# Cobre Cave Geochemical Data from 116300 to 100600 Cal Yr BP #---------------------------------------------------------------------------------------- # World Data Service for Paleoclimatology, Boulder # and # NOAA Paleoclimatology Program #---------------------------------------------------------------------------------------- # Template Version 4.0 # Encoding: UTF-8 # NOTE: Please cite original publication, NOAA Landing Page URL, dataset and publication DOIs (where available), and date accessed when using downloaded data. # If there is no publication information, please cite Investigator, Title, NOAA Landing Page URL, and date accessed. # # Description/Documentation lines begin with # # Data lines have no # # # NOAA_Landing_Page: https://www.ncei.noaa.gov/access/paleo-search/study/40772 # Landing_Page_Description: NOAA Landing Page of this data file's parent study, which includes all study metadata. # # Study_Level_JSON_Metadata: https://www.ncei.noaa.gov/pub/data/metadata/published/paleo/json/noaa-cave-40772.json # Study_Level_JSON_Description: JSON metadata of this data file's parent study, which includes all study metadata. # # Data_Type: Speleothems # # Dataset_DOI: # # Science_Keywords: #----------------------------------------- # Resource_Links # # Data_Download_Resource: https://www.ncei.noaa.gov/pub/data/paleo/speleothem/SISAL-v3/noaa_templates/Rossi2014-PA-8.txt # Data_Download_Description: NOAA Template File; PA-8 Speleothem Geochemical Data # # Related_Online_Resource: https://www.ncei.noaa.gov/access/paleo-search/study/39799 # Related_Online_Description: URL; SISAL v3 Database Landing Page # #----------------------------------------- # Contribution_Date # Date: 2024-09-02 #----------------------------------------- # File_Last_Modified_Date # Date: 2024-12-21 #----------------------------------------- # Title # Study_Name: Cobre Cave Geochemical Data from 116300 to 100600 Cal Yr BP #----------------------------------------- # Investigators # Investigators: Rossi, C.; Mertz-Kraus, R.; Osete, M.-L. #----------------------------------------- # Description_Notes_and_Keywords # Description: Data contributed as part of SISAL v3 Global Speleothem Isotope and Trace Element Database (https://doi.org/10.25921/jajq-qg60). Notes from the SISAL database: Entity PA-8 (SISAL entity_id = 561): Some U-Th ages are outside the range of the isototpe sampling. The published age model was created using laminae data not provided here. NIST SRM 612 was used for calibration of the element concentrations. For most elements, the measured concentrations on NIST SRM 614 and USGS MACS-3 agree within 13% with the preferred values reported in the GeoReM database and the mean values of Jochum et al. (2012), respectively. For the QCM, relative standard deviations for the averaged element concentrations were typically <10%. #----------------------------------------- # Publication # Authors: Rossi, Carlos; Regina Mertz-Kraus; María-Luisa Osete # Published_Date_or_Year: 2014 # Published_Title: Paleoclimate variability during the Blake geomagnetic excursion (MIS 5d) deduced from a speleothem record # Journal_Name: Quaternary Science Reviews # Volume: 102 # Edition: # Issue: # Pages: 166-180 # Report_Number: # DOI: 10.1016/j.quascirev.2014.08.007 # Online_Resource: # Full_Citation: Rossi, C., Mertz-Kraus, R. and Osete, M.