# Baradla Cave Geochemical Data from 129000 to 108800 Cal Yr BP #---------------------------------------------------------------------------------------- # World Data Service for Paleoclimatology, Boulder # and # NOAA Paleoclimatology Program #---------------------------------------------------------------------------------------- # Template Version 4.0 # Encoding: UTF-8 # NOTE: Please cite original publication, NOAA Landing Page URL, dataset and publication DOIs (where available), and date accessed when using downloaded data. # If there is no publication information, please cite Investigator, Title, NOAA Landing Page URL, and date accessed. # # Description/Documentation lines begin with # # Data lines have no # # # NOAA_Landing_Page: https://www.ncei.noaa.gov/access/paleo-search/study/40173 # Landing_Page_Description: NOAA Landing Page of this data file's parent study, which includes all study metadata. # # Study_Level_JSON_Metadata: https://www.ncei.noaa.gov/pub/data/metadata/published/paleo/json/noaa-cave-40173.json # Study_Level_JSON_Description: JSON metadata of this data file's parent study, which includes all study metadata. # # Data_Type: Speleothems # # Dataset_DOI: # # Science_Keywords: #----------------------------------------- # Resource_Links # # Data_Download_Resource: https://www.ncei.noaa.gov/pub/data/paleo/speleothem/SISAL-v3/noaa_templates/Demeny2017-BAR-II#B.txt # Data_Download_Description: NOAA Template File; BAR-II#B Speleothem Geochemical Data # # Related_Online_Resource: https://www.ncei.noaa.gov/access/paleo-search/study/39799 # Related_Online_Description: URL; SISAL v3 Database Landing Page # #----------------------------------------- # Contribution_Date # Date: 2024-09-02 #----------------------------------------- # File_Last_Modified_Date # Date: 2024-12-21 #----------------------------------------- # Title # Study_Name: Baradla Cave Geochemical Data from 129000 to 108800 Cal Yr BP #----------------------------------------- # Investigators # Investigators: Demény, A.; Kern, Z.; Czuppon, G.; Németh, A.; Leél-Őssy, S.; Siklósy, Z.; Lin, K.; Hu, H.-M.; Shen, C.-C.; Vennemann, T. W.; Haszpra, L. #----------------------------------------- # Description_Notes_and_Keywords # Description: Data contributed as part of SISAL v3 Global Speleothem Isotope and Trace Element Database (https://doi.org/10.25921/jajq-qg60). Notes from the SISAL database: Entity BAR-II#B (SISAL entity_id = 160) had two or more isotope values (d18O and d13C) at depth_sample = 234.5, 232.4, 231.8, 222.95, 222, 183, 182.2, 179.75, 177.4, 172, 162.6, 133.4, 130.6, 129.5, 128.5, 122.4, 120.5, 114.9, 112.1, 103.6, 84.15, 82.05, 80.85, 56.05, 38.6, 20.05mm; these were averaged.\\ Entity NU2 (entity_id = 397): C14 date at 27mm was not calibrated as it was determined as the location of the 1965 bomb peak. In the original paper, only the recounted 2016 lamina data was present whereas the average of three counts is shown here to include lamina age uncertainty. #----------------------------------------- # Publication # Authors: Demény, Attila; Zoltán Kern; György Czuppon; Alexandra Németh; Szabolcs Leél-Őssy; Zoltán Siklósy; Ke Lin; Hsun-Ming Hu; Chuan-Chou Shen; Torsten W. Vennemann; László Haszpra # Published_Date_or_Year: 2017 # Published_Title: Stable isotope compositions of speleothems from the last interglacial – Spatial patterns of climate fluctuations in Europe # Journal_Name: Quaternary Science Reviews # Volume: 161 # Edition: # Issue: # Pages: 68-80 # Report_Number: # DOI: 10.1016/j.quascirev.2017.02.012 # Online_Resource: # Full_Citation: Demény, A., Kern, Z., Czuppon, G., Németh, A., Leél-Őssy, S., Siklósy, Z., Lin, K., Hu, H.-M., Shen, C.