# Molinos Cave, Ejulve Cave Geochemical Data from 11300 to 2700 Cal Yr BP #---------------------------------------------------------------------------------------- # World Data Service for Paleoclimatology, Boulder # and # NOAA Paleoclimatology Program #---------------------------------------------------------------------------------------- # Template Version 4.0 # Encoding: UTF-8 # NOTE: Please cite original publication, NOAA Landing Page URL, dataset and publication DOIs (where available), and date accessed when using downloaded data. # If there is no publication information, please cite Investigator, Title, NOAA Landing Page URL, and date accessed. # # Description/Documentation lines begin with # # Data lines have no # # # NOAA_Landing_Page: https://www.ncei.noaa.gov/access/paleo-search/study/40752 # Landing_Page_Description: NOAA Landing Page of this data file's parent study, which includes all study metadata. # # Study_Level_JSON_Metadata: https://www.ncei.noaa.gov/pub/data/metadata/published/paleo/json/noaa-cave-40752.json # Study_Level_JSON_Description: JSON metadata of this data file's parent study, which includes all study metadata. # # Data_Type: Speleothems # # Dataset_DOI: # # Science_Keywords: #----------------------------------------- # Resource_Links # # Data_Download_Resource: https://www.ncei.noaa.gov/pub/data/paleo/speleothem/SISAL-v3/noaa_templates/Moreno2017-HOR.txt # Data_Download_Description: NOAA Template File; HOR Speleothem Geochemical Data # # Related_Online_Resource: https://www.ncei.noaa.gov/access/paleo-search/study/39799 # Related_Online_Description: URL; SISAL v3 Database Landing Page # #----------------------------------------- # Contribution_Date # Date: 2024-09-02 #----------------------------------------- # File_Last_Modified_Date # Date: 2024-12-21 #----------------------------------------- # Title # Study_Name: Molinos Cave, Ejulve Cave Geochemical Data from 11300 to 2700 Cal Yr BP #----------------------------------------- # Investigators # Investigators: Moreno, A.; Pérez-Mejías, C.; Bartolomé, M.; Sancho, C.; Cacho, I.; Stoll, H.; Delgado-Huertas, A.; Hellstrom, J.; Edwards, R. L.; Cheng, H. #----------------------------------------- # Description_Notes_and_Keywords # Description: Data contributed as part of SISAL v3 Global Speleothem Isotope and Trace Element Database (https://doi.org/10.25921/jajq-qg60). #----------------------------------------- # Publication # Authors: Moreno, Ana; Carlos Pérez-Mejías; Miguel Bartolomé; Carlos Sancho; Isabel Cacho; Heather Stoll; Antonio Delgado-Huertas; John Hellstrom; R. Lawrence Edwards; Hai Cheng # Published_Date_or_Year: 2017 # Published_Title: New speleothem data from Molinos and Ejulve caves reveal Holocene hydrological variability in northeast Iberia # Journal_Name: Quaternary Research # Volume: 88 # Edition: # Issue: # Pages: 223-233 # Report_Number: # DOI: 10.1017/qua.2017.39 # Online_Resource: # Full_Citation: Moreno, A., Pérez-Mejías, C., Bartolomé, M., Sancho, C., Cacho, I., Stoll, H., Delgado-Huertas, A., Hellstrom, J., Edwards, R. L. and Cheng, H.: New speleothem data from Molinos and Ejulve caves reveal Holocene hydrological variability in northeast Iberia, Quat. Res., 88(2), 223–233, 2017. # Abstract: #----------------------------------------- # Publication # Authors: Muñoz, Arsenio; Miguel Bartolomé; Alicia Muñoz; Carlos Sancho; Ana Moreno; John C. Hellstrom; Mª Cinta Osácar; Isabel Cacho # Published_Date_or_Year: 2015 # Published_Title: Solar influence and hydrological variability during the Holocene from a speleothem annual record (Molinos Cave, NE Spain) # Journal_Name: Terra Nova # Volume: 27 # Edition: # Issue: # Pages: 300-311 # Report_Number: # DOI: 10.1111/ter.12160 # Online_Resource: # Full_Citation: Muñoz, A., Bartolomé, M., Muñoz, A., Sancho, C., Moreno, A., Hellstrom, J. C., Osácar, M. C. and Cacho, I.: Solar influence and hydrological variability during the Holocene from a speleothem annual record (Molinos Cave, NE Spain), Terra Nov., 27(4), 300–311, 2015. # Abstract: #----------------------------------------- # Publication # Authors: Pérez-Mejías, Carlos; Ana Moreno; Carlos Sancho; Rebeca Martín-García; Christoph Spötl; Isabel Cacho; Hai Cheng; R. Lawrence Edwards # Published_Date_or_Year: 2019 # Published_Title: Orbital-to-millennial scale climate variability during Marine Isotope Stages 5 to 3 in northeast Iberia # Journal_Name: Quaternary Science Reviews # Volume: 224 # Edition: # Issue: # Pages: 105946 # Report_Number: # DOI: 10.1016/j.quascirev.2019.105946 # Online_Resource: # Full_Citation: Pérez-Mejías, C., Moreno, A., Sancho, C., Martín-García, R., Spötl, C., Cacho, I., Cheng, H. and Edwards, R. L. (2019) Orbital-to-millennial scale climate variability during Marine Isotope Stages 5 to 3 in northeast Iberia. Quaternary Science Reviews 224, 105946. # Abstract: #----------------------------------------- # Publication # Authors: Kaushal, Nikita, Franziska A. Lechleitner, Micah Wilhelm, Khalil Azennoud, Janica C. Bühler, Kerstin Braun, Yassine Ait Brahim, Andy Baker, Yuval Burstyn, Laia Comas-Bru, Jens Fohlmeister, Yonaton Goldsmith, Sandy P. Harrison, István G. Hatvani, Kira Rehfeld, Magdalena Ritzau, Vanessa Skiba, Heather M. Stoll, József G. Szucs, Péter Tanos, Pauline C. Treble, Vitor Azevedo, Jonathan L. Baker, Andrea Borsato, Sakonvan Chawchai, Andrea Columbu, Laura Endres, Jun Hu, Zoltán Kern, Alena Kimbrough, Koray Koç, Monika Markowska, Belen Martrat, Syed Masood Ahmad, Carole Nehme, Valdir Felipe Novello, Carlos Pérez-Mejías, Jiaoyang Ruan, Natasha Sekhon, Nitesh Sinha, Carol V. Tadros, Benjamin H. Tiger, Sophie Warken, Annabel Wolf, Haiwei Zhang, and SISAL Working Group members # Published_Date_or_Year: 2024 # Published_Title: SISALv3: a global speleothem stable isotope and trace element database # Journal_Name: Earth System Science Data # Volume: 16 # Edition: # Issue: # Pages: 1933-1963 # Report_Number: # DOI: 10.5194/essd-16-1933-2024 # Online_Resource: # Full_Citation: # Abstract: Palaeoclimate information on multiple climate variables at different spatiotemporal scales is becoming increasingly important to understand environmental and societal responses to climate change. A lack of high-quality reconstructions of past hydroclimate has recently been identified as a critical research gap. Speleothems, with their precise chronologies, widespread distribution, and ability to record changes in local to regional hydroclimate variability, are an ideal source of such information. Here, we present a new version of the Speleothem Isotopes Synthesis and AnaLysis