# Buca della Renella Geochemical Data from 7300 to 1000 Cal Yr BP #---------------------------------------------------------------------------------------- # World Data Service for Paleoclimatology, Boulder # and # NOAA Paleoclimatology Program #---------------------------------------------------------------------------------------- # Template Version 4.0 # Encoding: UTF-8 # NOTE: Please cite original publication, NOAA Landing Page URL, dataset and publication DOIs (where available), and date accessed when using downloaded data. # If there is no publication information, please cite Investigator, Title, NOAA Landing Page URL, and date accessed. # # Description/Documentation lines begin with # # Data lines have no # # # NOAA_Landing_Page: https://www.ncei.noaa.gov/access/paleo-search/study/40178 # Landing_Page_Description: NOAA Landing Page of this data file's parent study, which includes all study metadata. # # Study_Level_JSON_Metadata: https://www.ncei.noaa.gov/pub/data/metadata/published/paleo/json/noaa-cave-40178.json # Study_Level_JSON_Description: JSON metadata of this data file's parent study, which includes all study metadata. # # Data_Type: Speleothems # # Dataset_DOI: # # Science_Keywords: #----------------------------------------- # Resource_Links # # Data_Download_Resource: https://www.ncei.noaa.gov/pub/data/paleo/speleothem/SISAL-v3/noaa_templates/Drysdale-unpublished-RL4_2018.txt # Data_Download_Description: NOAA Template File; RL4_2018 Speleothem Geochemical Data # # Related_Online_Resource: https://www.ncei.noaa.gov/access/paleo-search/study/39799 # Related_Online_Description: URL; SISAL v3 Database Landing Page # #----------------------------------------- # Contribution_Date # Date: 2024-09-02 #----------------------------------------- # File_Last_Modified_Date # Date: 2024-12-21 #----------------------------------------- # Title # Study_Name: Buca della Renella Geochemical Data from 7300 to 1000 Cal Yr BP #----------------------------------------- # Investigators # Investigators: Drysdale, R. #----------------------------------------- # Description_Notes_and_Keywords # Description: Data contributed as part of SISAL v3 Global Speleothem Isotope and Trace Element Database (https://doi.org/10.25921/jajq-qg60). Data is unpublished from Drysdale, R., et al. Notes from the SISAL database: RL4_2006 (SISAL entity_id = 282), RL4_2016 (entity_id = 283) and RL4_2018 (entity_id = 381) share the same U-Th dates. Their 'decay_constant=other because they were calculated using the following decay constants: 234U: 2.835×10^(-6 )/yr and 230Th: 9.195 × 10^(-6)/yr. Duplicate isotope samples of RL4_2006 (entity_id = 282) at depth_sample = 80.1, 78.63, 82.1mm with different interp_age and isotope values have been averaged. RL4_2018 (entity_id = 381) supersedes RL4_2006 (entity_id = 282) and RL4_2016 (entity_id = 283). #----------------------------------------- # Publication # Authors: Kaushal, Nikita, Franziska A. Lechleitner, Micah Wilhelm, Khalil Azennoud, Janica C. Bühler, Kerstin Braun, Yassine Ait Brahim, Andy Baker, Yuval Burstyn, Laia Comas-Bru, Jens Fohlmeister, Yonaton Goldsmith, Sandy P. Harrison, István G. Hatvani, Kira Rehfeld, Magdalena Ritzau, Vanessa Skiba, Heather M. Stoll, József G. Szucs, Péter Tanos, Pauline C. Treble, Vitor Azevedo, Jonathan L. Baker, Andrea Borsato, Sakonvan Chawchai, Andrea Columbu, Laura Endres, Jun Hu, Zoltán Kern, Alena Kimbrough, Koray Koç, Monika Markowska, Belen Martrat, Syed Masood Ahmad, Carole Nehme, Valdir Felipe Novello, Carlos Pérez-Mejías, Jiaoyang