-C., Vennemann, T. W. and Haszpra, L.: Stable isotope compositions of speleothems from the last interglacial – Spatial patterns of climate fluctuations in Europe, Quat. Sci. Rev., 161, 68–80, 2017. # Abstract: #----------------------------------------- # Publication # Authors: Hatvani, István Gábor; Zoltán Kern; Szabolcs Leél-Őssy; Attila Demény # Published_Date_or_Year: 2018 # Published_Title: Speleothem stable isotope records for east-central Europe: resampling sedimentary proxy records to obtain evenly spaced time series with spectral guidance # Journal_Name: Earth System Science Data # Volume: 10 # Edition: # Issue: 1 # Pages: 139-149 # Report_Number: # DOI: 10.5194/essd-10-139-2018 # Online_Resource: # Full_Citation: Hatvani, I. G., Kern, Z., Leél-Őssy, S. and Demény, A.: Speleothem stable isotope records for east-central Europe: resampling sedimentary proxy records to obtain evenly spaced time series with spectral guidance, Earth Syst. Sci. Data, 10(1), 139–149, 2018. # Abstract: #----------------------------------------- # Publication # Authors: Kaushal, Nikita, Franziska A. Lechleitner, Micah Wilhelm, Khalil Azennoud, Janica C. Bühler, Kerstin Braun, Yassine Ait Brahim, Andy Baker, Yuval Burstyn, Laia Comas-Bru, Jens Fohlmeister, Yonaton Goldsmith, Sandy P. Harrison, István G. Hatvani, Kira Rehfeld, Magdalena Ritzau, Vanessa Skiba, Heather M. Stoll, József G. Szucs, Péter Tanos, Pauline C. Treble, Vitor Azevedo, Jonathan L. Baker, Andrea Borsato, Sakonvan Chawchai, Andrea Columbu, Laura Endres, Jun Hu, Zoltán Kern, Alena Kimbrough, Koray Koç, Monika Markowska, Belen Martrat, Syed Masood Ahmad, Carole Nehme, Valdir Felipe Novello, Carlos Pérez-Mejías, Jiaoyang Ruan, Natasha Sekhon, Nitesh Sinha, Carol V. Tadros, Benjamin H. Tiger, Sophie Warken, Annabel Wolf, Haiwei Zhang, and SISAL Working Group members # Published_Date_or_Year: 2024 # Published_Title: SISALv3: a global speleothem stable isotope and trace element database # Journal_Name: Earth System Science Data # Volume: 16 # Edition: # Issue: # Pages: 1933-1963 # Report_Number: # DOI: 10.5194/essd-16-1933-2024 # Online_Resource: # Full_Citation: # Abstract: Palaeoclimate information on multiple climate variables at different spatiotemporal scales is becoming increasingly important to understand environmental and societal responses to climate change. A lack of high-quality reconstructions of past hydroclimate has recently been identified as a critical research gap. Speleothems, with their precise chronologies, widespread distribution, and ability to record changes in local to regional hydroclimate variability, are an ideal source of such information. Here, we present a new version of the Speleothem Isotopes Synthesis and AnaLysis database (SISALv3), which has been expanded to include trace element ratios and Sr isotopes as additional, hydroclimate-sensitive geochemical proxies. The oxygen and carbon isotope data included in previous versions of the database have been substantially expanded. SISALv3 contains speleothem data from 365 sites from across the globe, including 95 , 85 , 52 , 25 , 29 , and 14 Sr-isotope records. The database also has increased spatiotemporal coverage for stable oxygen (892) and carbon (620) isotope records compared with SISALv2 (which consists of 673 and 430 stable oxygen and carbon records, respectively). Additional meta information has been added to improve the machine-readability and filtering of data. Standardized chronologies are included for all new entities along with the originally published chronologies. Thus, the SISALv3 database constitutes a unique resource of speleothem palaeoclimate information that allows regional to global palaeoclimate analyses based on multiple geochemical proxies, permitting more robust interpretations of past hydroclimate and comparisons with isotope-enabled climate models and other Earth system and hydrological models. The database can be accessed at https://doi.org/10.5287/ora-2nanwp4rk (Kaushal et al., 