-L.: Paleoclimate variability during the Blake geomagnetic excursion (MIS 5d) deduced from a speleothem record, Quat. Sci. Rev., 102, 166–180, 2014. # Abstract: #----------------------------------------- # Publication # Authors: Osete, María-Luisa; Javier Martín-Chivelet; Carlos Rossi; R. Lawrence Edwards; Ramon Egli; M. Belén Muñoz-García; Xianfeng Wang; F. Javier Pavón-Carrasco; Friedrich Heller # Published_Date_or_Year: 2012 # Published_Title: The Blake geomagnetic excursion recorded in a radiometrically dated speleothem # Journal_Name: Earth and Planetary Science Letters # Volume: 353-354 # Edition: # Issue: # Pages: 173-181 # Report_Number: # DOI: 10.1016/j.epsl.2012.07.041 # Online_Resource: # Full_Citation: Osete, M.-L., Martín-Chivelet, J., Rossi, C., Edwards, R. L., Egli, R., Muñoz-García, M. B., Wang, X., Pavón-Carrasco, F. J. and Heller, F.: The Blake geomagnetic excursion recorded in a radiometrically dated speleothem, Earth Planet. Sci. Lett., 353–354, 173–181, 2012. # Abstract: #----------------------------------------- # Publication # Authors: Kaushal, Nikita, Franziska A. Lechleitner, Micah Wilhelm, Khalil Azennoud, Janica C. Bühler, Kerstin Braun, Yassine Ait Brahim, Andy Baker, Yuval Burstyn, Laia Comas-Bru, Jens Fohlmeister, Yonaton Goldsmith, Sandy P. Harrison, István G. Hatvani, Kira Rehfeld, Magdalena Ritzau, Vanessa Skiba, Heather M. Stoll, József G. Szucs, Péter Tanos, Pauline C. Treble, Vitor Azevedo, Jonathan L. Baker, Andrea Borsato, Sakonvan Chawchai, Andrea Columbu, Laura Endres, Jun Hu, Zoltán Kern, Alena Kimbrough, Koray Koç, Monika Markowska, Belen Martrat, Syed Masood Ahmad, Carole Nehme, Valdir Felipe Novello, Carlos Pérez-Mejías, Jiaoyang Ruan, Natasha Sekhon, Nitesh Sinha, Carol V. Tadros, Benjamin H. Tiger, Sophie Warken, Annabel Wolf, Haiwei Zhang, and SISAL Working Group members # Published_Date_or_Year: 2024 # Published_Title: SISALv3: a global speleothem stable isotope and trace element database # Journal_Name: Earth System Science Data # Volume: 16 # Edition: # Issue: # Pages: 1933-1963 # Report_Number: # DOI: 10.5194/essd-16-1933-2024 # Online_Resource: # Full_Citation: # Abstract: Palaeoclimate information on multiple climate variables at different spatiotemporal scales is becoming increasingly important to understand environmental and societal responses to climate change. A lack of high-quality reconstructions of past hydroclimate has recently been identified as a critical research gap. Speleothems, with their precise chronologies, widespread distribution, and ability to record changes in local to regional hydroclimate variability, are an ideal source of such information. Here, we present a new version of the Speleothem Isotopes Synthesis and AnaLysis database (SISALv3), which has been expanded to include trace element ratios and Sr isotopes as additional, hydroclimate-sensitive geochemical proxies. The oxygen and carbon isotope data included in previous versions of the database have been substantially expanded. SISALv3 contains speleothem data from 365 sites from across the