Bear Lake, Utah-Idaho Geochemical and Mineralogical Data ----------------------------------------------------------------------- World Data Center for Paleoclimatology, Boulder and NOAA Paleoclimatology Program ----------------------------------------------------------------------- NOTE: PLEASE CITE ORIGINAL REFERENCE WHEN USING THIS DATA!!!!! NAME OF DATA SET: Bear Lake, Utah-Idaho Geochemical and Mineralogical Data LAST UPDATE: 3/2009 (Original receipt by WDC Paleo) CONTRIBUTOR: Walter E. Dean, U. S. Geological Survey, Denver, Colorado IGBP PAGES/WDCA CONTRIBUTION SERIES NUMBER: 2009-028 WDC PALEO CONTRIBUTION SERIES CITATION: Dean, W.E. 2009. Bear Lake, Utah-Idaho Geochemical and Mineralogical Data. IGBP PAGES/World Data Center for Paleoclimatology Data Contribution Series # 2009-028. NOAA/NCDC Paleoclimatology Program, Boulder CO, USA. ORIGINAL REFERENCES: Dean, W.E., R. Forester, S. Colman, A. Liu, G. Skipp, K. Simmons, P. Swarzenski, and R. Anderson. 2005. Modern and Glacial-Holocene Carbonate Sedimentation in Bear Lake, Utah-Idaho. U.S. Geological Survey Open-File Report 2005-1124. (http://pubs.usgs.gov/of/2005/1124) Dean, W., J. Rosenbaum, G. Skipp, S. Colman, R. Forester, A. Liu, K. Simmons, and J. Bischoff. 2006. Unusual Holocene and late Pleistocene carbonate sedimentation in Bear Lake, Utah and Idaho, U.S.A. Sedimentary Geology, v. 185, p. 93-112. Dean, W.E. 2009. Endogenic carbonate sedimentation in Bear Lake, Utah and Idaho over the last two glacial-interglacial cycles, in Rosenbaum, J.G., and Kaufman, D.S., eds., Paleoenvironments of Bear Lake, Utah and Idaho, and Its Catchment. Geological Society of America, Special Paper 450, ISBN: 9780813724508 Bischoff, J.L., K. Simmons, and D.D. Shamp. 2005. Geochemistry of sediments in cores and sediment traps from Bear Lake, Utah and Idaho. U.S. Geological Survey Open-File Report 2005-1215. (http://pubs.usgs.gov/of/2005/1215) GEOGRAPHIC REGION: Western North America PERIOD OF RECORD: 25 KYrBP - present FUNDING SOURCES: U.S. Geological Survey DESCRIPTION: Piston cores were collected in 1996 from three localities in Bear Lake using the University of Minnesota, Limnological Research Center's (UMN-LRC) Kullenberg coring system (Dean et al., 2006). Core BL96-1 is 5 m long from a water depth of 50 m. Core BL96-2 is 4 m long from a water depth of 40 m. Core BL96-3 is 4 m long from a water depth of 30 m. Overlapping cores provide a 25,000-year record. Unknown amounts of sediments were missing from the tops of the piston cores, so surface sediments (up to 50 cm) were collected with a gravity corer in 1998 (Dean et al., 2007). Core BL98-4 is 17 cm m long from a water depth of 30 m. Core BL98-6 is 20 cm long from a water depth of 30 m. Core BL98-9 is 30 cm long from a water depth of 40 m. Core BL98-10 is 36 cm long from a water depth of 40 m. Core BL98-12 is 38 cm long from a water depth of 30 m. Core BL98-13 is 36 cm long from a water depth of 30 m. Piston cores and gravity cores were collected at five localities at the northern end of the lake in 2002. Geochemical and mineralogical data were collected on two of the piston cores and gravity cores from the same localities. Core BL02-3PC is 475 cm long