2024). #----------------------------------------- # Funding_Agency # Funding_Agency_Name: # Grant: #----------------------------------------- # Site_Information # Site_Name:Baradla Cave # Location:Hungary # Northernmost_Latitude:48.4667 # Southernmost_Latitude:48.4667 # Easternmost_Longitude:20.5 # Westernmost_Longitude:20.5 # Elevation_m:375 #----------------------------------------- # Data_Collection # Collection_Name: BAR-II#B isotopes Demény2017 SISAL v3 # First_Year: 128125 # Last_Year: 108757 # Time_Unit: Cal Yr BP # Core_Length_m: # Parameter_Keywords: oxygen isotopes, carbon isotopes # Notes: Contact: István G. Hatvani; Type: stalagmite; Dist. from entrance (m): 1000; Entity Status: current; Depth Reference: from top; Overlying Bedrock Thickness (m): 150; Drip Type: unknown; Drip Height: 15; Drip Water Equilibrium Studies: unknown; Trace Elements Measured: ; Organics Measured: no; Fluid Inclusions Measured: yes; Fabric Studies: yes; Clumped Isotopes Measured: no; Noble Gases Measured: no; C14 Measured: no; ODL Measurements: no; Mg/Ca Measured: no; Type from WOKAM: discontinuous carbonate; Vegetation Type: deciduous; Land Use: forest; Copernicus lcc: cultivated and managed vegetation / agriculture; Cover Type: patchy; Host Rock Trace Elements: yes; Drip Water Trace Elements: yes; Isotope Standard: Vienna-PDB; d18O dripwater carbonate difference: NA; Trace Elements Datafile: no; Trace Elements Metadata File: NA; Cave Map: no; Entity Scan: no #----------------------------------------- # Chronology_Information # Chronology: Uranium-Thorium # Chronology_Download_Resource: https://www.ncei.noaa.gov/pub/data/paleo/templates/noaa-wds-paleo-uth-terms.csv # Chronology_Download_Description: Uranium-Thorium terms and definitions. # Chronology_Notes: Metadata and data from SISAL v3 database. # Rejection_Rationale: # 238U_Decay_Constant: Cheng et al. 2013 # 234U_Decay_Constant: Cheng et al. 2013 # 230Th_Decay_Constant: Cheng et al. 2013 # Initial_230Th/232Th: # Initial_230Th/232Th_Method: # Age_Model_Method: # Missing_Values: NA # Chronology_Table: # date_type depth_top_mm thick_mm samp_id material_dated weight_mg age_uncorr_BM age_uncorr_uncert_pos_yr age_uncorr_uncert_neg_yr date_used 238U_ppb 238U_uncert_ppb 232Th_ppt 232Th_uncert_ppb 230Th_ppt 230Th_uncert_ppb 230Th_232Th_act 230Th_232Th_act_uncert 230Th_238U_act 230Th_238U_act_uncert 234U_238U_act 234U_238U_act_uncert 230Th_232Th_act_init 230Th_232Th_act_init_uncert age_corr_BP1950 age_corr_uncert_pos_yr age_corr_uncert_neg_yr # MC-ICP-MS U/Th 262 1 BAR-II#B-1 calcite NA 127815.008344 1247.66557113 1247.66557113 yes 202.790976771 0.219261064786 7091.931202 24.7800746749 NA NA 428.227089741 2.62558975386 0.907019802114 0.00467383184945 1.270706997 0.001920143 0.741429357049014 0.370714678524507 127424.30343 1288.03977175 1288.03977175 # MC-ICP-MS U/Th 230 1 BAR-II#B-2 calcite NA 127174.60904 754.052904793 754.052904793 yes 295.065365438 0.434804488539 394.291005632 3.97835191261 NA NA 10953.7539127 112.848373823 0.886519635589 0.00226054242118 1.248243733 0.002312756 0.741429357049014 0.370714678524507 127104.569536 754.056794658 754.056794658 # MC-ICP-MS U/Th 203 1 BAR-II#B-3 calcite NA 125992.859092 849.125991804 849.125991804 yes 180.931965236 0.30806898054 95.7663820159 3.36569960639 NA NA 27532.5840733 970.079197852 0.882615395342 0.00267128363512 1.249119714 0.002490814 0.741429357049014 0.370714678524507 125930.694661 849.097798121 849.097798121 # MC-ICP-MS U/Th 165 1 BAR-II#B-4 calcite NA 123926.95543 909.082148514 909.082148514 yes 114.816840214 0.174975069529 107.44802139 3.29992147309 NA NA 15451.5406608 477.057414468 0.875772623876 0.00307618905189 1.250795955 0.002447673 0.741429357049014 0.370714678524507 123860.826346 909.0467934 909.0467934 # MC-ICP-MS U/Th 137.5 1 BAR-II#B2015-5 calcite NA 120517.28596 977.910601437 977.910601437 yes 61.2714641547 