# Central Great Barrier Reef, Porites spp. trace metals 1983-1998 CE #----------------------------------------------------------------------- # World Data Service for Paleoclimatology, Boulder # and # NOAA Paleoclimatology Program #----------------------------------------------------------------------- # Template Version 4.0 # Encoding: UTF-8 # NOTE: Please cite original publication, NOAA Landing Page URL, dataset and publication DOIs (where available), and date accessed when using downloaded data. # If there is no publication information, please cite investigator, study title, NOAA Landing Page URL, and date accessed. # # Description/Documentation lines begin with '#' followed by a space # Data lines have no '#' # # NOAA_Landing_Page: https://www.ncei.noaa.gov/access/paleo-search/study/39021 # Landing_Page_Description: NOAA Landing Page of this file's parent study, which includes all study metadata. # # Study_Level_JSON_Metadata: https://www.ncei.noaa.gov/pub/data/metadata/published/paleo/json/noaa-coral-39021.json # Study_Level_JSON_Description: JSON metadata of this data file's parent study, which includes all study metadata. # # Data_Type: Corals and Sclerosponges # # Dataset_DOI: 10.25921/p7g3-qc81 # # Science_Keywords: #--------------------------------------- # Resource_Links # # Data_Download_Resource: https://www.ncei.noaa.gov/pub/data/paleo/coral/west_pacific/great_barrier/fallon2003/fallon2003-pandora1-98a-metals.txt # Data_Download_Description: NOAA Template File; Pandora 1-98a Trace Metals Data # #--------------------------------------- # Contribution_Date # Date: 2024-02-12 #--------------------------------------- # File_Last_Modified_Date # Date: 2025-06-30 #--------------------------------------- # Title # Study_Name: Central Great Barrier Reef, Porites spp. trace metals 1983-1998 CE #--------------------------------------- # Investigators # Investigators: Fallon, S.J. (https://orcid.org/0000-0002-8064-5903); McCulloch, M.T. (https://orcid.org/0000-0003-1538-1558); Alibert, C. (https://orcid.org/0000-0002-9113-7365) #--------------------------------------- # Description_Notes_and_Keywords # Description: Contributed as part of the Great Barrier Reef Coral Skeletal Records Database (GBRCD). # Provided Keywords: Great Barrier Reef, Coral Geochemistry, Sea Surface Temperature, LA-ICP-MS #--------------------------------------- # Publication # Authors: Fallon, S.J., McCulloch, M.T., Alibert, C. # Published_Date_or_Year: 2003 # Published_Title: Examining water temperature proxies in Porites corals from the Great Barrier Reef: a cross-shelf comparison # Journal_Name: Coral Reefs # Volume: 22 # Edition: # Issue: 4 # Pages: 389–404 # Report_Number: # DOI: 10.1007/s00338-003-0322-5 # Online_Resource: # Full_Citation: # Abstract: Cores from colonies of the coral species Porites sp. were collected from inshore, mid-shelf, and outer reef localities (central Great Barrier Reef) to test the robustness of the major elemental sea surface temperature (SST) proxies (B/Ca, Mg/Ca, Sr/Ca, U/Ca) to the influence of inshore processes. Time series analyses of Sr/Ca, U/Ca, B/Ca, and Mg/Ca are compared to sea surface temperature (SST) in order to provide calibrations for these elements. This study shows that there are significant variations between the corals with respect to some of the proxies. In some cases, variations of ~6 °C are observed for a single U/Ca value. This magnitude of variation is also seen in the Mg/Ca proxy and, to a smaller extent, in the B/Ca–SST relationship. In two of the corals, both Mg/Ca and U/Ca do not follow a seasonal signal. The Mg/Ca and U/Ca ratios for two inshore corals are significantly different than the offshore corals (lower and higher, respectively). The other two proxies (B/Ca and Sr/Ca) do not display any inshore vs. offshore variations except for one inshore site that did not have a clear seasonal signal for either of these proxies. The Sr/Ca–SST relationship is the most robust, with a temperature variation of ~2 °C for a single Sr/Ca value, which is within error for this technique. #--------------------------------------- # Publication # Authors: Fallon, S.J. # Published_Date_or_Year: 2000 # Published_Title: Environmental Records from Corals and Coralline Sponges # Journal_Name: # Volume: # Edition: # Issue: # Pages: # Report_Number: # DOI: 10.25911/5d778a502c764 # Online_Resource: # Full_Citation: Fallon, S.J. (2000), ‘Environmental Records from Corals and Coralline Sponges’, PhD Thesis, Australian National University, https://doi.org/10.25911/5d778a502c764. # Abstract: This research centers on the extraction of environmental information stored in the calcium carbonate skeletons of corals (Porites) and coralline sponges (Astrosclera willeyana). Elemental variations are measured in these samples using laser ablation inductively coupled plasma mass spectrometry. During this project, techniques were refined and developed to quantitatively measure major (B, Mg, Sr, Ba, U) and minor (Mn, Zn, Pb, REE’s) elemental abundances in corals and coralline sponges. This method was used to extract seasonal records from a high latitude coral living at its limits of cold-water tolerance in Japan. Seasonal cycles of major elements (B, Mg, Sr, U) were calibrated against in situ instrumental temperature monitors. Calibrations were in good agreement with other published reports. This coral also recorded wind-induced upwelling (both annual and El Nin~o related) by increases in the Ba/Ca ratio. The trace element annual patterns and slow growth rate also indicated that this coral had very slow/no extension during the cold winter months when water temperature was below 18 oC. Cores from Porites sp. coral colonies were also collected from inshore, mid-shelf and outer reef localities (central Great Barrier Reef) to test the robustness of the major elemental SST and runoff proxies (B/Ca, Mg/Ca, Sr/Ca, Ba/Ca, U/Ca). The inshore reefs selected for this study are heavily influenced by river runoff whereas the mid-reef and outer-reef locations are not. It is shown that Ba/Ca provides an excellent proxy for river runoff. Time series analyses of Sr/Ca, U/Ca, B/Ca and Mg/Ca are compared to in situ sea surface temperature (SST) and/or IGOSS NMC weekly satellite SST to provide calibrations for these elements. Previous workers have noted differences in the calibration of Sr/Ca vs. SST; this LA-ICP-MS dataset shows a slight variation between different corals. This suggests small-scale intra- coral variability. Both the U/Ca and Mg/Ca have calibrations within error for mid-shelf and outer reef corals but the calibrations differ for the inshore corals. Sr/Ca and B/Ca appear to be the most robust of the elemental temperature proxies in terms of recording water temperature. Measurements of coral manganese suggest a seasonal cycle closely linked to solar radiation and wind. Increased solar radiation may increase the dissolved seawater Mn that result in corals having elevated concentrations of Mn during the summer. The use of corals as recorders of marine pollution was examined on the island of Misima in Papua New Guinea where open-cut gold mining commenced in 1989. This mining caused increased sedimentation affecting the nearby fringing coral reef to varying degrees, causing coral mortality (complete suffocation) in some areas. This sediment is made up of completely weathered quartz feldspar, greenstone and schist. These rocks have distinct chemical constituents (rare earth elements [REE], zinc and lead etc.), which are entering the near-shore environment in considerably higher than normal concentrations. Eight coral colonies (2 from high sedimentation, 2 transitional, 2 minor and 2 unaffected control sites) were analyzed for Mn, Y, La, Ce, Zn and Pb. All sites show low steady “background” levels prior to the commencement of mining. After mine construction began in 1988, all sites aside from the control show dramatic increases of Mn, Y, La, and Ce associated with the increased sedimentation. Zn and Pb increase after 1989 when ore processing began. The concentration of these elements in these corals decreases as the distance from the mine increases. Rare earth elements (REE) measured in two corals