and BL02-3GC is 15 cm long, both from a water depth of 40 m. Core BL02-4PC is 380 cm long and BL02-4GC is 40 cm long, both from a water depth of 30 m. The data set includes files of carbon data, X-ray diffraction (XRD) mineralogy, carbon- and oxygen-isotope data on bulk carbonate, Sr isotope data on bulk carbonate, and HCl-leach chemistry. Not all data were collected on sediments from all cores. Bear Lake: 42°0'N, 111°20'W, 1805m elev. BEAR LAKE METHODS: Carbon Analyses Concentrations of total carbon and inorganic (total carbonate) carbon were determined by coulometry (Engleman and, others, 1985) in USGS laboratories in Denver, CO. Inorganic carbon (IC) in the untreated sample is reacted with perchloric acid to liberate CO2, which is then titrated in a coulometer cell to measure carbonate carbon. Total carbon (TC) is measured by liberating CO2 by combustion of an untreated sample and titrating the CO2. Values of organic carbon (OC) were determined by difference between TC and IC. Replicate analyses demonstrate the coulometer technique has a precision of better than ±1% for both carbonate and total carbon. Percent CaCO3 was calculated by dividing percent carbonate carbon by 0.12, the fraction of carbon in CaCO3. Reference: Engleman, E. E., Jackson, L. L., Norton, D. R., and Fischer, A. G., 1985, Determination of carbonate carbon in geological materials by coulometric titration. Chemical Geology, v. 53, p. 125-128. Isotope Analyses Measurements of ratios of stable isotopes of carbon and oxygen were made on aliquots of the carbon samples (see Dean et al., 2006, 2007 for methods). Isotope measurements on samples from the 1996 cores, 1998 cores, and sediment traps were made in the stable isotope laboratory at the University of Minnesota. Isotope measurements on samples from the 2002 cores were made in the stable isotope laboratory at the University of Arizona. Results of analyses are reported in the usual per mil (‰) d-notation relative to the Vienna Pee Dee Belemnite (VPDB) marine-carbonate standard for carbon and oxygen: d‰=[(Rsample/RVPDB)-1]x103 where R is the ratio (13C:12C) or (18O:16O). Measurements of Sr isotope ratios (86Sr/87Sr) were made on samples from six cores, in Samples were leached in 5M acetic acid, and the leachate was centrifuged and purified with conventional ion-exchange methods. Samples were loaded on a single tantalum filament with phosphoric acid. Isotope ratios were measured with an automated VG54 sector multi-collector, thermal ionization mass spectrometer in dynamic mode. Mass dependent fractionation was corrected assuming a 86Sr/87Sr ratio of 0.1194. Strontium isotope ratios are reported relative to SRM-987 standard value of 0.71025. X-ray Diffraction Analyses Semi-quantitative estimates of mineral contents in splits of the carbon samples were determined by standard X-ray diffraction (XRD) techniques (e.g., Moore and Reynolds, 1989) in USGS laboratories in Denver, CO. Each sample was packed into an aluminum holder and scanned from 15° to 50° 2Q at 2° 2Q/min using Ni-filtered, Cu-Ka radiation at 45 kv, 30 ma, and peak intensities recorded as counts per second (cps). Results are reported as the peak intensity of the main XRD