8.648 0.006 20.4 24.3 5E 24.66445 -80.9042 0 01/21/17 8.659 0.012 64.3 24.4 6A 24.7579 -80.9514 0 01/18/17 8.596 0.008 1.6 23.0 6B 24.73291667 -80.9484 0 01/18/17 8.624 0.012 5.8 23.2 6C 24.70836667 -80.9458 0 01/18/17 8.639 0.009 10.1 23.9 6C patch reef 24.71193333 -80.9475 0 01/18/17 8.607 0.013 4.3 23.1 6D 24.68318333 -80.9432 0 01/18/17 8.650 0.010 7.0 25.6 6E 24.65875 -80.9415 0 01/18/17 8.655 0.008 47.5 26.3 7A 24.7274 -80.9851 0 01/18/17 8.611 0.007 2.3 22.4 7B 24.70158333 -80.9826 0 01/18/17 8.605 0.012 11.6 22.9 7C 24.6766 -80.9799 0 01/18/17 8.663 0.013 6.5 24.1 7D 24.65221667 -80.9776 0 01/18/17 8.669 0.007 37.5 25.3 7E 24.62695 -80.975 0 01/18/17 8.656 0.007 76.2 26.2 8A 24.71583333 -80.0179 0 01/18/17 8.610 0.008 1.6 22.8 8B 24.69093333 -80.0152 0 01/18/17 8.637 0.007 9.3 24.4 8C 24.66601667 -80.0126 0 01/18/17 8.643 0.005 5.5 25.2 8D 24.64135 -80.0102 0 01/18/17 8.658 0.007 38.1 26.0 8E 24.61743333 -80.0076 0 01/18/17 8.648 0.005 75.0 26.2 9A 24.71086667 -80.0526 0 01/18/17 8.588 0.006 1.4 22.2 9B 24.68843333 -80.0508 0 01/18/17 8.633 0.004 6.7 22.7 9C 24.66343333 -80.0485 0 01/18/17 8.653 0.007 12.2 24.5 9D 24.63845 -80.0469 0 01/18/17 8.659 0.006 21.0 25.0 9E 24.6141 -80.0444 0 01/18/17 8.655 0.007 66.8 25.9 10A 24.6864 -80.0868 0 01/18/17 8.618 0.015 2.4 22.6 10B 24.66123333 -80.087 0 01/18/17 8.663 0.009 10.1 24.1 10C 24.6363 -80.0862 0 01/18/17 8.649 0.007 4.9 25.1 10D 24.61183333 -80.0854 0 01/18/17 8.645 0.014 47.9 25.8 11A 24.69566667 -80.122 0 01/18/17 8.641 0.009 2.7 21.7 11B 24.67161667 -80.1214 0 01/18/17 8.645 0.017 4.9 21.8 11C 24.64648333 -80.1219 0 01/18/17 8.651 0.007 10.9 23.6 11D 24.62151667 -80.1216 0 01/18/17 8.656 0.012 9.4 24.8 11E 24.59676667 -80.1218 0 01/18/17 8.656 0.012 59.7 25.7 1A 24.83216667 -80.7748 0 08/01/17 8.755 0.008 3.5 28.7 1B 24.80726667 -80.7721 0 08/01/17 8.696 0.012 3.8 29.2 1C 24.78235 -80.7698 0 08/01/17 8.668 0.018 5.5 29.4 1D 24.7575 -80.7672 0 08/01/17 8.655 0.007 6.3 29.5 1E 24.74038333 -80.7654 0 08/01/17 8.625 0.011 34.1 29.3 2A 24.80871667 -80.808 0 08/01/17 8.683 0.010 1.3 28.1 2B 24.7878 -80.806 0 08/01/17 8.659 0.011 4.9 28.9 2C 24.76698333 -80.804 0 08/01/17 8.648 0.012 6.7 29.2 2C patch reef 24.76726667 -80.7944 0 08/01/17 8.640 0.014 