database (SISALv3), which has been expanded to include trace element ratios and Sr isotopes as additional, hydroclimate-sensitive geochemical proxies. The oxygen and carbon isotope data included in previous versions of the database have been substantially expanded. SISALv3 contains speleothem data from 365 sites from across the globe, including 95 , 85 , 52 , 25 , 29 , and 14 Sr-isotope records. The database also has increased spatiotemporal coverage for stable oxygen (892) and carbon (620) isotope records compared with SISALv2 (which consists of 673 and 430 stable oxygen and carbon records, respectively). Additional meta information has been added to improve the machine-readability and filtering of data. Standardized chronologies are included for all new entities along with the originally published chronologies. Thus, the SISALv3 database constitutes a unique resource of speleothem palaeoclimate information that allows regional to global palaeoclimate analyses based on multiple geochemical proxies, permitting more robust interpretations of past hydroclimate and comparisons with isotope-enabled climate models and other Earth system and hydrological models. The database can be accessed at https://doi.org/10.5287/ora-2nanwp4rk (Kaushal et al., 2024). #----------------------------------------- # Funding_Agency # Funding_Agency_Name: # Grant: #----------------------------------------- # Site_Information # Site_Name:Ejulve Cave # Location:Spain # Northernmost_Latitude:40.76 # Southernmost_Latitude:40.76 # Easternmost_Longitude:-0.59 # Westernmost_Longitude:-0.59 # Elevation_m:1240 #----------------------------------------- # Data_Collection # Collection_Name: HOR isotopes Moreno2017 SISAL v3 # First_Year: 6072 # Last_Year: 2708 # Time_Unit: Cal Yr BP # Core_Length_m: # Parameter_Keywords: oxygen isotopes, carbon isotopes # Notes: Contact: Carlos Pérez-Mejías; Type: stalagmite; Dist. from entrance (m): NA; Entity Status: current; Depth Reference: from base; Overlying Bedrock Thickness (m): 10; Drip Type: seasonal drip; Drip Height: NA; Drip Water Equilibrium Studies: unknown; Trace Elements Measured: ; Organics Measured: no; Fluid Inclusions Measured: no; Fabric Studies: yes; Clumped Isotopes Measured: no; Noble Gases Measured: no; C14 Measured: no; ODL Measurements: no; Mg/Ca Measured: no; Type from WOKAM: continuous carbonate; Vegetation Type: shrubland; Land Use: forest; Copernicus lcc: herbaceous vegetation; Cover Type: thin; Host Rock Trace Elements: no; Drip Water Trace Elements: no; Isotope Standard: Vienna-PDB; d18O dripwater carbonate difference: NA; Trace Elements Datafile: no; Trace Elements Metadata File: NA; Cave Map: yes; Entity Scan: no #----------------------------------------- # Chronology_Information # Chronology: Uranium-Thorium # Chronology_Download_Resource: https://www.ncei.noaa.gov/pub/data/paleo/templates/noaa-wds-paleo-uth-terms.csv # Chronology_Download_Description: Uranium-Thorium terms and definitions. # Chronology_Notes: Metadata and data from SISAL v3 database. # Rejection_Rationale: # 238U_Decay_Constant: Cheng et al. 2000 # 234U_Decay_Constant: Cheng et al. 2000 # 230Th_Decay_Constant: Cheng et al. 2000 # Initial_230Th/232Th: # Initial_230Th/232Th_Method: # Age_Model_Method: # Missing_Values: NA # Chronology_Table: # date_type depth_bot_mm thick_mm samp_id material_dated weight_mg age_uncorr_BM age_uncorr_uncert_pos_yr age_uncorr_uncert_neg_yr date_used 238U_ppb 238U_uncert_ppb 232Th_ppt 232Th_uncert_ppb 230Th_ppt 230Th_uncert_ppb 230Th_232Th_act 230Th_232Th_act_uncert 230Th_238U_act 230Th_238U_act_uncert 234U_238U_act 234U_238U_act_uncert 230Th_232Th_act_init 230Th_232Th_act_init_uncert age_corr_BP1950 age_corr_uncert_pos_yr age_corr_uncert_neg_yr # MC-ICP-MS U/Th 1335 2 HOR-133.5 calcite NA NA NA NA yes 150.7 NA NA NA NA NA 94.955 2.036 0.0274 0.002 1.0815 0.0018 0.814 0.407 2715 27 27 # MC-ICP-MS U/Th 1275 2 HOR-127.5 calcite NA NA NA NA yes 153.1 NA NA NA NA NA 8.885 0.185 0.029 0.003 1.073 0.0027 0.814 0.407 2659 192 192 # MC-ICP-MS U/Th 1210 2 HOR-121 calcite NA NA NA NA yes 144 NA NA NA NA NA 23.322 0.555 0.0297 0.002 1.0688 0.0025 0.814 0.407 2900 79 79 # MC-ICP-MS U/Th 1150 2 HOR-115 calcite NA NA NA NA yes 138.8 NA NA NA NA NA 8.329 0.185 0.0318 0.004 1.0654 0.0022 0.814 0.407 2924 227 227 # MC-ICP-MS U/Th 1090 2 HOR-109 calcite NA NA NA NA yes 108 NA NA NA NA NA 22.952 0.555 0.0342 0.003 1.0814 0.0023 0.814 0.407 3315 93 93 # MC-ICP-MS U/Th 1030 2 HOR-103 calcite NA NA NA NA yes 109 NA NA NA NA NA 26.839 0.555 0.0349 0.004 1.0739 0.0023 0.814 0.407 3427 85 85 # MC-ICP-MS U/Th 980 2 HOR 98 calcite NA NA NA NA yes 99 NA NA NA NA NA 103.655 2.406 0.0363 0.004 1.073 0.002 0.814 0.407 3661 48 48 # MC-ICP-MS U/Th 910 2 HOR-91 calcite NA NA NA NA yes 119.4 NA NA NA NA NA 12.216 0.37 0.0363 0.005 1.0739 0.0022 0.814 0.407 3440 182 182 # MC-ICP-MS U/Th 850 2 HOR-85 calcite NA NA NA NA yes 122.5 NA NA NA NA NA 26.839 0.555 0.0397 0.005 1.0789 0.0022 0.814 0.407 3899 99 99 # MC-ICP-MS U/Th 790 2 HOR-79 calcite NA NA NA NA yes 117.5 NA NA NA NA NA 33.132 0.74 0.0401 0.004 1.069 0.0021 0.814 0.407 4000 81 81 # MC-ICP-MS U/Th 730 2 HOR-73 calcite NA NA NA NA yes 108.3 NA NA NA NA NA 44.423 0.925 0.0415 0.003 1.0743 0.0022 0.814 0.407 4154 65 65 # MC-ICP-MS U/Th 670 2 HOR-67 calcite NA NA NA NA yes 111.7 NA NA NA NA NA 11.661 0.185 0.0434 0.004 1.0689 0.0022 0.814 0.407 4147 224 224 # MC-ICP-MS U/Th 635 2 HOR 63.5 calcite NA NA NA NA yes 122.9 NA NA NA NA NA 90.328 2.591 0.0434 0.003 1.0762 0.0018 0.814 0.407 4380 46 46 # MC-ICP-MS U/Th 550 2 HOR-55 calcite NA NA NA NA yes 137.5 NA NA NA NA NA 59.787 1.296 0.0455 0.003 1.0639 0.0019 0.814 0.407 4643 53 53 # MC-ICP-MS U/Th 490 2 HOR-49 calcite NA NA NA NA yes 104.2 NA NA NA NA NA 23.693 0.555 0.0498 0.003 1.0874 0.0022 0.814 0.407 4877 127 127 # MC-ICP-MS U/Th 430 2 HOR-43 calcite NA NA NA NA yes 123 NA NA NA NA NA 58.306 1.296 0.0503 0.003 1.0839 0.0023 0.814 0.407 5040 59 59 # MC-ICP-MS U/Th 370 2 HOR-37 calcite NA NA NA NA yes 122.1 NA NA NA NA NA 12.402 0.185 0.0521 0.005 1.085 0.0022 0.814 0.407 4958 250 250 # MC-ICP-MS U/Th 355 2 HOR 35.5 calcite NA NA NA NA yes 112.1 NA NA NA NA NA 178.99 3.887 0.0553 0.004 1.1024 0.0018 0.814 0.407 5519 50 50 # MC-ICP-MS U/Th 250 2 HOR-25 calcite NA NA NA NA yes 133.8 NA NA NA NA NA 25.729 0.555 0.0544 0.003 1.0765 0.002 0.814 0.407 5418 129 129 # MC-ICP-MS U/Th 190 2 HOR-19 calcite NA NA NA NA yes 134.6 NA NA NA NA NA 47.94 1.111 0.056 0.005 1.0634 0.0034 0.814 0.407 5735 92 92 # MC-ICP-MS U/Th 130 2 HOR-13 calcite NA NA NA NA yes 114.1 NA NA NA NA NA 23.322 0.555 