peak for each mineral. Reference: Moore, D.M., and Reynolds, R.C., Jr., 1989. X-ray diffraction and identification and analysis of clay minerals. Oxford University Press, 332 pp. Inorganic Geochemical Analyses Samples for inorganic geochemical analyses were leached in 3N HCl overnight, and the supernatant was analyzed by inductively coupled, argon-plasma, atomic-emission spectrometry (ICP-AES) for major components (percent) Ca, Fe, and Mg, and minor components (parts per million, ppm) Na, Mn, Ba, Sr and Li (Bischoff et al., 2005). Reference: Bischoff, J.L., Simmons, K., and Shamp, D.D., 2005. Geochemistry of sediments in Bear Lake cores and sediment traps. U.S. Geol. Survey, Open-File Report 2005-1215. http://pubs.usgs.gov/of/2005/1215. Abbreviations: cmblf, centimeters below lake floor; ICP, inductively coupled, argon-plasma, emission spectrometry; XRD, X-ray diffraction; VPDB, Vienna Pee Dee Belemnite marine-carbonate standard for carbon and oxygen isotopes DATA: 1. BL96-3 stable isotopes Depth depth in core in cm below lake floor 13C (VPDB) delta 13C relative to standard VPDB 18O (VPDB) delta 18O relative to standard VPDB Depth 13C 18O 2 1.54 -5.82 7 1.86 -5.88 12 0.92 -7.88 27 -0.88 -11.11 32 -0.96 -11.28 37 -0.91 -10.81 42 -1.28 -7.45 47 -2.16 -9.47 52 -2.31 -9.43 57 -2.29 -9.72 62 -2.57 -9.88 67 -2.59 -10.08 72 -2.66 -9.49 77 -2.88 -9.26 82 -2.85 -9.75 87 -3.01 -10.23 92 -3.03 -9.71 97 -2.94 -9.34 102 -2.3 -9.37 107 -2.9 -9.41 112 -2.91 -9.46 117 -2.96 -9.67 122 -2.99 -9.52 127 -2.77 -9.93 132 -3 -9.63 137 -3 -9.81 142 -2.94 -9.35 147 -2.28 -9.52 152 -2.14 -9.51 157 -2.04 -9.67 162 -1.7 -9.28 167 -1.82 -9.19 172 -2.44 -10.45 182 -2.36 -9.9 187 -2.62 -9.8 188 -2.78 -9.86 193 -2.25 -9.6 198 -1.95 -9.07 203 -2.22 -9.76 208 -2.13 -9.23 213 -2.68 -9.96 218 -2.77 -9.61 223 -2.52 -10.1 228 -2.88 -9.34 233 -3.36 -10.16 238 -2.23 -9.35 243 -2.29 -9.73 248 -2.07 -9.17 253 -1.95 -8.64 258 -1.64 -8.96 263 -1.79 -9.26 268 -1.91 -9.25 273 -1.51 -8.02 278 -1.72 -7.52 283 -2.45 -10.05 294 -2.78 -9.49 299 -2.81 -9.44 304 -2.43 -9.72 309 -2.39 -9.57 314 -2.23 -9.55 319 -2.62 -9.87 324 -2.6 -9.31 329 -2.65 -9.64 334 -2.78 -10.28 339 -1.45 -8.88 344 -2.76 -9.92 349 -2.99 -10.31 354 -2.11 -8.39 359 -2.1 -9.29 364 -2.87 -10.03 369 -2.87 -9.98 374 -3.16 -10.2 384 -3.26 -9.86 389 -2.97 -9.36 389 -3.03 -9.56 394 -2.9 -9.77 399 -1.82 -7.98 404 -1.67 -8.1 2. BL96-3 XRD Depth depth in core in cm below lake floor aragonite (cps) XRD aragonite peak intensity in counts per second quartz (cps) XRD quartz peak intensity in counts per second calcite (cps) XRD calcite peak intensity in counts per second dolomite (cps) XRD dolomite peak intensity in counts per second feldspar (cps) XRD feldspar peak intensity in counts per second Depth Arag. Quartz Calcite Dolo. Feldspar 3 1158 1017 1986 238 238 11 342 1630 3459 288 189 15 203 2294 4788 405 304 19 258 2088 3545 455 223 23 179 2163 3493 522 333 27 0 2713 3411 346 328 31 0 2669 3322 510 255 35 0 3155 2689 562 316 39 0 1288 4966 1641 368 43 0 5591 463 751 399 47 0 5659 857 795 507 51 0 4538 977 733 386 55 0 4631 911 577 372 59 0 4756 1169 691 385 63 0 3948 1217 439 296 67 0 4532 299 443 299 71 0 3878 1376 655 339 75 0 3982 1293 