0.108233292445 137.151744233 3.02352043241 NA NA 6481.66001089 143.76703643 0.879959472978 0.00265640379497 1.273305289 0.004060139 0.741429357049014 0.370714678524507 120409.49099 977.643431374 977.643431374 # MC-ICP-MS U/Th 123 1 BAR-II#B-5 calcite NA 119334.084406 706.185827892 706.185827892 yes 61.7734976905 0.0670893483818 465.139906917 4.58078004574 NA NA 1889.34769282 19.3346976934 0.861628471725 0.00257304862461 1.256726783 0.001876185 0.741429357049014 0.370714678524507 119203.807958 709.463376246 709.463376246 # MC-ICP-MS U/Th 107.5 1 BAR-II#B2015-4 calcite NA 120080.59865 1198.45977043 1198.45977043 yes 50.5572146257 0.106441341681 1677.78830474 4.71736776634 NA NA 431.633316961 2.34176028805 0.868765029215 0.00442649167366 1.261163543 0.002998283 0.741429357049014 0.370714678524507 119371.087733 1233.7002909 1233.7002909 # MC-ICP-MS U/Th 75 1 BAR-II#B-6 calcite NA 117612.845069 775.3153631 775.3153631 yes 61.7229919885 0.0612027066908 681.717288489 4.08850063246 NA NA 1308.80414454 9.01538655296 0.87550522826 0.00309077151831 1.28452737 0.00179339 0.741429357049014 0.370714678524507 117451.193999 781.588567967 781.588567967 # MC-ICP-MS U/Th 63 1 BAR-II#B2015-3 calcite NA 116363.121741 977.695875139 977.695875139 yes 42.0966473876 0.0960481952623 205.772609353 3.38981628668 NA NA 2936.18977864 49.2437587775 0.870477450044 0.00338276531092 1.284287478 0.003522644 0.741429357049014 0.370714678524507 116205.368342 977.767235077 977.767235077 # MC-ICP-MS U/Th 47.5 1 BAR-II#B2015-2 calcite NA 115808.29275 746.635792824 746.635792824 yes 40.8276150629 0.0682700941769 162.40819704 1.79239036109 NA NA 3676.24409103 41.8075184714 0.886934647314 0.00284994508958 1.309425685 0.002424028 0.741429357049014 0.370714678524507 115669.626024 746.960858274 746.960858274 # MC-ICP-MS U/Th 32 1 BAR-II#B2015-1 calcite NA 113344.686953 681.367058184 681.367058184 yes 40.4303970926 0.0408184934378 225.771037127 2.82327488911 NA NA 2642.55842022 34.1058409281 0.894989964974 0.00299753778179 1.335513456 0.001626039 0.741429357049014 0.370714678524507 113178.589886 682.597975806 682.597975806 # MC-ICP-MS U/Th 15 1 BAR-II#B-7 calcite NA 110475.892914 1195.80338746 1195.80338746 yes 23.8687511442 0.0447436310423 1062.47065144 3.62705879006 NA NA 340.349838808 2.19543083686 0.917570705129 0.00530819339291 1.386352396 0.004084012 0.741429357049014 0.370714678524507 110032.792788 1252.42054581 1252.42054581 #----------------------------------------- # Variables # PaST_Thesaurus_Download_Resource: https://www.ncei.noaa.gov/access/paleo-search/skos/past-thesaurus.rdf # PaST_Thesaurus_Download_Description: Paleoenvironmental Standard Terms (PaST) Thesaurus terms, definitions, and relationships in SKOS format. # ## depth_sample depth,,,millimeter,,speleothems,,,N, ## interp_age age,,,calendar year before present,,speleothems,,,N, ## interp_age_uncert_pos age,,two standard deviations upper bound,calendar year,,speleothems,,,N, ## interp_age_uncert_neg age,,two standard deviations lower bound,calendar year,,speleothems,,,N, ## sample_thickness sample thickness,,,millimeter,,speleothems,,,N, ## d18O_measurement delta 18O,calcite,,per mil VPDB,,speleothems,,,N,measurement precision is 0.1 per mil ## d13C_measurement delta 13C,calcite,,per mil VPDB,,speleothems,,,N,measurement precision is 0.1 per mil #----------------------------------------- # Data: # Missing_Values: NA depth_sample interp_age interp_age_uncert_pos interp_age_uncert_neg sample_thickness d18O_measurement d13C_measurement 270.48 128124.708024 1207.54964776 960.460196461 1 -7.87926349565 -6.57560959867 265.7466 127961.924343 1087.52347649 934.929630134 1 -7.62614407945 -8.03700093765 261.0132 127822.275119 997.091228822 1002.97105443 1 -7.03887001942 -7.3948496912 256.2798 127705.172994 937.049564758 1115.27217491 1 -7.55614709245 -7.78388511756 