0.0603 0.003 1.0738 0.0022 0.814 0.407 6027 155 155 # MC-ICP-MS U/Th 70 2 HOR-7 calcite NA NA NA NA yes 127.4 NA NA NA NA NA 61.082 1.296 0.0594 0.003 1.0735 0.0018 0.814 0.407 6063 67 67 # MC-ICP-MS U/Th 35 2 HOR-3.5 calcite NA NA NA NA no 128.4 NA NA NA NA NA 149.929 3.147 0.0975 0.004 1.1026 0.0021 0.814 0.407 9970 58 58 #----------------------------------------- # Variables # PaST_Thesaurus_Download_Resource: https://www.ncei.noaa.gov/access/paleo-search/skos/past-thesaurus.rdf # PaST_Thesaurus_Download_Description: Paleoenvironmental Standard Terms (PaST) Thesaurus terms, definitions, and relationships in SKOS format. # ## depth_sample depth,,,millimeter,,speleothems,,,N, ## interp_age age,,,calendar year before present,,speleothems,,,N, ## interp_age_uncert_pos age,,two standard deviations upper bound,calendar year,,speleothems,,,N, ## interp_age_uncert_neg age,,two standard deviations lower bound,calendar year,,speleothems,,,N, ## sample_thickness sample thickness,,,millimeter,,speleothems,,,N, ## d18O_measurement delta 18O,calcite,,per mil VPDB,,speleothems,,,N,measurement precision is 0.06 per mil ## d13C_measurement delta 13C,calcite,,per mil VPDB,,speleothems,,,N,measurement precision is 0.02 per mil #----------------------------------------- # Data: # Missing_Values: NA depth_sample interp_age interp_age_uncert_pos interp_age_uncert_neg sample_thickness d18O_measurement d13C_measurement 1395 2708.44250848 30.621849 30.252474 0.5 -7.43525 -9.50275 1390 2715.69404091 33.524285 28.699825 0.5 -7.61625 -9.33375 1385 2722.44251551 36.172756 29.815714 0.5 -7.53125 -9.58075 1380 2729.12114285 39.764248 30.398786 0.5 -7.91125 -10.12675 1375 2735.78608761 43.198289 32.504657 0.5 -7.18625 -9.53175 1370 2741.93587433 49.348075 34.638224 0.5 -6.93225 -9.53075 1365 2748.76519816 56.177399 39.629443 0.5 -7.04625 -9.97275 1360 2754.4827135 61.894914 42.0451 0.5 -7.00725 -9.60875 1355 2759.20194905 66.61415 44.824554 0.5 -6.65725 -9.52875 1350 2762.06306955 69.47527 49.220769 0.5 -6.40925 -9.31575 1345 2763.6843229 71.096524 56.328118 0.5 -6.55341666667 -9.47666666667 1340 2764.44879009 71.860991 62.499623 0.5 -6.78741666667 -9.49966666667 1335 2765.0629854 72.290433 69.909716 0.5 -6.43741666667 -8.62366666667 1330 2765.67718072 72.472319 77.855368 0.5 -6.04041666667 -9.14466666667 1325 2766.29137604 72.051659 84.067622 0.5 -6.65341666667 -9.54466666667 1320 2770.71821718 76.4785 87.599603 0.5 -7.73741666667 -8.92866666667 1315 2777.92168824 81.05448 88.814115 0.5 -7.01141666667 -9.32066666667 1310 2787.92107384 85.567609 87.756997 0.5 -7.00041666667 -9.43366666667 1305 2799.74240129 85.725304 85.583157 0.5 -6.20241666667 -9.07966666667 1300 2811.93332381 81.205186 83.972408 0.5 -6.66241666667 -9.58066666667 1295 2825.21528002 77.461029 82.378545 0.5 -6.87841666667 -9.30366666667 1290 2838.81205133 74.61872 79.367189 0.5 -6.82241666667 -9.10266666667 1285 2852.70818078 71.845867 78.306449 0.5 -6.60541666667 -8.88966666667 1280 2866.73592761 70.077181 77.024858 0.5 -7.67841666667 -9.17566666667 1275 2880.89102448 74.142849 77.146054 0.5 -6.97241666667 -9.48466666667 1270 2895.2138301 79.111614 76.541091 0.5 -7.01541666667 -9.87066666667 1265 2909.52762702 86.248428 75.992337 0.5 -6.90841666667 -9.56066666667 1260 2923.63413959 98.940158 77.241216 