646 265 79 0 4866 1267 446 337 83 0 4534 1297 616 315 86 0 4464 1345 516 415 87 0 4252 1188 463 321 91 0 2435 703 214 172 95 0 2400 762 411 179 99 0 1976 616 261 186 103 0 1920 612 298 188 107 0 2089 714 224 177 111 0 3649 1136 358 294 115 0 4531 1182 420 460 119 0 3604 1128 454 395 123 0 3670 1192 429 314 127 0 3777 1209 356 335 131 0 3894 1193 394 315 135 0 4030 1177 400 300 139 0 3736 1118 438 318 143 0 4762 1279 435 340 147 0 6173 555 769 429 151 0 5368 962 853 496 155 0 5229 704 614 375 159 0 4752 910 516 625 163 0 7268 657 572 360 167 0 5671 875 924 648 171 0 4499 1243 551 385 175 0 4465 1562 426 426 179 0 5555 1035 541 318 183 0 5124 1063 517 369 187 0 4558 1168 514 411 192 0 4614 904 492 346 196 0 6443 222 574 426 200 0 5322 963 703 1101 204 0 6348 936 532 587 208 0 4508 1065 650 403 212 0 4706 1354 550 536 216 0 4066 1324 523 337 220 0 4328 1426 363 338 224 0 6298 1121 552 320 228 0 4489 1188 450 650 232 0 3749 1339 482 311 236 0 4904 1219 490 336 240 0 5760 1121 725 494 244 0 5573 769 593 336 248 0 5795 633 683 383 252 0 5688 471 650 585 256 0 5785 945 779 448 260 0 6264 859 841 447 264 0 5541 780 860 955 268 0 5646 924 470 420 272 0 5628 1013 756 402 276 0 5855 523 658 405 280 0 4668 452 532 372 284 0 3604 982 627 575 288 0 3948 913 445 331 289 0 4150 1040 355 260 293 0 3195 925 430 247 301 0 3511 942 602 271 305 0 3378 598 367 290 309 0 4726 804 926 436 313 0 3076 861 387 352 317 0 5283 840 458 382 321 0 3364 996 503 1779 325 0 4224 1067 519 418 329 0 4330 950 295 321 333 0 4515 937 820 442 337 0 4657 1074 523 389 341 0 4092 991 385 373 345 0 4076 1009 387 316 349 0 3480 1189 939 423 353 0 4055 485 508 404 357 0 4890 375 472 1167 361 0 4343 1095 381 812 365 0 3972 1115 353 467 369 0 3211 850 349 233 373 0 3459 1101 415 290 377 0 3376 1097 388 643 381 0 3299 904 344 755 385 0 2990 1081 503 268 3. BL96-3 leach chemistry Depth depth in core in cm below lake floor Na (ppm) parts per million sodium by ICP K (ppm) parts per million potassium by ICP Ca (%) percent calcium by ICP Mg (%) percent magnesium by ICP Fe (%) percent iron by ICP Ti (ppm) parts per million titanium by ICP Mn (ppm) parts per million manganese by ICP Ba (ppm) parts per million barium by ICP Sr (ppm) parts per million strontium by ICP Li (ppm) parts per million lithium by ICP Depth Na K Ca% Mg% Fe% Ti Mn Ba Sr Li 0 824 723 25.28 1.13 0.56 62 339 297 723 11 3 831 101 27.36 1.31 0.42 68 528 259 428 7 7 545 231 24.41 1.18 0.99 73 881 266 494 11 11 379 210 21.83 1.06 1.49 82 1186 233 390 8 15 324 465 15.34 1.01 2.01 73 883 162 220 8 19 347 863 15.45 0.99 2.37 68 857 160 213 7 23 298 794 15.49 0.99 2.02 72 906 163 202 8 27 368 791 13.13 0.99 2.16 87 734 152 161 6 31 308 781 12.7 1.08 2.67 85 906 141 149 7 35 318 812 10.22 1.25 2.86 97 459 119 117 6 39 272 517 5.73 1.47 3.28 106 277 90 65 6 43 278 901 2.86 1.25 3.44 100 295 89 41 9 47 279 850 3.84 1.16 2.85 84 369 100 54 8 51 266 1094 4.16 1.15 2.51 83 478 112 56 9 55 266 1265 4.17 1.1 2.34 75 369 116 57 8 59 252 860 4.68 1.02 2 67 361 116 62 10 63 253 1145 4.99 0.93 1.82 57 403 113 65 10 67 242 768 5.23 0.97 1.65 58 564 124 66 9 71 275 578 5.24 0.95 1.47 53 616 114 67 8 75 227 1043 5.1 0.9 1.47 49 500 111 68 9 79 264 1074 4.93 