suggest a pattern different from “normal” seawater. When the coral REE pattern is compared to seawater an enrichment of the light and middle REE’s appear. The heavy REE’s are depleted relative to the seawater pattern. This suggests the nearshore seawater REE’s are influenced by island weathering. Coralline sponges have been proposed as a new source of tropical paleoclimatic information. Profiles of d13C in coralline sponges have documented (better and more accurately than corals) the atmospheric increase of Due to their very slow growth rates ~0.2 mm yr-1 sponges are better suited to recording and providing long-term environmental information rather than annual information. These sponges appear to smooth the record stored in their skeleton by adding secondary aragonite near the base of the living tissue layer. This smoothing limits their use as annual environmental recorders but still enables their use for decadal or longer environmental fluctuations. Smoothed records of Sr/Ca from five sponges around the Southwest Pacific C associated with increased fossil fuel consumption. suggest that these sponges are able to capture 5 yr. and longer seawater temperature anomalies over the past 50-200 years. The temperature sensitivity of Sr/Ca in sponges is 7 to 12 times larger than corals with ~0.7-0.9 mmol/mol DSr/Ca per oC for sponges compared to ~0.07 mmol/mol DSr/Ca per oC for corals. #--------------------------------------- # Funding_Agency # Funding_Agency_Name: Australian National University # Grant: #--------------------------------------- # Site_Information # Site_Name: Pandora Reef # Location: Great Barrier Reef, Australia # Northernmost_Latitude: -18.82 # Southernmost_Latitude: -18.82 # Easternmost_Longitude: 146.43 # Westernmost_Longitude: 146.43 # Elevation_m: -2 #--------------------------------------- # Data_Collection # Collection_Name: Pandora 1-98a trace metals Fallon2003 # First_Year: 1990 # Last_Year: 1998 # Time_Unit: year Common Era # Core_Length_m: # Parameter_Keywords: trace metals # Notes: Porites sp. #--------------------------------------- # Chronology_Information # Chronology: #--------------------------------------- # Variables # PaST_Thesaurus_Download_Resource: https://www.ncei.noaa.gov/access/paleo-search/skos/past-thesaurus.rdf # PaST_Thesaurus_Download_Description: Paleoenvironmental Standard Terms (PaST) Thesaurus terms, definitions, and relationships in SKOS format. # # Data variables follow that are preceded by "##" in columns one and two. # Variables list, one per line, shortname-tab-var components: what, material, error, units, seasonality, data type, detail, method, C or N for Character or Numeric data) # ## Depth depth,,,millimeter,,corals and sclerosponges,,,N, ## age_CE age,,,year Common Era,,corals and sclerosponges,,,N, ## B/Ca Boron/Calcium,Porites sp.,,mole per mole,,corals and sclerosponges,,inductively-coupled plasma mass spectrometry,N,laser ablation inductively-coupled mass spectrometry ## Mg/Ca Magnesium/Calcium,Porites sp.,,mole per mole,,corals and sclerosponges,,inductively-coupled plasma mass spectrometry,N,laser ablation inductively-coupled mass spectrometry ## Sr/Ca Strontium/Calcium,Porites sp.,,mole per mole,,corals and sclerosponges,,inductively-coupled plasma mass spectrometry,N,laser ablation inductively-coupled mass spectrometry ## Ba/Ca Barium/Calcium,Porites sp.,,mole per mole,,corals and sclerosponges,,inductively-coupled plasma mass spectrometry,N,laser ablation inductively-coupled mass spectrometry ## U/Ca Uranium/Calcium,Porites sp.,,mole per mole,,corals and sclerosponges,,inductively-coupled plasma mass spectrometry,N,laser ablation inductively-coupled mass spectrometry ## Mn Manganese,Porites sp.,,microgram per gram,,corals and sclerosponges,,inductively-coupled plasma mass spectrometry,N,laser ablation inductively-coupled mass spectrometry #------------------------ # Data: # Data lines follow (have no #) # Data line format - tab-delimited text, variable short name as header # Missing_Values: NA Depth age_CE B/Ca Mg/Ca Sr/Ca Ba/Ca U/Ca Mn 0.1411 1998.7880 0.000526543 0.003414331 