Ruan, Natasha Sekhon, Nitesh Sinha, Carol V. Tadros, Benjamin H. Tiger, Sophie Warken, Annabel Wolf, Haiwei Zhang, and SISAL Working Group members # Published_Date_or_Year: 2024 # Published_Title: SISALv3: a global speleothem stable isotope and trace element database # Journal_Name: Earth System Science Data # Volume: 16 # Edition: # Issue: # Pages: 1933-1963 # Report_Number: # DOI: 10.5194/essd-16-1933-2024 # Online_Resource: # Full_Citation: # Abstract: Palaeoclimate information on multiple climate variables at different spatiotemporal scales is becoming increasingly important to understand environmental and societal responses to climate change. A lack of high-quality reconstructions of past hydroclimate has recently been identified as a critical research gap. Speleothems, with their precise chronologies, widespread distribution, and ability to record changes in local to regional hydroclimate variability, are an ideal source of such information. Here, we present a new version of the Speleothem Isotopes Synthesis and AnaLysis database (SISALv3), which has been expanded to include trace element ratios and Sr isotopes as additional, hydroclimate-sensitive geochemical proxies. The oxygen and carbon isotope data included in previous versions of the database have been substantially expanded. SISALv3 contains speleothem data from 365 sites from across the globe, including 95 , 85 , 52 , 25 , 29 , and 14 Sr-isotope records. The database also has increased spatiotemporal coverage for stable oxygen (892) and carbon (620) isotope records compared with SISALv2 (which consists of 673 and 430 stable oxygen and carbon records, respectively). Additional meta information has been added to improve the machine-readability and filtering of data. Standardized chronologies are included for all new entities along with the originally published chronologies. Thus, the SISALv3 database constitutes a unique resource of speleothem palaeoclimate information that allows regional to global palaeoclimate analyses based on multiple geochemical proxies, permitting more robust interpretations of past hydroclimate and comparisons with isotope-enabled climate models and other Earth system and hydrological models. The database can be accessed at https://doi.org/10.5287/ora-2nanwp4rk (Kaushal et al., 2024). #----------------------------------------- # Funding_Agency # Funding_Agency_Name: # Grant: #----------------------------------------- # Site_Information # Site_Name:Buca della Renella # Location:Italy # Northernmost_Latitude:44.08 # Southernmost_Latitude:44.08 # Easternmost_Longitude:10.21 # Westernmost_Longitude:10.21 # Elevation_m:300 #----------------------------------------- # Data_Collection # Collection_Name: RL4_2018 isotopes Drysdale SISAL v3 # First_Year: 7277 # Last_Year: 1024 # Time_Unit: Cal Yr BP # Core_Length_m: # Parameter_Keywords: oxygen isotopes, carbon isotopes # Notes: Contact: Russell Drysdale; Type: flowstone; Dist. from entrance (m): 100; Entity Status: current; Depth Reference: from top; Overlying Bedrock Thickness (m): 42; Drip Type: unknown; Drip Height: NA; Drip Water Equilibrium Studies: unknown; Trace Elements Measured: ; Organics Measured: yes; Fluid Inclusions Measured: unknown; Fabric Studies: unknown; Clumped Isotopes Measured: no; Noble Gases Measured: unknown; C14 Measured: unknown; ODL Measurements: unknown; Mg/Ca Measured: no; Type from WOKAM: continuous carbonate; Vegetation Type: unknown; Land Use: unknown; Copernicus lcc: closed forest, deciduous broad leaf; Cover Type: unknown; Host