0.92 1.5 51 476 121 64 8 83 255 1233 4.82 0.93 1.49 49 432 130 63 10 86 248 777 4.78 0.89 1.58 48 487 131 61 10 87 265 1064 4.73 0.88 1.62 50 487 136 61 9 91 268 828 4.89 0.85 1.54 48 469 116 63 7 95 258 601 4.95 0.85 1.44 42 476 101 66 10 99 233 1041 4.79 0.83 1.49 39 510 135 65 10 103 231 1076 4.41 0.85 1.52 43 492 145 59 10 107 180 1161 4.33 0.78 1.5 38 550 144 60 7 111 214 748 4.33 0.79 1.7 41 625 144 61 9 115 203 1077 4.67 0.83 1.53 43 537 143 64 8 119 195 1281 4.72 0.85 1.6 44 550 159 65 9 123 212 881 4.95 0.87 1.55 47 585 150 69 8 127 213 358 5.15 0.85 1.53 45 606 159 69 10 131 235 828 4.65 0.8 1.54 44 494 155 63 8 135 223 662 4.71 0.79 1.45 40 498 145 65 7 139 233 1094 4.56 0.79 1.52 43 468 155 63 10 143 229 454 4.64 0.9 1.73 58 507 155 64 9 147 223 994 3.13 1.04 1.92 73 528 155 47 8 151 282 980 3.79 0.97 1.7 64 493 145 55 9 155 261 1137 3.48 1 1.78 70 433 158 51 7 159 264 626 4.04 1.01 1.86 68 468 168 58 11 163 275 759 3.51 1.01 1.9 75 502 156 52 9 167 246 522 3.82 1.01 1.9 74 633 184 57 9 171 243 822 4.72 0.92 1.74 66 550 162 65 8 175 241 955 5.92 0.92 1.68 65 618 164 80 10 179 248 831 4.36 0.8 1.62 55 531 162 60 8 183 229 1294 4.18 0.88 1.76 58 558 150 58 9 187 258 1126 4.59 0.87 1.68 59 570 142 59 9 188 288 715 4.44 0.84 1.68 54 593 154 58 7 192 306 1170 4.03 0.84 1.67 55 557 158 54 8 196 290 827 3.41 0.91 1.85 64 451 148 49 6 200 264 690 3.91 0.96 1.66 67 441 160 53 8 204 257 826 3.94 0.92 1.55 61 483 147 53 9 208 237 1187 4.3 0.88 1.59 59 594 139 56 8 212 230 1129 4.35 0.8 1.53 54 569 141 57 8 216 220 1300 4.75 0.8 1.53 52 526 147 62 8 220 234 339 4.82 0.78 1.47 51 594 148 62 9 224 275 1256 4.8 0.82 1.45 54 563 133 61 10 228 261 610 4.81 0.81 1.42 50 710 147 63 9 232 216 1114 4.94 0.74 1.4 46 702 149 62 8 236 240 981 4.61 0.84 1.55 54 619 149 64 6 240 245 1200 4.06 0.9 1.61 61 579 158 56 7 244 209 978 3.65 0.9 1.69 61 535 153 53 8 248 222 681 3.55 0.94 1.79 65 599 158 52 6 252 258 830 3.44 0.96 1.65 67 533 161 49 8 256 238 715 3.35 0.97 1.8 70 485 164 50 7 260 251 949 3.3 1.1 1.92 77 599 174 49 5 264 229 682 3.7 1.02 1.9 75 610 175 54 5 268 228 807 3.85 1.01 1.79 72 562 177 56 6 272 231 795 3.61 1.04 1.75 73 506 175 52 6 276 222 470 2.78 1.02 1.9 74 530 178 44 4 280 248 1072 2.59 0.99 2.03 78 583 171 43 5 284 237 323 4.63 0.83 1.83 58 634 171 63 5 288 250 515 4.93 0.88 1.69 60 685 180 65 6 289 228 776 4.59 0.77 1.64 52 751 127 62 4 293 222 924 5.23 0.91 1.59 52 936 154 73 5 297 230 704 5.14 0.89 1.53 55 825 150 69 4 301 228 199 5.14 0.9 1.54 56 869 166 69 4 305 248 1032 3.94 0.88 1.87 64 641 166 57 6 309 251 1175 4.45 0.92 1.68 67 833 181 61 5 313 248 686 4.4 0.86 1.84 66 699 180 62 6 317 216 882 4.35 0.87 1.57 63 586 162 60 4 321 242 440 4.9 0.81 1.59 52 673 167 64 5 325 263 605 4.92 0.82 1.76 51 992 173 66 4 329 260 661 4.63 0.78 1.6 56 664 175 62 6 333 249 954 4.43 0.84 1.8 66 589 178 62 7 337 232 597 4.75 0.8 1.74 61 580 162 66 5 341 251 935 4.44 0.8 1.81 62 580 176 62 6 345 280 1109 4.52 0.83 1.81 60 641 165 64 6 349 266 1138 4.93 0.82 1.77 59 762 185 68 7 353 247 882 2.99 0.94 1.92 75 589 168 48 8 357 254 1087 2.66 0.96 2.1 78 499 178 45 5 361 254 964 4.87 0.9 1.64 59 743 173 66 6 365 296 847 4.93 0.78 1.64 53 774 167 68 5 369 