0.008777182 0.000004907 0.000001288 0.194400 0.4937 1998.7500 0.000529779 0.003081943 0.008865254 0.000004930 0.000001310 0.187999 0.8463 1998.6931 0.000557739 0.002940347 0.009087591 0.000004748 0.000001438 0.185204 1.1990 1998.6351 0.000570480 0.002878507 0.009157330 0.000004499 0.000001433 0.222017 1.5516 1998.5770 0.000560612 0.002686468 0.009087694 0.000004324 0.000001433 0.258833 1.9043 1998.5190 0.000547119 0.002615225 0.009243633 0.000004323 0.000001454 0.270624 2.2569 1998.4609 0.000594588 0.002897721 0.009190932 0.000004253 0.000001376 0.282446 2.6095 1998.4029 0.000543369 0.002829742 0.009182115 0.000004515 0.000001385 0.277683 2.9622 1998.3460 0.000496781 0.003228874 0.009061411 0.000004504 0.000001343 0.262342 3.3148 1998.2879 0.000405265 0.003511136 0.008756700 0.000004435 0.000001133 0.260578 3.6674 1998.2299 0.000363438 0.003446352 0.008703415 0.000004447 0.000001089 0.248948 4.0201 1998.2109 0.000392531 0.003856738 0.008795129 0.000004538 0.000001078 0.239665 4.3727 1998.1919 0.000419964 0.004032501 0.008739239 0.000004694 0.000001068 0.251808 4.7254 1998.1730 0.000399021 0.004085953 0.008809549 0.000005048 0.000001111 0.248554 5.0780 1998.1540 0.000388248 0.004564162 0.008715621 0.000005918 0.000001061 0.240765 5.4306 1998.1350 0.000373696 0.004786800 0.008752073 0.000006502 0.000000993 0.259255 5.7833 1998.1223 0.000381830 0.004474672 0.008802935 0.000006989 0.000001082 0.275370 6.1359 1998.1096 0.000377794 0.004297246 0.008844431 0.000006745 0.000001135 0.311486 6.4886 1998.0970 0.000351197 0.003958093 0.008855413 0.000006967 0.000001197 0.323261 6.8412 1998.0843 0.000325420 0.004162018 0.008667245 0.000009129 0.000001158 0.318498 7.1938 1998.0776 0.000341995 0.004036980 0.008591290 0.000009268 0.000001117 0.267073 7.5465 1998.0709 0.000389788 0.003587870 0.008845548 0.000008364 0.000001250 0.289593 7.8991 1998.0642 0.000446574 0.003498469 0.008900954 0.000006096 0.000001303 0.339066 8.2518 1998.0574 0.000441417 0.003072784 0.008992473 0.000004675 0.000001407 0.326053 8.6044 1998.0500 0.000424473 0.003030240 0.008972853 0.000003786 0.000001336 0.346655 8.9570 1998.0433 0.000437587 0.003323899 0.008971427 0.000003843 0.000001319 0.359285 9.3097 1998.0366 0.000420439 0.003699775 0.008746756 0.000003658 0.000001255 0.345378 9.6623 1998.0299 0.000420313 0.003542070 0.008687434 0.000003781 0.000001238 0.281806 10.0150 1998.0231 0.000407388 0.003513950 0.008629214 0.000003654 0.000001266 0.237126 10.3676 1998.0164 0.000431568 0.003712828 0.008862477 0.000003719 0.000001302 0.236757 10.7202 1998.0097 0.000428051 0.003750773 0.008988900 0.000003927 0.000001343 0.342056 11.0729 1998.0030 0.000430651 0.003671041 0.008993109 0.000003963 0.000001363 0.439316 11.4255 1997.9963 0.000416089 0.004020858 0.008786999 0.000003978 0.000001223 0.418055 11.7782 1997.9896 0.000424718 0.003824039 0.008926782 0.000003914 0.000001259 0.288744 12.1308 1997.9821 0.000429636 0.003578154 0.008967084 0.000003848 0.000001287 0.265300 12.4834 1997.9754 0.000442637 0.003547747 0.008990798 0.000003953 0.000001355 0.260836 12.8361 1997.9687 0.000442124 0.003799312 0.009045455 0.000003853 0.000001273 0.264277 13.1887 1997.9620 0.000407256 0.004134594 0.008694584 0.000003804 0.000001166 0.268040 13.5414 1997.9447 0.000403435 0.003623066 0.008861703 0.000003780 0.000001309 0.226770 13.8940 1997.8948 0.000454765 0.003388673 0.008949690 0.000003854 0.000001344 0.186872 14.2466 1997.8448 0.000469540 0.003361997 0.008977019 0.000003900 0.000001314 0.172477 14.5993 1997.7948 0.000492867 0.003018702 0.009079453 0.000003998 0.000001403 0.154117 14.9519 1997.7449 0.000473748 0.002940325 0.009172899 0.000003974 0.000001381 0.162250 15.3046 1997.6949 0.000486836 0.003113753 0.009078145 0.000004012 0.000001410 0.167357 15.6572 1997.6450 0.000494969 0.003261782 0.009204901 0.000003899 0.000001481 0.157484 16.0098 1997.5950 0.000498034 0.003063279 0.009260237 0.000004049 0.000001538 0.151666 16.3625 1997.5470 0.000488356 0.002904409 0.009216957 0.000004114 0.000001587 0.167354 16.7151 1997.5030 0.000506875 0.003003917 0.009252352 0.000004197 0.000001475 0.181751 17.0677 1997.4590 