globe, including 95 , 85 , 52 , 25 , 29 , and 14 Sr-isotope records. The database also has increased spatiotemporal coverage for stable oxygen (892) and carbon (620) isotope records compared with SISALv2 (which consists of 673 and 430 stable oxygen and carbon records, respectively). Additional meta information has been added to improve the machine-readability and filtering of data. Standardized chronologies are included for all new entities along with the originally published chronologies. Thus, the SISALv3 database constitutes a unique resource of speleothem palaeoclimate information that allows regional to global palaeoclimate analyses based on multiple geochemical proxies, permitting more robust interpretations of past hydroclimate and comparisons with isotope-enabled climate models and other Earth system and hydrological models. The database can be accessed at https://doi.org/10.5287/ora-2nanwp4rk (Kaushal et al., 2024). #----------------------------------------- # Funding_Agency # Funding_Agency_Name: # Grant: #----------------------------------------- # Site_Information # Site_Name:Cobre Cave # Location:Spain # Northernmost_Latitude:42.98 # Southernmost_Latitude:42.98 # Easternmost_Longitude:-4.37 # Westernmost_Longitude:-4.37 # Elevation_m:1600 #----------------------------------------- # Data_Collection # Collection_Name: PA-8 isotopes Rossi2014 SISAL v3 # First_Year: 116341 # Last_Year: 100605 # Time_Unit: Cal Yr BP # Core_Length_m: # Parameter_Keywords: oxygen isotopes, carbon isotopes # Notes: Contact: Laura Endres; Carlos Pérez-Mejías; Type: stalagmite; Dist. from entrance (m): 1200; Entity Status: current; Depth Reference: from top; Overlying Bedrock Thickness (m): 150; Drip Type: unknown; Drip Height: NA; Drip Water Equilibrium Studies: unknown; Trace Elements Measured: ; Organics Measured: no; Fluid Inclusions Measured: yes; Fabric Studies: no; Clumped Isotopes Measured: no; Noble Gases Measured: no; C14 Measured: no; ODL Measurements: no; Mg/Ca Measured: yes; Type from WOKAM: NA; Vegetation Type: sparse; Land Use: unknown; Copernicus lcc: herbaceous vegetation; Cover Type: unknown; Host Rock Trace Elements: unknown; Drip Water Trace Elements: unknown; Isotope Standard: Vienna-PDB; d18O dripwater carbonate difference: NA; Ba/Ca Method: LA-ICP-MS; Ba/Ca Standard: NIST SRM 612; Ba/Ca Downsampled: Yes-SISAL downsampled; Ba/Ca Downsampling Method: ; Mg/Ca Method: LA-ICP-MS; Mg/Ca Standard: NIST SRM 612; Mg/Ca Downsampled: Yes-SISAL downsampled; Mg/Ca Downsampling Method: ; P/Ca Method: LA-ICP-MS; P/Ca Standard: NIST SRM 612; P/Ca Downsampled: Yes-SISAL downsampled; P/Ca Downsampling Method: ; Sr/Ca Method: unknown; Sr/Ca Standard: NIST SRM 612; Sr/Ca Downsampled: Yes-SISAL downsampled; Sr/Ca Downsampling Method: ; U/Ca Method: LA-ICP-MS; U/Ca Standard: NIST SRM 612; U/Ca Downsampled: Yes-SISAL downsampled; U/Ca Downsampling Method: ; Trace Elements Datafile: no; Trace Elements Metadata File: no; Cave Map: no; Entity Scan: no #----------------------------------------- # Chronology_Information # Chronology: Uranium-Thorium # Chronology_Download_Resource: https://www.ncei.noaa.gov/pub/data/paleo/templates/noaa-wds-paleo-uth-terms.csv # Chronology_Download_Description: Uranium-Thorium terms and definitions. # Chronology_Notes: Metadata and data from SISAL v3 database. # Rejection_Rationale: # 238U_Decay_Constant: Cheng et al. 2000 # 234U_Decay_Constant: Cheng et al. 2000 # 230Th_Decay_Constant: Cheng et al. 2000 # Initial_230Th/232Th: # Initial_230Th/232Th_Method: # Age_Model_Method: # Missing_Values: NA # Chronology_Table: # date_type depth_top_mm thick_mm samp_id material_dated weight_mg age_uncorr_BM age_uncorr_uncert_pos_yr age_uncorr_uncert_neg_yr date_used 238U_ppb 238U_uncert_ppb 232Th_ppt 232Th_uncert_ppb 230Th_ppt 230Th_uncert_ppb 230Th_232Th_act 230Th_232Th_act_uncert 230Th_238U_act 230Th_238U_act_uncert 234U_238U_act 234U_238U_act_uncert 230Th_232Th_act_init 230Th_232Th_act_init_uncert age_corr_BP1950 age_corr_uncert_pos_yr age_corr_uncert_neg_yr # ICP-MS U/Th Other 17.96 NA C8-1 calcite NA 100193.5 1108.83 1108.83 no 149.6 0.5 1385 6 NA NA NA NA 0.698 0.004 1.142 0.004 NA NA 99200 1200 1200 # ICP-MS U/Th Other 85.2 NA C8-3 calcite NA 104484.74 1449.61 1449.61 yes 92.3 0.3 2949 11 NA NA NA NA 0.667 0.005 1.072 0.004 NA NA 100600 2400 2400 # ICP-MS U/Th Other 122.35 NA C8-15 calcite NA 112073.71 1610.67 1610.67 yes 41.1 0.2 46 3 NA NA NA NA 0.714 0.005 1.097 0.004 NA NA 111900 1600 1600 # ICP-MS U/Th Other 181.4 NA C8-16 calcite NA 114553.6 1336.96 1336.96 yes 166.4 0.6 289 4 NA NA NA NA 0.772 0.005 1.163 0.003 NA NA 114400 1300 1300 # ICP-MS U/Th Other 251.1 NA C8-18 calcite NA 119661.58 1741.38 1741.38 yes 173.6 0.6 6682 29 NA NA NA NA 0.737 0.005 1.091 0.003 NA NA 115000 2900 2900 # ICP-MS U/Th Other 288 NA C8-20 calcite NA 115514.16 1525.7 1525.7 yes 151.5 0.7 231 3 NA NA NA NA 0.734 0.005 1.107 0.004 NA NA 115300 1500 1500 # ICP-MS U/Th Other 331.9 NA C8-22 calcite NA 116600.36 1368.27 1368.27 yes 184.6 0.6 489 3 NA NA NA NA 0.73 0.004 1.096 0.003 NA NA 116300 1400 1400 # ICP-MS U/Th Other 375.43 NA C8-24 calcite NA 117640.73 1557.74 1557.74 yes 123.3 0.5 1187 5 NA NA NA NA 0.725 0.005 1.085 0.004 NA NA 116500 1600 1600 # ICP-MS U/Th Other 432.25 NA C8-27 calcite NA 118747.92 1488.05 1488.05 no 158.1 0.6 418 4 NA NA NA NA 0.735 0.004 1.093 0.004 NA NA 118400 1500 1500 # ICP-MS U/Th Other 470.6 NA C8-28 calcite NA 119703.23 1647.89 1647.89 no 160.2 0.6 1030 6 NA NA NA NA 0.736 0.005 1.09 0.004 NA NA 118900 1700 1700 # ICP-MS U/Th Other 541.8 NA C8-30 calcite NA 119770.24 1622.51 1622.51 no 155.3 0.6 284 4 NA NA NA NA 0.727 0.005 1.078 0.004 NA NA 119600 1600 1600 # ICP-MS U/Th Other 598.65 NA C8-32 calcite NA 119992.76 1541.49 1541.49 no 187.2 0.7 120 4 NA NA NA NA 0.737 0.004 1.09 0.004 NA NA 119900 1500 1500 # Event; hiatus 100.335 NA NA NA NA NA NA NA no NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA #----------------------------------------- # Variables # PaST_Thesaurus_Download_Resource: https://www.ncei.noaa.gov/access/paleo-search/skos/past-thesaurus.rdf # PaST_Thesaurus_Download_Description: Paleoenvironmental Standard Terms (PaST) Thesaurus terms, definitions, and relationships in SKOS format. # ## depth_sample depth,,,millimeter,,speleothems,,,N, ## interp_age age,,,calendar year before present,,speleothems,,,N, ## d18O_measurement delta 18O,calcite,,per mil