233 715 5.13 0.85 1.72 55 867 160 73 7 373 287 966 5.12 0.8 1.66 49 827 163 73 5 377 278 747 4.98 0.78 1.63 49 731 170 69 5 381 262 916 4.36 0.74 1.69 46 787 178 60 7 385 259 1105 5.32 0.82 1.69 42 1089 165 73 6 389 442 776 5.13 0.79 1.62 47 1019 138 73 7 394 370 1046 4.66 0.76 1.61 47 869 160 66 8 397 405 1101 4.6 0.79 1.61 54 566 170 67 5 401 403 513 2.68 1.02 2.06 78 512 156 48 6 405 460 873 2.93 0.99 1.96 72 550 166 51 6 4. BL96-3 ICP Depth depth in core in cm below lake floor % Al percent aluminum by ICP % Ca percent calcium by ICP % Mg percent magnesium by ICP % Fe percent iron by ICP % K percent potassium by ICP % Ti percent titanium by ICP % P percent phosphorus by ICP ppm Mn parts per million strontium by ICP % S percent sulfur by ICP ppm Ag parts per million silver by ICP ppm Co parts per million cobalt by ICP ppm Cr parts per million chromium by ICP ppm Cu parts per million copper by ICP ppm Li parts per million lithtium by ICP ppm Ni parts per million nickel by ICP ppm Pb parts per million lead by ICP ppm Sr parts per million strontium by ICP ppm V parts per million vanadium by ICP ppm Y parts per million yttrium by ICP ppm Zn parts per million zinc by ICP Depth Al %Ca %Mg %Fe %K %Ti %P Mn %S Ag Co Cr Cu Li Ni Pb Sr V Y Zn 0 1.86 22.87 1.2 0.78 0.68 0.08 0.045 311 0.35 -0.4 2 23 13 20 6 7 830 19 6 29 3 1.28 24.93 1.33 0.52 0.55 0.06 0.029 477 0.42 -0.4 2 17 3 14 3 -5 514 12 4 16 11 2.62 19.55 1.22 1.41 0.94 0.11 0.06 1061 0.75 -0.4 2 29 8 21 10 -5 469 30 7 39 15 4.67 13.59 1.49 2.29 1.54 0.18 0.075 839 1.02 -0.4 2 46 14 34 17 -5 299 53 12 63 19 4.77 13.79 1.48 2.46 1.53 0.18 0.072 819 1.17 -0.4 2 45 14 35 17 8 296 54 12 64 23 4.87 13.84 1.48 2.35 1.53 0.18 0.075 869 1.01 -0.4 2 45 14 35 18 -5 283 55 12 63 27 4.96 11.46 1.48 2.5 1.52 0.19 0.072 712 0.89 0.4 2 47 14 34 17 -5 248 56 13 64 31 4.85 11.13 1.57 2.67 1.59 0.19 0.08 849 1.04 0.4 2 49 15 34 18 6 230 58 14 66 35 4.85 8.89 1.67 2.71 1.65 0.2 0.087 455 1.15 0.4 3 54 16 33 20 6 195 59 15 67 39 5.36 6.23 2.04 3.18 1.87 0.23 0.09 327 1.49 0.5 4 54 17 34 20 8 163 63 17 68 43 6.79 3.28 2.02 3.6 2.23 0.29 0.102 364 1.22 0.5 6 65 20 44 27 11 153 78 19 86 47 7.01 4.16 1.95 3.29 2.26 0.28 0.106 427 0.76 0.5 6 68 21 46 28 13 160 82 19 88 51 6.99 4.76 1.94 3.09 2.23 0.28 0.107 505 0.48 0.5 4 67 20 46 26 17 156 82 19 88 55 7.06 4.71 1.89 3.1 2.24 0.28 0.11 418 0.44 0.5 5 66 20 46 29 15 154 84 19 90 59 7.34 5.28 1.86 3.05 2.31 0.28 0.113 409 0.33 0.5 4 72 22 48 28 17 159 89 20 95 63 7.48 5.41 1.77 3.11 2.34 0.28 0.114 420 0.32 0.5 5 57 23 48 30 17 155 90 20 96 67 7.3 5.55 1.77 2.95 2.34 0.27 0.114 565 0.16 0.5 5 67 22 46 29 17 154 89 19 91 71 7.445 5.6 1.8 2.96 2.37 0.27 0.1125 643.5 0.1 0.45 4 72.5 22.5 47.5 28.5 15 159 88 19 94.5 75 7.59 5.44 1.75 3.02 2.46 0.27 0.116 532 0.15 0.4 5 70 21 48 30 19 156 88 19 94 79 7.49 5.25 1.74 3 2.41 0.27 0.116 481 0.12 0.5 4 67 23 47 29 13 152 89 19 95 83 7.55 5.36 1.8 3.07 2.41 0.27 0.119 471 0.12 0.5 5 55 22 48 30 13 157 90 19 95 86 7.3 5.1 1.7 3.02 2.3 0.27 0.116 500 0.09 0.5 4 57 22 46 29 15 148 88 19 94 87 6.95 4.85 1.57 2.94 2.26 0.25 0.107 603 0.07 0.4 5 66 20 40 27 17 150 82 18 84 91 7.28 5.2 1.65 3 2.23 0.27 0.124 492 0.09 0.5 5 62 21 46 31 15 153 