0.000476830 0.002718885 0.009147446 0.000004031 0.000001430 0.179691 17.4204 1997.4150 0.000472154 0.003081722 0.008947564 0.000004068 0.000001335 0.193630 17.7730 1997.3710 0.000488560 0.003282066 0.009014445 0.000004207 0.000001263 0.211681 18.1257 1997.3270 0.000487263 0.003552957 0.008888843 0.000004155 0.000001182 0.199712 18.4783 1997.2830 0.000503544 0.003605876 0.008976921 0.000004077 0.000001180 0.192826 18.8309 1997.2711 0.000488371 0.003482071 0.008968253 0.000003994 0.000001212 0.212851 19.1836 1997.2592 0.000504521 0.003380103 0.008968999 0.000004093 0.000001249 0.225910 19.5362 1997.2344 0.000501816 0.003476256 0.009051630 0.000004755 0.000001288 0.251419 19.8889 1997.2097 0.000468605 0.003652966 0.008930376 0.000005820 0.000001201 0.225483 20.2415 1997.1845 0.000461580 0.003546556 0.008855864 0.000006711 0.000001191 0.228895 20.5941 1997.1597 0.000454519 0.003723703 0.008732544 0.000007127 0.000001133 0.243046 20.9468 1997.1350 0.000440584 0.003466644 0.008860965 0.000006930 0.000001172 0.268544 21.2994 1997.1102 0.000424209 0.003356616 0.008830277 0.000007045 0.000001187 0.258474 21.6521 1997.0850 0.000394504 0.003421163 0.008848693 0.000007372 0.000001230 0.254265 22.0047 1997.0603 0.000372177 0.003739226 0.008567595 0.000006083 0.000001126 0.244606 22.3573 1997.0543 0.000389306 0.004025801 0.008613582 0.000004889 0.000001125 0.275729 22.7100 1997.0483 0.000388339 0.004184169 0.008742154 0.000004508 0.000001094 0.272138 23.0626 1997.0424 0.000411374 0.004309765 0.008760075 0.000003974 0.000001104 0.297629 23.4153 1997.0360 0.000417590 0.004115013 0.008777872 0.000003749 0.000001124 0.294550 23.7679 1997.0300 0.000433513 0.004181426 0.008778043 0.000003617 0.000001094 0.269673 24.1205 1997.0240 0.000411472 0.003956609 0.008807841 0.000003600 0.000001144 0.282154 24.4732 1997.0181 0.000429680 0.004619654 0.008741350 0.000003707 0.000001054 0.307607 24.8258 1997.0121 0.000438736 0.004438687 0.008816641 0.000003684 0.000001046 0.300568 25.1785 1997.0062 0.000446481 0.004042170 0.008851221 0.000003570 0.000001132 0.313111 25.5311 1996.9998 0.000409434 0.004342827 0.008853175 0.000003493 0.000001062 0.308904 25.8837 1996.9938 0.000402546 0.004445085 0.008743605 0.000003507 0.000001084 0.393524 26.2364 1996.9878 0.000426485 0.004146551 0.008889415 0.000003555 0.000001150 0.422823 26.5890 1996.9819 0.000397943 0.004013747 0.008916438 0.000003495 0.000001129 0.490705 26.9417 1996.9718 0.000399291 0.003917227 0.008764063 0.000003432 0.000001097 0.471424 27.2943 1996.9617 0.000421748 0.004193684 0.008834578 0.000003527 0.000001098 0.563371 27.6469 1996.9521 0.000426394 0.004462923 0.008781908 0.000003481 0.000001080 0.661656 27.9996 1996.9420 0.000422072 0.004305067 0.008708627 0.000003464 0.000001057 0.586449 28.3522 1996.9179 0.000416075 0.003896400 0.008808001 0.000003484 0.000001179 0.500273 28.7048 1996.8939 0.000410264 0.003500016 0.008972322 0.000003634 0.000001252 0.342880 29.0575 1996.8698 0.000427069 0.003407792 0.008888860 0.000003605 0.000001278 0.323048 29.4101 1996.8469 0.000440270 0.003382239 0.008871555 0.000003633 0.000001209 0.312367 29.7628 1996.8228 0.000440009 0.003216590 0.008939102 0.000003543 0.000001309 0.316510 30.1154 1996.7987 0.000447447 0.002887152 0.008976097 0.000003672 0.000001414 0.333614 30.4680 1996.7747 0.000438911 0.003086192 0.008887148 0.000003465 0.000001295 0.295695 30.8207 1996.7506 0.000452369 0.002917189 0.009105722 0.000003543 0.000001362 0.245758 31.1733 1996.7276 0.000458466 0.003023198 0.009067841 0.000003585 0.000001310 0.213384 31.5260 1996.7036 0.000467426 0.003215353 0.009082339 0.000003760 0.000001336 0.214870 31.8786 1996.6795 0.000491196 0.003193589 0.009090848 0.000003788 0.000001308 0.233292 32.2312 1996.6577 0.000472080 0.003016578 0.009168548 0.000003726 0.000001360 0.272086 32.5839 1996.6369 0.000465249 0.002966078 0.009171545 0.000003559 0.000001335 0.254371 32.9365 1996.6150 0.000466325 0.002981904 0.009319819 0.000003505 0.000001444 0.202318 33.2892 1996.5948 0.000472525 0.002927321 0.009300444 0.000003289 0.000001380 0.178463 33.6418 1996.5745 0.000486854 0.002976710 0.009138044 