5.2 29.3 2D 24.74628333 -80.802 0 08/01/17 8.629 0.016 7.2 28.9 2E 24.72673333 -80.7993 0 08/01/17 8.617 0.014 32.0 29.4 3A 24.80191667 -80.8443 0 08/01/17 8.719 0.008 1.4 29.0 3B 24.77701667 -80.8415 0 08/01/17 8.674 0.005 4.9 29.3 3C 24.75218333 -80.8384 0 08/01/17 8.640 0.010 7.3 29.2 3D 24.72726667 -80.8356 0 08/01/17 8.647 0.007 6.4 29.4 3E 24.70248333 -80.8326 0 08/01/17 8.616 0.021 44.2 29.9 4A 24.79198333 -80.8783 0 07/31/17 8.720 0.010 3.4 30.1 4B 24.76711667 -80.8754 0 07/31/17 8.667 0.006 4.7 30.1 4C 24.74235 -80.8727 0 07/31/17 8.647 0.012 7.9 30.2 4D 24.71741667 -80.87 0 07/31/17 8.618 0.006 7.9 29.6 4E 24.69266667 -80.867 0 07/31/17 8.634 0.011 41.5 29.5 5A 24.76368333 -80.9149 0 07/31/17 8.650 0.008 1.6 29.8 5B 24.7389 -80.9124 0 07/31/17 8.642 0.006 7.8 30.2 5C 24.71423333 -80.9096 0 07/31/17 8.639 0.007 9.8 29.9 5D 24.68935 -80.9069 0 07/31/17 8.621 0.005 20.7 29.4 5E 24.66445 -80.9042 0 07/31/17 8.621 0.006 65.5 29.6 6A 24.7579 -80.9514 0 07/31/17 8.684 0.007 1.2 29.3 6B 24.73291667 -80.9484 0 07/31/17 8.644 0.006 5.8 30.2 6C 24.70836667 -80.9458 0 07/31/17 8.649 0.009 10.1 30.2 6D 24.68318333 -80.9432 0 07/31/17 8.633 0.007 6.7 29.4 6E 24.65875 -80.9415 0 07/31/17 8.626 0.004 48.8 29.6 7A 24.7274 -80.9851 0 07/30/17 8.657 0.006 2.3 31.1 7B 24.70158333 -80.9826 0 07/30/17 8.643 0.006 12.2 30.8 7C 24.6766 -80.9799 0 07/30/17 8.620 0.004 6.7 30.3 7D 24.65221667 -80.9776 0 07/30/17 8.620 0.010 39.3 29.9 7E 24.62695 -80.975 0 07/30/17 8.612 0.005 79.2 30.1 8A 24.71583333 -80.0179 0 07/30/17 8.650 0.006 1.7 30.9 8B 24.69093333 -80.0152 0 07/30/17 8.644 0.007 8.5 30.7 8C 24.66601667 -80.0126 0 07/30/17 8.638 0.007 5.5 30.2 8D 24.64135 -80.0102 0 07/30/17 8.631 0.007 39.6 30.1 8E 24.61743333 -80.0076 0 07/30/17 8.630 0.008 78.0 30.1 9A 24.71086667 -80.0526 0 07/30/17 8.661 0.007 1.2 30.6 9B 24.68843333 -80.0508 0 07/30/17 8.666 0.003 6.1 30.6 9C 24.66343333 -80.0485 0 07/30/17 8.647 0.010 12.2 30.7 9D 24.63845 -80.0469 0 07/30/17 8.632 0.010 24.1 29.9 9E 24.6141 -80.0444 0 07/30/17 8.629 0.006 68.9 30.1 10A 24.6864 -80.0868 0 07/30/17 8.647 0.007 2.4 -9999.0 10B 24.66123333 -80.087 0 07/30/17 8.662 0.005 9.8 -9999.0 10C 24.6363 -80.0862 0 07/30/17 8.635 0.009 4.9 -9999.0 10D 24.61183333 -80.0854 0 07/30/17 8.640 0.008 50.9 -9999.0 11A 24.69566667 -80.122 0 07/30/17 8.667 0.009 2.6 30.8 11B 24.67161667 -80.1214 0 07/30/17 8.677 0.008 4.9 30.8 11C 24.64648333 -80.1219 0 07/30/17 8.646 0.006 10.4 30.8 11D 24.62151667 -80.1216 0 07/30/17 8.641 0.008 10.1 30.9 11E 24.59676667 -80.1218 0 07/30/17 8.626 0.009 62.5 -9999.0 1A 24.83216667 -80.7748 0 01/09/18 8.587 0.021 4.1 18.5 1B 24.80726667 -80.7721 0 01/09/18 8.624 0.015 3.8 19.1 1C 24.78235 -80.7698 0 01/09/18 8.642 0.007 6.4 20.7 1D 24.7575 -80.7672 0 01/09/18 8.657 0.007 7.6 22.1 1E 24.74038333 -80.7654 0 01/09/18 8.669 0.024 38.1 23.0 2A 24.80871667 -80.808 0 01/09/18 8.589 0.010 1.5 19.7 2B 24.7878 -80.806 0 01/09/18 8.634 0.012 5.8 20.7 2C 24.76698333 -80.804 0 01/09/18 8.658 0.015 8.2 22.1 2D 24.74628333 -80.802 0 01/09/18 8.654 0.022 8.2 22.7 2E 24.72673333 -80.7993 0 01/09/18 8.653 0.014 34.4 23.2 3A 24.80191667 -80.8443 0 01/07/18 8.540 0.015 1.8 15.9 3B 24.77701667 -80.8415 0 01/07/18 8.622 0.012 5.5 18.0 3C 24.75218333 -80.8384 0 01/07/18 8.630 0.013 7.9 18.8 3D 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-80.0126 0 01/14/20 8.648 0.006 5.5 23.9 8D 24.64135 -80.0102 0 01/16/20 8.643 0.005 41.1 25.2 8E 24.61743333 -80.0076 0 01/16/20 8.659 0.005 80.8 25.3 9A 24.71086667 -80.0526 0 01/13/20 8.635 0.007 1.6 23.2 9B 24.68843333 -80.0508 0 01/17/20 8.615 0.005 6.6 22.9 9C 24.66343333 -80.0485 0 01/14/20 8.649 0.004 12.5 23.9 9D 24.63845 -80.0469 0 01/16/20 8.659 0.005 24.2 25.1 9E 24.6141 -80.0444 0 01/16/20 8.644 0.006 70.1 25.1 10A 24.6864 -80.0868 0 01/13/20 8.635 0.005 2.7 23.2 10B 24.66123333 -80.087 0 01/17/20 8.636 0.004 10.9 23.4 10C 24.6363 -80.0862 0 01/14/20 8.638 0.004 5.4 24.3 10D 24.61183333 -80.0854 0 01/16/20 8.642 0.005 52.4 25.1 11A 24.69566667 -80.122 0 01/14/20 8.619 0.004 3.2 23.5 11B 24.67161667 -80.1214 0 01/14/20 8.626 0.003 5.3 23.7 11C 24.64648333 -80.1219 0 01/14/20 8.647 0.006 11.9 24.4 11D 24.62151667 -80.1216 0 01/16/20 8.642 0.004 11.0 25.0 11E 24.59676667 -80.1218 0 01/16/20 8.647 0.005 63.7 25.1 Osmo1 24.85986667 -80.8013 2.4 09/22/16 8.772 0.007 3.4 -9999 Osmo2 24.7845 -80.79 4.5 09/22/16 8.704 0.007 5.5 -9999 Osmo3 24.76326667 -80.7557 9.4 09/22/16 8.696 0.004 10.4 -9999 Osmo4 24.76111667 -80.7414 16.7 09/22/16 8.677 0.010 17.7 -9999 Osmo1 24.85986667 -80.8013 2.4 01/19/17 8.638 0.008 3.4 -9999 Osmo2 24.7845 -80.79 4.5 01/20/17 8.622 0.010 5.5 -9999 Osmo3 24.76326667 -80.7557 9.4 01/20/17 8.639 0.012 10.4 -9999 Osmo4 24.76111667 -80.7414 16.7 01/21/17 8.652 0.012 17.7 -9999 Osmo1 24.85986667 -80.8013 2.4 08/02/17 8.736 0.013 3.4 -9999 Osmo2 24.7845 -80.79 4.5 08/02/17 8.693 0.016 5.5 -9999 Osmo3 24.76326667 -80.7557 9.4 08/02/17 8.644 0.017 10.4 29.7 Osmo4 24.76111667 -80.7414 16.7 08/02/17 8.669 0.017 17.7 -9999 Osmo1 24.85986667 -80.8013 2.4 11/07/17 8.595 0.013 3.4 -9999 Osmo1 24.85986667 -80.8013 2.4 01/08/18 8.536 0.009 3.4 16.7 Osmo2 24.7845 -80.79 4.5 11/07/17 8.641 0.017 5.5 -9999 Osmo2 24.7845 -80.79 4.5 01/09/18 8.638 0.012 5.5 -9999 Osmo3 24.76326667 -80.7557 9.4 11/07/17 8.607 0.012 10.4 -9999 Osmo3 24.76326667 -80.7557 9.4 01/09/18 8.652 0.021 10.4 -9999 Osmo4 24.76111667 -80.7414 16.7 11/07/17 8.608 0.010 17.7 -9999 Osmo4 24.76111667 -80.7414 16.7 01/09/18 8.650 0.008 17.7 -9999 Osmo1 24.85986667 -80.8013 2.4 06/28/18 8.785 0.005 3.4 -9999 Osmo2 24.7845 -80.79 4.5 06/28/18 8.770 0.008 5.5 -9999 Osmo3 24.76326667 -80.7557 9.4 06/28/18 8.640 0.006 10.4 -9999 Osmo3 24.76326667 -80.7557 9.4 07/01/18 8.666 0.008 10.4 -9999 Osmo4 24.76111667 -80.7414 16.7 06/28/18 8.640 0.009 17.7 29.4 Osmo1 24.85986667 -80.8013 2.4 01/13/19 8.648 0.002 3.4 20.9 Osmo2 24.7845 -80.79 4.5 01/13/19 8.655 0.004 5.5 23.2 Osmo3 24.76326667 -80.7557 9.4 01/13/19 8.648 0.005 10.4 23.7 Osmo4 24.76111667 -80.7414 16.7 01/13/19 8.654 0.009 17.7 23.2 Osmo1 24.85986667 -80.8013 2.4 01/15/20 8.579 0.008 3.4 -9999 Osmo2 24.7845 -80.79 4.5 01/16/20 8.624 0.006 5.5 -9999 Osmo3 24.76326667 -80.7557 9.4 01/15/20 8.637 0.005 10.4 -9999 Osmo4 24.76111667 -80.7414 16.7 01/15/20 8.656 0.005 17.7 -9999 Osmo1 24.85986667 -80.8013 2.4 08/26/20 8.649 0.004 3.4 -9999 Osmo2 24.7845 -80.79 4.5 08/26/20 8.641 0.006 5.5 -9999 Osmo3 24.76326667 -80.7557 9.4 08/26/20 8.625 0.006 10.4 -9999 Osmo4 24.76111667 -80.7414 16.7 08/26/20 8.624 0.005 17.7 -9999 Osmo2 24.7845 -80.79 4.5 08/20/21 8.643 0.006 5.5 -9999 Osmo3 24.76326667 -80.7557 9.4 08/20/21 8.628 0.003 10.4 -9999 Osmo4 24.76111667 -80.7414 16.7 08/17/21 8.634 0.006 17.7 -9999