92 20 96 95 7.77 5.23 1.73 3.11 2.45 0.27 0.119 508 0.06 0.5 5 73 23 48 30 17 149 93 19 97 99 8.08 5.1 1.75 3.24 2.65 0.27 0.116 523 0.07 0.4 5 66 23 48 30 20 149 92 19 96 103 8.49 4.93 1.85 3.38 2.85 0.28 0.122 539 0.07 0.5 5 76 24 49 31 18 150 96 19 97 107 8.56 4.71 1.75 3.37 2.92 0.26 0.116 565 0.05 0.5 6 68 22 47 32 24 144 96 18 94 111 8.24 4.71 1.74 3.33 2.8 0.26 0.132 613 0.06 0.4 5 72 22 46 31 15 145 93 18 89 115 7.65 4.9 1.7 3.15 2.47 0.26 0.119 555 0.06 0.4 5 72 22 47 30 15 146 91 19 94 119 7.84 5.03 1.72 3.17 2.6 0.26 0.119 557 0.06 0.4 5 70 21 45 31 19 148 92 18 92 123 7.25 5.12 1.67 3.04 2.3 0.26 0.12 594 0.07 0.4 5 71 21 45 29 17 149 90 19 93 127 6.98 5.13 1.62 2.97 2.27 0.25 0.117 595 0.06 0.4 4 64 19 44 29 17 144 87 19 89 131 7.4 4.81 1.62 3.05 2.44 0.25 0.113 516 0.07 0.4 6 69 20 43 30 17 141 89 18 88 135 8.76 5.03 1.8 3.39 2.89 0.29 0.113 553 0.06 0.5 4 82 23 48 31 16 162 95 20 95 139 9 5.07 1.86 3.58 3.09 0.29 0.109 546 0.07 0.4 4 71 23 48 32 16 163 97 19 95 143 8.3 5.22 1.9 3.47 2.64 0.32 0.113 564 0.07 0.5 3 74 22 49 31 15 178 92 20 98 147 7.4 3.79 1.97 3.42 2.41 0.31 0.11 612 0.1 0.5 4 64 20 45 27 15 174 85 20 88 151 7.63 4.27 1.91 3.29 2.4 0.31 0.117 554 0.09 0.5 3 69 21 46 28 19 168 90 21 92 155 7.35 3.87 1.89 3.25 2.31 0.3 0.114 501 0.11 0.6 4 69 20 44 29 15 168 88 21 89 159 7.03 4.32 1.82 3.19 2.22 0.29 0.107 525 0.11 0.5 4 66 20 43 27 17 166 85 20 88 163 6.79 3.82 1.78 3.15 2.14 0.29 0.111 527 0.09 0.5 4 64 19 42 28 22 163 85 20 85 171 7.65 5.33 1.88 3.29 2.45 0.31 0.113 622 0.1 0.5 3 69 22 48 28 17 189 87 20 89 175 7.54 6.45 1.85 3.26 2.43 0.3 0.11 700 0.11 0.5 3 63 21 48 27 18 198 85 20 87 179 8.15 4.89 1.78 3.38 2.64 0.305 0.119 605 0.08 0.5 4.5 71.5 21.5 47 30.5 17.5 171.5 91.5 20.5 93 183 7.73 4.7 1.81 3.3 2.5 0.3 0.117 623 0.08 0.5 4 72 21 45 30 18 171 91 21 90 187 7.72 5.05 1.76 3.24 2.48 0.3 0.113 613 0.08 0.5 5 71 21 44 30 18 170 89 21 90 192 7.94 4.41 1.77 3.29 2.62 0.29 0.117 586 0.08 0.6 4 56 22 44 31 16 160 90 20 88 196 7.13 3.77 1.75 3.25 2.26 0.29 0.113 500 0.1 0.5 5 64 20 44 30 20 154 88 21 87 200 7.55 4.67 1.92 3.23 2.43 0.31 0.113 540 0.09 0.5 3 70 22 45 27 16 183 85 21 87 204 7.84 4.84 1.94 3.31 2.53 0.32 0.114 579 0.1 0.5 4 70 22 47 30 16 183 87 21 88 208 7.91 5.16 1.89 3.33 2.51 0.32 0.12 694 0.07 0.5 4 69 21 48 29 18 181 89 22 90 212 7.91 5.01 1.79 3.3 2.58 0.3 0.12 654 0.06 0.5 4 53 21 46 29 18 172 90 20 90 216 7.71 5.25 1.72 3.2 2.44 0.3 0.124 589 0.07 0.5 5 74 21 46 31 16 168 90 21 92 220 8.03 5.28 1.76 3.28 2.6 0.29 0.124 657 0.07 0.5 4 57 22 46 31 18 172 93 20 92 224 7.36 5.14 1.69 3.07 2.32 0.28 0.12 594 0.07 0.5 4 57 20 43 30 19 163 90 20 89 228 7.34 5.12 1.68 3.05 2.29 0.29 0.121 741 0.06 0.5 4 57 20 44 30 16 163 90 21 89 232 7.65 4.97 1.56 3.03 2.45 0.28 0.117 715 0.07 0.4 4 67 19 43 32 19 149 89 20 87 236 7.7 5.08 1.77 3.18 2.46 0.29 0.123 659 0.07 0.5 4 73 22 46 28 14 170 90 21 87 240 7.83 4.91 1.91 3.29 2.52 0.31 0.124 650 0.08 0.5 4 74 21 47 29 19 188 88 21 90 244 7.82 4.24 1.86 3.31 2.47 0.31 0.12 627 0.08 0.5 4 73 21 47 28 19 174 90 21 92 248 7.58 4.2 1.88 3.31 2.4 0.3 0.117 677 0.11 0.5 5 75 20 46 29 19 173 88 21 87 252 6.89 3.89 1.76 3.02 2.2 0.29 0.113 575 0.09 0.5 4 67 19 41 27 19 