0.000002927 0.000001396 0.198037 33.9944 1996.5553 0.000452815 0.003178926 0.009144360 0.000003002 0.000001327 0.219602 34.3471 1996.5351 0.000487472 0.003187462 0.009252450 0.000003245 0.000001390 0.224153 34.6997 1996.5149 0.000491861 0.003177324 0.009430170 0.000003611 0.000001490 0.219054 35.0524 1996.4957 0.000470740 0.003591179 0.009051501 0.000003774 0.000001232 0.183667 35.4050 1996.4754 0.000476459 0.003449952 0.009036461 0.000003860 0.000001295 0.170460 35.7576 1996.4552 0.000477497 0.003607359 0.009112212 0.000004045 0.000001321 0.186594 36.1103 1996.4350 0.000458188 0.003792532 0.008972635 0.000004038 0.000001309 0.195728 36.4629 1996.4158 0.000439031 0.003903902 0.009103888 0.000004064 0.000001372 0.187552 36.8156 1996.3955 0.000436055 0.003573673 0.009037707 0.000004071 0.000001303 0.252658 37.1682 1996.3753 0.000432469 0.003674897 0.008925647 0.000004076 0.000001213 0.318080 37.5208 1996.3561 0.000441743 0.003516513 0.008827454 0.000003954 0.000001240 0.342235 37.8735 1996.3359 0.000473326 0.003763222 0.008951807 0.000004027 0.000001221 0.368859 38.2261 1996.3156 0.000462834 0.003690450 0.009011047 0.000003964 0.000001261 0.393630 38.5788 1996.2964 0.000421123 0.003730431 0.008975829 0.000003825 0.000001219 0.333745 38.9314 1996.2762 0.000417308 0.003599025 0.008970670 0.000003794 0.000001316 0.321771 39.2840 1996.2560 0.000429548 0.003396331 0.008839151 0.000004029 0.000001237 0.318997 39.6367 1996.2357 0.000439869 0.003993581 0.008980788 0.000004164 0.000001149 0.360424 39.9893 1996.2165 0.000421883 0.003868644 0.008997081 0.000004243 0.000001227 0.384997 40.3419 1996.1963 0.000385452 0.004480801 0.008806427 0.000004872 0.000001118 0.340648 40.6946 1996.1761 0.000407168 0.004301178 0.008721790 0.000005124 0.000001117 0.327724 41.0472 1996.1569 0.000375336 0.004230114 0.008690358 0.000004995 0.000001051 0.355802 41.3999 1996.1366 0.000385257 0.003835344 0.008614270 0.000004834 0.000001121 0.334473 41.7525 1996.1164 0.000399762 0.003853392 0.008816329 0.000004645 0.000001188 0.372939 42.1051 1996.0962 0.000384636 0.004014810 0.008694862 0.000004279 0.000001170 0.399891 42.4578 1996.0719 0.000376669 0.004047505 0.008644138 0.000004465 0.000001189 0.527419 42.8104 1996.0588 0.000412994 0.004024175 0.008789252 0.000004125 0.000001267 0.526437 43.1631 1996.0395 0.000427592 0.003975337 0.008726811 0.000003761 0.000001214 0.634849 43.5157 1996.0193 0.000430967 0.003848890 0.008764996 0.000003625 0.000001141 0.680938 43.8683 1996.0001 0.000417062 0.004129603 0.008662802 0.000003610 0.000001122 0.540531 44.2210 1995.9799 0.000426122 0.004074775 0.008783588 0.000003562 0.000001103 0.464933 44.5736 1995.9607 0.000427944 0.004145201 0.008601271 0.000003369 0.000001055 0.478888 44.9263 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0.004138444 0.008537716 0.000003594 0.000000969 0.419228 56.9764 1995.1052 0.000344658 0.004191680 0.008606667 0.000003711 0.000001044 0.425265 57.3186 1995.0960 0.000415505 0.003919518 0.008794196 0.000003731 0.000001156 0.439999 57.6608 1995.0863 0.000456436 0.004026673 0.008877163 0.000003814 0.000001173 0.487476 58.0030 1995.0765 0.000439604 0.003903624 0.008754945 0.000003762 0.000001177 0.481294 58.3452 1995.0673 0.000436631 0.003565800 0.008896829 0.000003672 0.000001233 0.378154 58.6874 1995.0575 0.000443521 0.003728799 0.008782301 0.000003653 0.000001209 0.385902 59.0296 1995.0477 0.000446372 0.003749501 0.008892602 0.000003613 0.000001194 0.414400 59.3719 1995.0385 0.000472150 0.003816781 0.008780509 0.000003688 0.000001153 0.524857 59.7141 1995.0288 0.000445157 0.003496148 0.008768144 0.000003607 0.000001135 0.454307 60.0563 1995.0190 0.000459821 0.003651297 0.008749820 0.000003575 0.000001120 0.350008 60.3985 1995.0098 0.000446759 0.003448194 0.008784793 0.000003568 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0.000004498 0.000001225 0.161599 68.6114 1994.2802 0.000477197 0.003401954 0.008801207 0.000004802 0.000001158 0.177784 68.9536 1994.2500 0.000466722 0.003870394 0.008706302 0.000005490 0.000001097 0.178091 69.2958 1994.2277 0.000437353 0.003606454 0.008724057 0.000006087 0.000001204 