Rock Trace Elements: no; Drip Water Trace Elements: no; Isotope Standard: Vienna-PDB; d18O dripwater carbonate difference: NA; Trace Elements Datafile: no; Trace Elements Metadata File: NA; Cave Map: no; Entity Scan: no #----------------------------------------- # Chronology_Information # Chronology: Uranium-Thorium # Chronology_Download_Resource: https://www.ncei.noaa.gov/pub/data/paleo/templates/noaa-wds-paleo-uth-terms.csv # Chronology_Download_Description: Uranium-Thorium terms and definitions. # Chronology_Notes: Metadata and data from SISAL v3 database. # Rejection_Rationale: # 238U_Decay_Constant: other (see notes) # 234U_Decay_Constant: other (see notes) # 230Th_Decay_Constant: other (see notes) # Initial_230Th/232Th: # Initial_230Th/232Th_Method: # Age_Model_Method: # Missing_Values: NA # Chronology_Table: # date_type depth_top_mm thick_mm samp_id material_dated weight_mg age_uncorr_BM age_uncorr_uncert_pos_yr age_uncorr_uncert_neg_yr date_used 238U_ppb 238U_uncert_ppb 232Th_ppt 232Th_uncert_ppb 230Th_ppt 230Th_uncert_ppb 230Th_232Th_act 230Th_232Th_act_uncert 230Th_238U_act 230Th_238U_act_uncert 234U_238U_act 234U_238U_act_uncert 230Th_232Th_act_init 230Th_232Th_act_init_uncert age_corr_BP1950 age_corr_uncert_pos_yr age_corr_uncert_neg_yr # MC-ICP-MS U/Th 2 NA RL4-1 calcite 20-30 1290 40 40 yes NA NA NA NA NA NA 0.00797446646341 0.000277646237213 0.00837 0.00029 0.7088 NA 0.155 0.045 1217 50 50 # MC-ICP-MS U/Th 14.5 NA RL4-2 calcite 20-30 3020 80 80 yes NA NA NA NA NA NA 0.000362484701838 9.3432294392e-05 0.0194 0.005 0.7095 NA 0.155 0.045 1717 770 770 # MC-ICP-MS U/Th 26 NA RL4-9 calcite 20-30 2150 90 90 yes NA NA NA NA NA NA 0.0134801081499 0.000954491803546 0.01396 0.00061 0.7135 NA 0.155 0.045 2036 160 160 # MC-ICP-MS U/Th 30.5 NA RL4-3 calcite 20-30 2290 50 50 yes NA NA NA NA NA NA 0.0212913252331 0.00047274779404 0.01507 0.00033 0.7325 NA 0.155 0.045 2227 50 50 # MC-ICP-MS U/Th 56 NA RL4-10 calcite 20-30 3130 70 70 yes NA NA NA NA NA NA 0.0473389355742 0.0018606768993 0.02028 0.00047 0.7153 NA 0.155 0.045 3056 90 90 # MC-ICP-MS U/Th 77 NA RL4-11 calcite 20-30 3670 100 100 yes NA NA NA NA NA NA 0.0963379109447 0.00497153534966 0.02315 0.00062 0.7038 NA 0.155 0.045 3576 100 100 # MC-ICP-MS U/Th 85.5 NA RL4-4 calcite 20-30 3620 70 70 yes NA NA NA NA NA NA 0.153181513731 0.00308836245299 0.02287 0.00044 0.6999 NA 0.155 0.045 3567 70 70 # MC-ICP-MS U/Th 104 NA RL4-12 calcite 20-30 4240 80 80 yes NA NA NA NA NA NA 0.0789050877715 0.00308255121605 0.02652 5e-04 0.6961 NA 0.155 0.045 4156 90 90 # MC-ICP-MS U/Th 112 NA RL4-13 calcite 20-30 4870 80 80 yes NA NA NA NA NA NA 0.00897601980597 0.000405238249875 0.03118 5e-04 0.7141 NA 0.155 0.045 4606 440 440 # MC-ICP-MS U/Th 117 NA RL4-5 calcite 20-30 5410 90 90 yes NA NA NA NA NA NA 0.0127929255711 0.000229190713734 0.03472 0.00059 0.7177 NA 0.155 0.045 5297 100 100 # MC-ICP-MS U/Th 120 NA Rl4-6 calcite 20-30 5550 80 80 yes NA NA NA NA NA NA 0.00764776839566 0.000119164412344 0.03487 0.00051 0.703 NA 0.155 0.045 5387 110 110 # MC-ICP-MS U/Th 136 NA RL4-7 calcite 20-30 6350 110 110 yes NA NA NA NA NA NA 0.00226059619125 3.88217865686e-05 0.03998 0.00066 0.7074 NA 0.155 0.045 5887 280 280 # MC-ICP-MS U/Th 153 NA RL4-8 calcite 20-30 7560 100 100 yes NA NA NA NA NA NA 0.00162197591832 2.14429280911e-05 0.04677 0.00058 0.6998 NA 0.155 0.045 6817 430 430 #----------------------------------------- # Variables # PaST_Thesaurus_Download_Resource: https://www.ncei.noaa.gov/access/paleo-search/skos/past-thesaurus.rdf # PaST_Thesaurus_Download_Description: Paleoenvironmental Standard Terms (PaST) Thesaurus terms, definitions, and relationships in SKOS format. # ## depth_sample depth,,,millimeter,,speleothems,,,N, ## interp_age age,,,calendar year before present,,speleothems,,,N, ## d18O_measurement delta 18O,calcite,,per mil VPDB,,speleothems,,,N,measurement precision is 0.1 per mil ## d13C_measurement delta 13C,calcite,,per mil VPDB,,speleothems,,,N,measurement precision is 0.05 per mil #----------------------------------------- # Data: # Missing_Values: NA depth_sample interp_age d18O_measurement d13C_measurement 0.1 1024.11 -4.69821529307 -5.29505393448 0.3 1035.03 -4.71649915353 -5.22658089967 0.5 1045.94 -4.60624487466 -4.9798428184 0.7 1056.85 -4.56452970062 -4.95688484239 0.9 1067.76 -4.7919063264 -5.72747540155 1.1 1078.67 -4.89559211544 -5.90246255456 1.3 1089.59 -4.47433420038 -5.83752948888 1.5 1100.5 -4.82028951358 -5.93119562521 1.7 1111.41 -4.74524193483 -5.86008864005 1.9 1122.32 -4.72878504369 -5.97227602292 2.1 1133.23 -4.45077326427 -5.73545063875 2.3 1144.14 -4.56167089615 -5.66822197437 2.5 1155.06 -4.5648752943 -6.06205661371 2.7 1165.97 -4.68910657545 -6.35853145788 2.9 1176.88 -4.56428190605 -6.79699671871 3.1 1187.79 -4.66751324654 -7.41977173647 3.3 1198.7 -4.58058367073 -7.70455566248 3.5 1209.62 -4.72403324333 -7.56267166538 3.7 1220.53 -4.31647972548 -7.06276590096 3.9 1231.44 -4.39721484255 -7.49475455208 4.1 1242.35 -4.40306083026 -7.28666729044 4.3 1253.26 -4.39365032051 -6.64078944597 4.5 1264.18 -4.35946835531 -7.08715810558 4.7 1275.09 -4.18950130483 -5.8563215682 4.9 1286 -4.25878110662 -5.66652381898 5.1 1295.59 -4.50375065795 -6.84173638979 5.3 1305.18 -4.12053184524 -5.78726245126 5.5 1314.78 -4.41176276365 -6.74212116741 5.7 1324.37 -4.05603990223 -6.87799324836 5.9 1333.39 -4.10234717693 -6.64638973883 6.1 1342.3 -4.12579204309 -6.98711036687 6.3 1351.21 -4.33520924337 -7.76675223961 6.5 1360.12 -3.99105327829 -7.07292316114 6.7 1369.26 -3.6397616533 -6.22730591725 6.9 1378.85 -3.45985376948 -5.94245829246 7.1 1388.45 -3.61493345139 -6.22007502758 7.3 1398.04 -3.92590756633 -6.66047639141 7.5 1407.63 -4.32364181659 -7.58009922943 7.7 1417.22 -3.70255847601 -7.72671051405 7.9 1426.82 -3.75910067562 -6.70475177318 8.1 1436.41 -3.83694197659 -7.04333375372 8.3 1446 -3.96852626562 -7.85736399821 8.5 1452.48 -3.99718972978 -7.37920577295 8.7 1458.96 -4.03080441725 -7.34616808335 8.9 1465.43 -3.70483135548 -6.0211774624 9.1 1471.91 -3.81869077383 -6.31859555905 9.3 1478.39 -3.89486183072 -6.58977317759 9.5 1484.87 -3.68197668099 -6.17335512723 9.7 1493.19 -3.52252470798 -6.07231562471 9.9 1501.91 -3.66416445862 -5.45062586661 10.1 1510.63 -3.70989441837 -5.81952026089 10.3 1519.35 -3.80226356899 -6.11923248977 10.5 1528.07 -3.72899957113 -5.84219626328 10.7 1536.78 -3.48439935125 -5.68314222239 10.9 1545.5 -3.43615713105 -6.58057288871 11.1 1554.22 -3.7778792431 -7.01449700898 11.3 1562.94 -3.8997970834 -6.72565090299 11.5 1571.66 -3.4396102574 -5.54531875346 11.7 1580.38 -3.79756753959 -5.95280390397 11.9 1590.02 -3.79798792636 -6.4712671639 12.1 1601.35 -3.66502802309 -6.65228474233 12.3 1612.67 -3.52917296072 -6.62849324378 12.5 1624 -3.7588719867 -6.38987211594 12.7 1635.33 -3.81231299212 -6.13921478509 12.9 1646.66 -3.60764790366 -6.19751754943 13.1 1657.83 -3.65639001521 -6.30076431234 13.3 1668.29 -4.02425010069 -6.66910415796 13.5 1678.76 -4.05982290718 -6.85743455221 13.7 1689.22 -4.09357863379 -6.72749964144 13.9 1699.68 -4.00019503377 -6.74280787115 14.1 1710.14 -4.09192995688 -6.84449313899 