164 82 20 81 256 7.16 3.86 1.83 3.19 2.26 0.3 0.117 549 0.1 0.5 5 69 20 43 28 21 167 85 21 86 260 7.13 3.62 1.87 3.17 2.27 0.3 0.114 625 0.08 0.5 5 68 20 42 27 21 173 83 21 82 264 6.9 3.94 1.75 3.1 2.18 0.29 0.113 624 0.1 0.5 5 69 19 41 28 15 168 83 21 82 268 6.57 4.02 1.67 2.94 2.08 0.28 0.111 553 0.1 0.5 5 65 18 39 27 20 162 81 20 81 272 6.6 3.73 1.69 2.94 2.08 0.27 0.118 510 0.11 0.5 5 51 18 39 28 22 158 83 21 79 276 7.43 3.03 1.75 3.07 2.13 0.31 0.113 600 0.11 0.5 6 66 21 44 28 19 163 82 21 81 280 7.58 2.98 1.82 3.28 2.26 0.34 0.114 663 0.08 0.5 6 68 22 47 28 19 173 85 21 84 284 8.08 5.24 1.69 3.23 2.43 0.31 0.115 695 0.1 0.4 5 67 24 46 28 16 179 87 20 83 288 7.21 5.39 1.64 3 2.3 0.3 0.11 690 0.08 0.5 5 46 22 44 27 17 175 85 19 81 289 7.59 5.16 1.63 3.18 2.4 0.3 0.121 752 0.07 0.5 7 50 21 48 31 18 171 91 19 90 293 7.54 5.71 1.71 2.97 2.28 0.3 0.121 961 0.07 0.4 5 49 20 46 29 16 180 87 20 85 297 7.1 5.27 1.58 2.79 2.15 0.28 0.114 785 0.06 0.4 5 49 19 41 27 17 168 83 19 78 301 6.99 5.4 1.61 2.77 2.09 0.27 0.114 803 0.08 0.4 5 50 19 41 27 17 171 82 19 79 305 7.56 4.13 1.71 3.15 2.23 0.3 0.115 688 0.09 0.4 5 69 22 46 27 17 170 85 19 82 309 7.32 5.1 1.72 2.97 2.22 0.3 0.114 868 0.06 0.4 6 65 20 44 27 17 185 80 19 80 313 7.65 5.11 1.7 3.12 2.29 0.3 0.111 724 0.06 0.4 6 67 21 47 28 17 180 83 19 82 317 7.19 5.1 1.64 2.94 2.25 0.29 0.114 633 0.08 0.5 5 51 20 44 27 17 184 80 19 81 321 7.4 5.47 1.63 3.05 2.34 0.29 0.115 688 0.06 0.4 5 47 20 45 27 16 172 84 19 82 325 7.15 5.27 1.56 3.1 2.41 0.27 0.114 943 0.06 0.4 6 48 20 44 29 16 165 86 17 83 329 7.08 4.88 1.48 2.91 2.21 0.27 0.111 621 0.05 0.4 6 47 18 42 29 17 163 84 19 78 333 6.94 4.86 1.54 2.98 2.04 0.28 0.118 568 0.06 0.4 5 50 21 44 28 19 170 86 20 83 337 7.155 5.09 1.52 2.94 2.11 0.275 0.117 574 0.06 0.4 6 60 19.5 44 28.5 18 166 85.5 20 84 341 7.85 5.1 1.64 3.18 2.37 0.29 0.116 621 0.06 0.4 5 72 22 48 29 18 179 87 20 86 345 7.88 5.29 1.7 3.23 2.42 0.3 0.117 681 0.07 0.4 6 71 21 48 28 19 181 87 20 85 349 7.5 5.5 1.62 3.07 2.27 0.28 0.116 747 0.06 0.4 6 70 20 47 28 17 175 84 20 85 353 7.17 3.39 1.76 3.25 2.24 0.31 0.116 597 0.06 0.5 6 51 19 47 28 19 174 88 20 86 357 6.82 3.01 1.68 3.19 2.09 0.28 0.113 522 0.1 0.4 7 56 17 43 29 19 166 85 21 82 361 6.54 5.15 1.53 2.74 2 0.25 0.113 659 0.06 0.4 7 48 18 41 28 16 167 80 19 79 365 7.24 5.15 1.54 2.95 2.23 0.25 0.121 703 0.06 0.4 7 51 18 44 30 19 157 88 19 87 369 7.23 5.4 1.6 2.92 2.16 0.26 0.12 786 0.06 0.4 6 73 20 46 28 19 166 87 20 86 373 8.02 5.82 1.69 3.16 2.52 0.27 0.12 815 0.06 0.4 6 75 21 50 29 18 178 89 20 85 377 8.1 5.53 1.65 3.16 2.66 0.26 0.112 740 0.06 0.4 6 70 20 47 29 18 167 87 19 83 381 8.43 4.92 1.65 3.28 2.94 0.25 0.112 736 0.05 0.4 8 60 20 46 31 18 155 88 18 82 385 7.9 5.72 1.68 3.13 2.57 0.25 0.12 985 0.06 0.4 7 61 19 48 29 17 161 88 19 88 389 7.1 5.51 1.59 3.03 2.41 0.25 0.12 884 0.06 0.4 7 62 18 47 30 17 163 90 18 93 393 7.44 4.94 1.57 3.05 2.59 0.24 0.114 751 0.06 0.4 8 51 18 44 31 17 154 89 18 82 397 7.14 4.88 1.54 2.9 2.29 0.25 0.119 527 0.06 0.4 6 52 17 44 30 19 158 88 20 83 401 6.32 2.8 1.63 2.94 1.92 0.26 0.113 473 0.13 0.4 9 53 15 42 29 20 151 84 20 79 405 6.3 2.95 1.6 2.82 1.88 0.25 0.13 486 0.11 0.4 9 51 15 41 29 19 149 85 21 81