0.182538 69.6380 1994.2049 0.000435789 0.003606040 0.008819726 0.000006012 0.000001164 0.195858 69.9802 1994.1826 0.000422007 0.003669143 0.008740250 0.000006142 0.000001108 0.220962 70.3224 1994.1597 0.000403229 0.003711920 0.008727105 0.000005496 0.000001045 0.269761 70.6646 1994.1374 0.000403231 0.003987578 0.008649622 0.000004358 0.000001029 0.265525 71.0068 1994.1146 0.000368844 0.003756426 0.008626577 0.000003637 0.000001009 0.252743 71.3490 1994.0923 0.000395975 0.003939139 0.008622394 0.000003736 0.000001032 0.234697 71.6912 1994.0694 0.000389791 0.003975169 0.008688968 0.000003760 0.000001055 0.231328 72.0334 1994.0471 0.000377916 0.004242707 0.008554898 0.000003799 0.000000957 0.247722 72.3756 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1992.5784 0.000527413 0.002959377 0.009325002 0.000004304 0.000001421 0.187342 100.1582 1992.5470 0.000521607 0.003059559 0.009181628 0.000004405 0.000001414 0.176868 100.5032 1992.5297 0.000520496 0.003159103 0.009199227 0.000004400 0.000001390 0.222692 100.8482 1992.5133 0.000521455 0.002962226 0.009147761 0.000004181 0.000001262 0.245698 101.1932 1992.4970 0.000490019 0.003171247 0.008990557 0.000004092 0.000001100 0.285161 101.5382 1992.4807 0.000496064 0.003413820 0.008789817 0.000003959 0.000001049 0.307869 101.8832 1992.4634 0.000480540 0.003543699 0.009016818 0.000004074 0.000001252 0.212760 102.2282 1992.4470 0.000491179 0.003149495 0.009045074 0.000003984 0.000001320 0.236054 102.5732 1992.4307 0.000497490 0.003333478 0.009005700 0.000004083 0.000001317 0.231287 102.9182 1992.4144 0.000462292 0.003196331 0.008978552 0.000004011 0.000001257 0.217216 103.2632 1992.3970 0.000469681 0.003517828 0.008852997 0.000004113 0.000001176 0.227031 103.6082 1992.3807 0.000500776 0.003533733 0.008833738 0.000004393 0.000001173 0.235889 103.9532 1992.3644 0.000487311 0.003473626 0.008889875 0.000004515 0.000001204 0.243400 104.2982 1992.3481 0.000466194 0.003782233 0.008982299 0.000004582 0.000001213 0.268176 104.6432 1992.3307 0.000483334 0.003324664 0.008998274 0.000004656 0.000001273 0.335632 104.9882 1992.3144 0.000484425 0.003700678 0.009106721 0.000004520 0.000001206 0.301866 105.3332 1992.2981 0.000481360 0.003722197 0.008920960 0.000004593 0.000001228 0.254558 105.6782 1992.2818 0.000438280 0.003506855 0.008904561 0.000004593 0.000001220 0.205129 106.0232 1992.2644 0.000398918 0.004051341 0.008655421 0.000004321 0.000001057 0.222302 106.3682 1992.2481 0.000406224 0.004547030 0.008767616 0.000004143 0.000001025 0.254512 106.7132 1992.2318 0.000399808 0.004291148 0.008771192 0.000003981 0.000001091 0.300601 107.0582 1992.2155 0.000398158 0.004714831 0.008656139 0.000003880 0.000000976 0.362786 107.4032 1992.1991 0.000398186 0.004362459 0.008606105 0.000003781 0.000001065 0.393397 107.7482 1992.1818 0.000403399 0.003859001 0.008838772 0.000003721 0.000001097 0.411907 108.0932 1992.1655 0.000406734 0.003759502 0.008755494 0.000003656 0.000001116 0.424067 108.4383 1992.1492 0.000411270 0.003827487 0.008683759 0.000003411 0.000001097 0.455049 108.7833 1992.1328 0.000412828 0.004220216 0.008806694 0.000003340 0.000001060 0.444087 109.1283 1992.1155 0.000435059 0.004305985 0.008640126 0.000003448 0.000001006 0.505969 109.4733 1992.0992 0.000406103 0.004009180 0.008718994 0.000003985 0.000001033 0.477032 109.8183 1992.0829 0.000419706 0.003848417 0.008656154 0.000004058 0.000001077 0.474176 110.1633 1992.0665 0.000422036 0.004077734 0.008687554 0.000003671 0.000001095 0.356646 110.5083 1992.0492 0.000429701 0.003905757 0.008753134 0.000003469 0.000001103 0.470935 110.8533 1992.0329 0.000454520 0.003990368 0.008678464 0.000003341 0.000001021 0.710693 111.1983 1992.0165 0.000446745 0.004144488 0.008679686 0.000003563 0.000001026 0.648747 111.5433 1992.0002 0.000461322 0.003950883 0.008749367 0.000003491 0.000001071 0.469304 111.8883 1991.9829 0.000438206 0.003744440 0.008760034 0.000003500 0.000001124 0.467997 112.2333 1991.9666 0.000457106 0.003643009 0.008733482 0.000003615 0.000001149 0.446267 112.5783 1991.9502 0.000428127 0.003537557 0.008659497 0.000003740 0.000001131 0.466292 112.9233 1991.9339 