VPDB,,speleothems,,,N,measurement precision is 0.1 per mil ## d13C_measurement delta 13C,calcite,,per mil VPDB,,speleothems,,,N,measurement precision is 0.1 per mil ## Ba_Ca_measurement barium/calcium,,,millimole per mole,,speleothems,,,N, ## Mg_Ca_measurement barium/calcium,,,millimole per mole,,speleothems,,,N, ## P_Ca_measurement phosphorus/calcium,,,millimole per mole,,speleothems,,,N, ## Sr_Ca_measurement strontium/calcium,,,millimole per mole,,speleothems,,,N, ## U_Ca_measurement uranium/calcium,,,millimole per mole,,speleothems,,,N, #----------------------------------------- # Data: # Missing_Values: NA depth_sample interp_age d18O_measurement d13C_measurement Ba_Ca_measurement Mg_Ca_measurement P_Ca_measurement Sr_Ca_measurement U_Ca_measurement 95.8 100605.613697 -7.28493422 -5.06418084 0.00111943872770972 0.340990075667022 0.200873642668909 0.0149687678544416 1.59658715056431e-05 96.8 100638.613697 -7.5806733 -5.51775996 0.00129200273325975 0.317238571831911 0.213301640354679 0.0167194987731814 2.03854487019163e-05 97.8 100676.613697 -7.56698354 -5.20085784 0.00129200273325975 0.347532811899665 0.216175020113535 0.0170014633183725 2.03120765998529e-05 98.8 100706.613697 -7.65808084 -5.07059052 0.00105198011134317 0.358068585597944 0.207954245043885 0.014342038195211 2.059121857723e-05 99.85 100733.613697 -7.74970946 -5.18596476 0.00103535823253462 0.46141852462446 0.280500218991978 0.0117837456821335 1.59208170115627e-05 100.335 NA NA NA NA NA NA NA NA 100.82 111959.2 -8.02783304 -4.86218166 0.00112579738498856 0.369200064162718 0.245743149006018 0.0151304487219913 1.83744443905402e-05 101.82 111980 -7.7304834 -3.0551232 0.0013501759491361 0.366967555190476 0.261990161910592 0.0178342852129055 2.84431394112968e-05 102.81 112019 -8.33736254 -3.51850536 0.000734235651530326 0.432857075718895 0.259752663091628 0.0118856700647998 1.92770616085714e-05 103.85 112054 -7.76289592 -3.8761278 0.000734235651530326 0.361171359327106 0.305312297789983 0.0118205451490326 1.88032451376505e-05 104.89 112080.5 -7.99079016 -2.89045098 0.00107649080495444 0.385017346313354 0.147905573598005 0.0163359544198975 1.80781676532655e-05 105.87 112129 -8.32578664 -3.1668213 0.00124116599570175 0.391379092563648 0.201214314235497 0.0159824515902024 1.94096470087067e-05 106.85 112153 -8.15486596 -3.59890914 0.00120890005912416 0.405199518670755 0.179865173403356 0.0168834530168215 1.67584305705792e-05 107.86 112175 -8.0354832 -3.73011906 0.00109989010568981 0.395338256128059 0.187355516071646 0.0164566852955478 1.42595998409059e-05 108.88 112200 -8.35377012 -3.23695074 0.00123480733842291 0.398116671056358 0.197273241205034 0.0166719923506353 1.8825733614421e-05 109.9 112225 -7.92354928 -3.57694656 0.00134381729185726 0.382229862905926 0.189148248079228 0.0180058812635198 1.37801418656575e-05 110.89 112250.5 -8.13825706 -3.62558472 0.00174173768259433 0.391568062203148 0.167508887018569 0.0215916296166779 1.65864321806909e-05 111.89 112270.5 -7.98001954 -4.0274151 0.00123480733842291 0.399320765291674 0.233309118277239 0.0166857644549551 1.27027993190168e-05 112.89 112286.5 -8.15546992 -4.31707608 0.00163908638643882 0.385516523535326 0.175636532285455 0.0202286340146968 1.95082732965315e-05 