253.907337346 127651.903666 915.241065637 1168.54150301 1 -7.68174820176 -8.62310368583 253.4 127640.803442 911.10995735 1179.64172698 1 -7.43781584532 -8.50887302433 252.5 127621.287337 904.16329258 1199.15783194 1 -7.46944873911 -7.88122655706 252.3 127616.975189 902.680004551 1203.46997997 1 -7.60077557192 -8.16693169088 251.35 127596.579424 895.897044102 1223.86574484 1 -7.43663211849 -7.46154077469 251.2 127593.368719 894.862141419 1227.07645009 1 -7.57045731536 -7.69955459853 250.6 127580.539985 890.80819999 1239.9051845 1 -7.38612644051 -7.73875820985 249.8 127563.442131 885.587208089 1257.0030383 1 -7.57247345461 -7.44733236348 249.35 127553.811422 882.725584553 1266.63374744 1 -7.50726115254 -7.38108399035 248.8 127542.011751 879.285044226 1278.43341834 1 -7.35317937714 -7.21558996118 248.35 127532.323408 876.505808395 1288.12176114 1 -7.39145321123 -7.49001928994 247.6 127516.082693 871.918979672 1304.36247616 1 -7.2492863334 -6.97346634184 246.95 127501.885801 867.961379378 1318.55936783 1 -7.55599124027 -7.8004948513 246.65 127495.287509 866.132240873 1325.15766078 1 -7.74102269561 -7.95637359381 246.05 127481.990521 862.45516326 1338.4546483 1 -7.34962819666 -7.51471394652 245.6 127471.919665 859.670264192 1348.30598567 1 -7.79203101854 -7.61121685852 245.05 127459.482471 856.220285138 1360.07806364 1 -7.24151447974 -8.18166882464 244.55 127448.040726 853.026691422 1370.50748766 1 -7.35714978309 -7.93059176471 244 127435.291211 849.435351148 1381.66110914 1 -7.59682981583 -8.30354890389 243.7 127428.259154 847.436083348 1387.59706701 1 -7.67489332833 -8.38247328092 243.1 127414.018066 843.33947207 1399.14036834 1 -7.23855516267 -8.04704311619 242.75 127405.598465 840.886997484 1405.66898242 1 -7.54928785327 -8.51178214469 242.15 127390.972918 836.58036725 1416.51738856 1 -7.49818591353 -8.09205111931 241.65 127378.600855 832.898241943 1425.23443571 1 -7.19142313703 -8.50718538446 240.95 127361.000879 827.611304788 1436.96001784 1 -7.2657808797 -8.35234076568 240.45 127348.23153 823.747733975 1445.00423845 1 -7.62307854969 -9.0520014009 239.8 127331.386693 818.626058198 1449.88667552 1 -7.21941824562 -8.69567615233 239.6 127326.148337 817.02922627 1450.66194099 1 -7.61259462561 -8.66487424615 238.7 127302.255917 809.733597005 1452.83815487 1 -7.26420257726 -8.37026430675 238.6 127299.569065 808.912703888 1452.95000421 1 -7.62227209399 -8.61411002452 237.75 127276.473372 801.862557605 1452.88399601 1 -7.5216667456 -8.02372612409 237.7 127275.100517 801.444111784 1452.82443654 1 -7.04383209952 -7.43346056036 236.75 127248.717132 793.4270526 1450.55580663 1 -7.28799620694 -8.68785804728 236.65 127245.907031 792.576592557 1450.19385837 1 -6.83450973884 -7.9618067209 235.9 127224.633092 786.166274433 1446.75664894 1 -7.39686772624 -8.69865044086 235.5 127213.144787 782.728429532 1444.41462879 1 -7.18627389445 -8.38938275055 234.5 127183.995393 774.096832222 1437.07668836 1 -7.13546257157 -8.64852233324 233.7 127160.239384 767.17547506 1429.75028834 1 -7.57086054321 -9.25985490681 233.45 127152.736807 765.013350424 1427.20711929 1 -6.81478095838 -7.69036464897 232.9 127136.099986 760.262896845 1421.20232988 1 -6.9170665445 -8.02460127137 232.75 127131.531512 758.969494589 1419.4690419 1 -7.16561655468 -7.68296628989 232.4 127120.820061 755.956456511 1415.26935408 1 -7.13842333958 -7.34864484345 231.8 127102.290118 750.811556803 1407.57759259 1 -7.13591767937 -7.61750132649 231.5 127092.946293 748.25106648 1403.50589201 1 -7.57914018325 -7.35375212519 231.3 127086.688024 746.549264974 1400.71019111 1 -7.21867332994 -7.50832628563 231 127077.257206 744.005182686 1396.39741064 1 -7.0466104339 -8.27822411707 230.8 127070.941149 742.315359758 1393.44426685 1 -7.44263408714 -7.75311684813 230.45 127059.832748 739.371300446 1388.12977302 1 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