0.000425283 0.003831890 0.008718084 0.000003885 0.000001143 0.433780 113.2683 1991.9166 0.000435392 0.003806500 0.008774935 0.000003937 0.000001139 0.394031 113.6133 1991.9003 0.000431533 0.004196775 0.008615467 0.000004055 0.000001077 0.309032 113.9583 1991.8839 0.000411629 0.004299328 0.008608002 0.000004009 0.000001046 0.318028 114.3033 1991.8676 0.000445964 0.004024005 0.008813043 0.000004176 0.000001157 0.357655 114.6483 1991.8503 0.000446796 0.003329316 0.008795698 0.000004053 0.000001174 0.366132 114.9933 1991.8340 0.000457161 0.003458847 0.008706329 0.000004020 0.000001079 0.343462 115.3383 1991.8166 0.000467762 0.003720182 0.008710774 0.000003930 0.000001102 0.344472 115.6833 1991.8003 0.000473697 0.003313195 0.008820802 0.000003811 0.000001235 0.317331 116.0283 1991.7829 0.000467942 0.003211232 0.008803535 0.000003737 0.000001195 0.303859 116.3734 1991.7666 0.000458616 0.003368707 0.008816715 0.000004159 0.000001239 0.268982 116.7184 1991.7075 0.000480356 0.002981152 0.008875720 0.000004367 0.000001324 0.273533 117.0634 1991.6493 0.000499896 0.002896545 0.009051978 0.000004606 0.000001424 0.241024 117.4084 1991.5901 0.000506030 0.002709449 0.009130753 0.000004809 0.000001481 0.233592 117.7534 1991.5320 0.000518010 0.002874269 0.009027428 0.000005143 0.000001395 0.216563 118.0984 1991.4728 0.000530226 0.002847622 0.009149827 0.000005261 0.000001371 0.197851 118.4434 1991.4555 0.000504148 0.002657266 0.009126971 0.000005078 0.000001451 0.199354 118.7884 1991.4392 0.000489072 0.002924968 0.009019259 0.000004860 0.000001400 0.195232 119.1334 1991.4218 0.000496524 0.003192551 0.009132967 0.000005044 0.000001300 0.231694 119.4784 1991.4055 0.000477695 0.002900063 0.009094692 0.000005107 0.000001366 0.203617 119.8234 1991.3882 0.000483730 0.002968652 0.009031283 0.000005000 0.000001264 0.203806 120.1684 1991.3718 0.000495387 0.003189284 0.008832654 0.000005071 0.000001209 0.217474 120.5134 1991.3545 0.000477642 0.002835189 0.009025595 0.000005196 0.000001275 0.202912 120.8584 1991.3382 0.000491644 0.002965428 0.009070189 0.000005485 0.000001286 0.212905 121.2034 1991.3208 0.000480003 0.003270435 0.009052266 0.000005521 0.000001298 0.186631 121.5484 1991.3045 0.000447791 0.002791337 0.009086946 0.000005490 0.000001443 0.190397 121.8934 1991.2872 0.000440574 0.003290775 0.009067005 0.000005629 0.000001317 0.168453 122.2384 1991.2709 0.000428545 0.003143671 0.008983524 0.000005714 0.000001312 0.188981 122.5834 1991.2535 0.000411600 0.003078036 0.009056938 0.000005292 0.000001403 0.189167 122.9284 1991.2372 0.000422999 0.003375689 0.008974835 0.000005164 0.000001430 0.283368 123.2734 1991.2198 0.000447333 0.003190879 0.009107581 0.000005696 0.000001438 0.289793 123.6184 1991.2035 0.000420528 0.003194739 0.009043083 0.000005928 0.000001416 0.245374 123.9634 1991.1862 0.000414360 0.003135912 0.009113292 0.000006022 0.000001507 0.300716 124.3084 1991.1699 0.000400759 0.002704138 0.009318067 0.000006339 0.000001708 0.244208 124.6535 1991.1525 0.000384299 0.002359308 0.009619442 0.000005986 0.000001879 0.196656 124.9985 1991.1362 0.000362018 0.002227884 0.009399142 0.000006103 0.000001842 0.178606 125.3435 1991.1189 0.000366636 0.002635748 0.009217159 0.000007602 0.000001596 0.198326 125.6885 1991.0995 0.000390660 0.003006026 0.009059890 0.000009684 0.000001414 0.418564 126.0335 1991.0801 0.000415381 0.003019240 0.008996915 0.000010376 0.000001341 0.551641 126.3785 1991.0597 0.000390215 0.002983649 0.008927286 0.000009297 0.000001415 0.480989 126.7235 1991.0403 0.000420173 0.003395458 0.008984814 0.000006010 0.000001396 0.357467 127.0685 1991.0209 0.000424539 0.003937163 0.008769195 0.000005048 0.000001094 0.279837 127.4135 1991.0015 0.000434183 0.003731065 0.008867686 0.000004519 0.000001225 0.296242 127.7585 1990.9822 0.000404914 0.003372128 0.008876391 0.000004072 0.000001353 0.305981 128.1035 1990.9618 0.000424447 0.003869607 0.008711230 0.000003937 0.000001262 0.349114 128.4485 1990.9424 0.000430522 0.003858443 0.008786466 0.000004095 0.000001220 0.339481 128.6727 1990.9230 0.000420587 0.003403249 0.008817666 0.000004143 0.000001229 0.329858