113.92 112303.5 -8.13533792 -4.4256636 0.000840318861753308 0.409881276458886 0.363320195166856 0.0125385027676364 2.14853572658669e-05 114.95 112325 -8.15869104 -4.66498974 0.000814411582454552 0.440133756545268 0.287725040791476 0.0122565382224453 1.93813294007237e-05 115.97 112349 -7.77819624 -3.60824088 0.000990880152255456 0.391431594182428 0.178174391004429 0.0149144008651498 1.44288712920729e-05 116.98 112364.5 -7.57365512 -3.10347858 0.00138536862892506 0.338415726258844 0.247414647878546 0.0178112877564468 2.84996257706474e-05 117.99 112388 -8.10201946 -3.81598992 0.00135653460641494 0.339967289041712 0.206899987554647 0.0163663000795853 2.26474650095716e-05 119 112414 -8.19684118 -4.08010644 0.0013086246120683 0.348128038164304 0.178805690354424 0.0183062455421605 1.84759852439712e-05 120.01 112454.5 -8.05048154 -3.6216258 0.00162001041460231 0.332238372669426 0.167730356692023 0.0193190970668644 1.33740559924724e-05 121.02 112475 -8.28854244 -4.10979834 0.001526644518937 0.331544454811238 0.183179566094594 0.0200063644512069 1.7621485942242e-05 122.03 112491 -8.12778842 -4.15975614 0.00170947174601674 0.3356263357425 0.163325844656116 0.0229906329129758 1.37999421739764e-05 123.04 112517 -7.98022086 -3.93607716 0.00150073723963825 0.304498393600402 0.213854613822754 0.0185169654065927 2.39447362355176e-05 124.08 112534.5 -7.87431326 -3.92761064 0.0013594613496263 0.366192748918414 0.184913066319445 0.01765957304279 1.72435300501551e-05 125.07 112568 -8.18152758 -5.24395154 0.00155891045551459 0.35677142505566 0.172893031484508 0.0186716942980938 1.63748719444343e-05 126.07 112595 -7.95242542 -4.16938754 0.0014850931818692 0.333441628973138 0.227600487369092 0.0191076364006782 2.17786192769659e-05 127.05 112619 -8.06959366 -4.17570296 0.00117734423324009 0.35679477911038 0.256991474606253 0.0151972317394427 1.99615191791343e-05 128.03 112639 -7.84109546 -4.44302432 0.00105198011134317 0.33585437349216 0.319935785002056 0.0149082301293297 1.55147311383777e-05 129.02 112666 -7.6552771 -4.09463936 0.001526644518937 0.340705462572659 0.290917044898274 0.0177139505644358 3.39315418545467e-05 130.04 112688 -7.94125216 -4.77444248 0.00124752465298059 0.377295680582898 0.235647621756685 0.0154223794210754 2.09806063345873e-05 131.08 112707 -7.95957228 -4.97342534 0.00160046179258239 0.353668261290504 0.229789436253513 0.0203549864865016 2.98983990797549e-05 132.08 112725 -7.96339736 -4.60015574 0.00141763456550265 0.378459093926271 0.228001014651863 0.0169301781991391 2.42662057682538e-05 133.1 112740 -7.82710372 -4.66887128 0.0015681958560048 0.344520769828429 0.319700625555555 0.0172374030445255 3.71128347257913e-05 134.08 112754 -7.77174072 -4.49486732 0.00159410313530355 0.313684560549915 0.315817270767038 0.0178352262923187 4.74039471326915e-05 135.8 112781.5 -8.2537008 -6.40334954 0.00177693036238329 0.318224794883028 0.262840219204144 0.0185177062083467 3.98684678126866e-05 136.83 112813 -8.084592 -5.44934408 0.00166448849488148 0.328128202081872 0.274206399871569 0.0174572463194399 3.0970100122068e-05 137.84 112830 -8.18968104 -5.71035002 0.00217777749633173 0.301023057827386 0.188908186028111 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