0.5 -7.20141666667 -9.31866666667 1255 2938.65134163 110.429543 76.759766 0.5 -7.26641666667 -9.12066666667 1250 2954.12113664 125.418516 77.21184 0.5 -6.96241666667 -8.91866666667 1245 2969.33601837 137.693947 79.472694 0.5 -7.24341666667 -9.38866666667 1240 2985.21415665 151.239766 78.206608 0.5 -7.39941666667 -9.62466666667 1235 3000.69698437 160.231238 79.32547 0.5 -7.22641666667 -9.58366666667 1230 3016.62863422 171.507704 80.792483 0.5 -7.68141666667 -9.57466666667 1225 3032.96247798 177.613972 79.512408 0.5 -6.51041666667 -9.37766666667 1220 3049.27321569 179.699782 79.967519 0.5 -6.68641666667 -9.06766666667 1215 3065.25833832 186.772268 80.183766 0.5 -7.29541666667 -9.33266666667 1210 3082.23117574 194.20077 79.851391 0.5 -7.28041666667 -9.65766666667 1205 3099.28985712 202.906109 80.520343 0.5 -7.05041666667 -9.24966666667 1200 3116.61917267 211.898746 82.385926 0.5 -7.35241666667 -9.21966666667 1195 3134.5169954 214.223807 82.999653 0.5 -7.31441666667 -9.39166666667 1190 3152.79108368 213.989392 83.280647 0.5 -7.51241666667 -9.44766666667 1185 3170.96720929 201.438044 81.264771 0.5 -7.75841666667 -9.31966666667 1180 3188.82820262 146.664367 82.491504 0.5 -7.43741666667 -9.31166666667 1175 3206.10934092 110.892775 84.85081 0.5 -6.68633333333 -8.555 1170 3222.94402887 96.36099 84.417193 0.5 -7.20433333333 -9.065 1165 3239.44479943 88.720639 83.523184 0.5 -7.72333333333 -9.798 1160 3256.00194455 84.453503 83.240566 0.5 -7.61733333333 -9.126 1155 3272.65329466 80.811394 81.839975 0.5 -6.55633333333 -8.855 1150 3289.08310792 78.863509 82.389919 0.5 -6.95633333333 -9.096 1145 3305.44476861 75.651582 83.554306 0.5 -7.51333333333 -9.514 1140 3321.98868952 71.977043 84.404861 0.5 -6.13033333333 -8.544 1135 3338.29677199 69.639322 84.479285 0.5 -6.7805 -9.26783333333 1130 3354.80181066 68.393185 81.250863 0.5 -7.01633333333 -9.432 1125 3371.60319169 67.860204 76.399327 0.5 -7.69533333333 -9.3 1120 3388.0259251 64.52285 68.581369 0.5 -6.87833333333 -8.972 1115 3404.17115183 61.360961 63.33704 0.5 -6.17433333333 -8.775 1110 3420.53443894 63.621934 59.099533 0.5 -7.14833333333 -8.982 1105 3437.22093719 65.521689 56.375259 0.5 -6.34833333333 -9.077 1100 3453.94562877 68.260965 56.864519 0.5 -6.65733333333 -9.11 1095 3470.93683603 71.239683 60.569364 0.5 -6.55433333333 -9.014 1090 3487.51398235 73.833403 63.232656 0.5 -8.00033333333 -9.247 1085 3504.23167294 74.526226 67.824468 0.5 -6.68533333333 -9.549 1080 3520.86619606 76.802144 72.913476 0.5 -6.76333333333 -9.573 1075 3537.60065732 78.317895 75.027315 0.5 -7.44133333333 -9.282 1070 3554.56389076 63.493488 69.302507 0.5 -6.09333333333 -9.095 1065 3571.78438962 60.269804 60.288589 0.5 -6.56733333333 -9.229 1060 3589.1263946 43.810812 42.946584 0.5 -7.95133333333 -9.285 1055 3605.79703286 41.396028 42.487066 0.5 -7.42333333333 -9.163 1050 3622.15809527 43.070867 43.540683 0.5 -8.13533333333 -8.785 1045 3638.86266986 46.626267 45.231378 0.5 -8.43633333333 -9.281 1040 3647.13216811 47.391523 55.127224 0.5 -7.61633333333 -8.962 1035 3655.29552426 48.425533 65.726667 0.5 -6.59433333333 -8.868 1030 3663.48179859 49.577614 76.6816 0.5 -7.75433333333 -8.458 1025 3671.61279755 50.375975 88.96639 0.5 -7.24233333333 -8.545 1020 3679.59389019 54.267911 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