14.3 1719.52 -4.01804045725 -6.63212051773 14.5 1727.52 -3.90323176319 -6.33896896023 14.7 1735.52 -3.67982947815 -5.91637583751 14.9 1743.52 -3.67405420794 -5.860148785 15.1 1751.52 -3.92642770278 -5.96780326983 15.3 1759.52 -3.93642484046 -6.10019671277 15.5 1767.52 -3.71895760085 -6.14727407155 15.7 1775.52 -3.98072522577 -6.33872867518 15.9 1784.29 -3.94643361879 -6.30988949663 16.1 1793.1 -3.8826936438 -6.23633188314 16.3 1801.92 -4.15841099054 -7.40217450077 16.5 1810.74 -4.54189208343 -8.44245771342 16.7 1819.55 -4.27496861299 -8.31366906903 16.9 1828.37 -4.40799915073 -8.28265737002 17.1 1837.18 -4.33222164964 -8.24173573754 17.3 1846 -4.56358934743 -8.38172078891 17.5 1853.67 -4.58964923564 -7.44173098948 17.7 1861.35 -4.2783370705 -6.89992468963 18.1 1876.69 -4.43197753121 -7.81425898058 18.3 1884.36 -4.44537890764 -7.84764492487 18.5 1892.04 -4.23591753786 -6.95368740117 18.7 1899.71 -4.25426977233 -5.91476034186 18.9 1907.22 -3.87321477064 -5.84255212355 19.1 1914.02 -3.75267861537 -5.75957046801 19.3 1920.81 -3.57657238409 -5.71719912333 19.5 1927.6 -3.54675658948 -5.81234471343 19.7 1934.4 -3.38607957058 -5.79951533356 19.9 1941.19 -3.87997195099 -6.35994753727 20.1 1947.98 -3.88139054883 -6.57073972413 20.3 1954.78 -3.98206632146 -6.48143471497 20.5 1961.24 -3.99549190956 -6.43532899669 20.7 1967.64 -3.95761327321 -6.85142122095 20.9 1974.03 -3.94273197839 -6.66528842495 21.1 1980.42 -3.8537505276 -6.33548521814 21.3 1986.82 -3.88733089939 -6.00426163241 21.5 1993.21 -4.01594175997 -5.97133254875 21.7 1999.61 -3.96047036312 -5.8382785307 21.9 2006 -3.91893382339 -5.77897325295 22.1 2015.81 -3.7602447429 -5.9930180957 22.3 2025.62 -3.8991861443 -6.13713570268 22.5 2035.43 -3.94858671278 -6.31663930288 22.7 2045.24 -3.88739616467 -6.65265967945 22.9 2055.05 -3.88538239993 -6.69447302213 23.1 2064.86 -3.93140664183 -6.6348952024 23.3 2074.68 -3.87818751335 -7.16295872105 23.5 2082.06 -3.88169943312 -7.31099664004 23.7 2089.07 -3.9450450948 -7.09544631668 23.9 2096.08 -3.98599129535 -7.15328144273 24.1 2103.08 -3.87410294327 -7.08792603501 24.3 2110.09 -3.62742044393 -7.0645132841 24.5 2117.1 -3.91688916533 -7.29913735112 24.7 2124.11 -3.96148937576 -7.81429399878 24.9 2130.39 -4.12215037455 -7.82233944774 25.1 2136.4 -3.94331175189 -7.6360729306 25.3 2142.41 -3.78825578316 -6.92690319065 25.5 2148.42 -4.14920896928 -7.22152559121 25.7 2154.43 -3.92304624771 -7.23567865196 25.9 2160.44 -3.96428753293 -7.01581629437 26.1 2166.56 -3.88662915407 -6.84911623997 26.3 2174.07 -4.04505476315 -7.08139808538 26.5 2181.58 -3.99558204841 -7.5671854109 26.7 2189.09 -4.19249718756 -7.9370699509 26.9 2196.59 -4.05057155764 -7.97134011873 27.1 2204.1 -4.18739567445 -7.86385296272 27.3 2211.61 -3.91303649782 -6.9685357115 27.5 2219.12 -3.977378568 -6.98067642087 27.7 2226.62 -3.98550326633 -7.03793019636 27.9 2234.13 -3.92492787803 -6.80630586318 28.1 2241.64 -4.06933876118 -6.68285633084 28.3 2249.15 -3.91255070475 -6.83144265493 28.5 2256.65 -3.92486329011 -6.74525883156 28.7 2264.16 -3.96342767423 -6.74656828013 28.9 2271.67 -3.99676327499 -6.8256235338 29.1 2279.18 -4.028966647 -6.68960046329 29.3 2286.68 -3.62625571885 -6.44906178507 29.5 2294.19 -4.04083460095 -6.64183747089 29.7 2301.7 -4.20524666414 -7.05036998455 29.9 2309.21 -4.16488109134 -7.09940315031 30.1 2316.71 -4.01665212102 -7.05982319054 30.3 2324.23 -4.11788697307 -7.34256710031 30.5 2331.74 -4.15676764115 -7.22772889518 30.7 2339.25 -4.32277705319 -7.46299294238 30.9 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