#    Buckeye creek Geochemical Data from 126700 to 41600 Cal Yr BP
#----------------------------------------------------------------------------------------
#               World Data Service for Paleoclimatology, Boulder
#                                   and
#                       NOAA Paleoclimatology Program
#----------------------------------------------------------------------------------------
# Template Version 4.0
# Encoding: UTF-8
# NOTE: Please cite original publication, NOAA Landing Page URL, dataset and publication DOIs (where available), and date accessed when using downloaded data.
# If there is no publication information, please cite Investigator, Title, NOAA Landing Page URL, and date accessed.
#   
# Description/Documentation lines begin with #
# Data lines have no #
#   
# NOAA_Landing_Page: https://www.ncei.noaa.gov/access/paleo-search/study/40783
#   Landing_Page_Description: NOAA Landing Page of this data file's parent study, which includes all study metadata.
#
# Study_Level_JSON_Metadata: https://www.ncei.noaa.gov/pub/data/metadata/published/paleo/json/noaa-cave-40783.json
#   Study_Level_JSON_Description: JSON metadata of this data file's parent study, which includes all study metadata.
#
# Data_Type: Speleothems
#   
# Dataset_DOI:
#   
# Science_Keywords:
#-----------------------------------------
# Resource_Links
#   
# Data_Download_Resource: https://www.ncei.noaa.gov/pub/data/paleo/speleothem/SISAL-v3/noaa_templates/Springer2014-BCC-10_2014.txt
#   Data_Download_Description: NOAA Template File; BCC-10_2014 Speleothem Geochemical Data
#   
# Related_Online_Resource:  https://www.ncei.noaa.gov/access/paleo-search/study/39799
#   Related_Online_Description: URL; SISAL v3 Database Landing Page
#   
#-----------------------------------------
# Contribution_Date
#   Date: 2024-09-02
#-----------------------------------------
# File_Last_Modified_Date
#   Date: 2024-12-21
#-----------------------------------------
# Title
#   Study_Name: Buckeye creek Geochemical Data from 126700 to 41600 Cal Yr BP
#-----------------------------------------
# Investigators
#   Investigators: Springer, G. S.; Rowe, H. D.; Hardt, B.; Cheng, H.; Edwards, R. L.
#-----------------------------------------
# Description_Notes_and_Keywords
#   Description: Data contributed as part of SISAL v3 Global Speleothem Isotope and Trace Element Database (https://doi.org/10.25921/jajq-qg60). Notes from the SISAL database: Vegetation and land use: Forest with patches of grass and farmland. \\ Entity BCC-10_2019 (SISAL entity_id = 682): Samples from the section below 204.75mm in original dataset not included due to age inversions.
#-----------------------------------------
# Publication
#   Authors: Springer, Gregory S.; Harold D. Rowe; Ben Hardt; Hai Cheng; R. Lawrence Edwards
#   Published_Date_or_Year: 2014
#   Published_Title: East central North America climates during marine isotope stages 3-5
#   Journal_Name: Geophysical Research Letters
#   Volume: 41
#   Edition:
#   Issue: 9
#   Pages: 3233-3237
#   Report_Number:
#   DOI: 10.1002/2014gl059884
#   Online_Resource:
#   Full_Citation: Springer, G. S., Rowe, H. D., Hardt, B., Cheng, H. and Edwards, R. L.: East central North America climates during marine isotope stages 3-5, Geophys. Res. Lett., 41(9), 3233–3237, 2014.
#   Abstract:
#-----------------------------------------
# Publication
#   Authors: Kaushal, Nikita, Franziska A. Lechleitner, Micah Wilhelm, Khalil Azennoud, Janica C. Bühler, Kerstin Braun, Yassine Ait Brahim, Andy Baker, Yuval Burstyn, Laia Comas-Bru, Jens Fohlmeister, Yonaton Goldsmith, Sandy P. Harrison, István G. Hatvani, Kira Rehfeld, Magdalena Ritzau, Vanessa Skiba, Heather M. Stoll, József G. Szucs, Péter Tanos, Pauline C. Treble, Vitor Azevedo, Jonathan L. Baker, Andrea Borsato, Sakonvan Chawchai, Andrea Columbu, Laura Endres, Jun Hu, Zoltán Kern, Alena Kimbrough, Koray Koç, Monika Markowska, Belen Martrat, Syed Masood Ahmad, Carole Nehme, Valdir Felipe Novello, Carlos Pérez-Mejías, Jiaoyang Ruan, Natasha Sekhon, Nitesh Sinha, Carol V. Tadros, Benjamin H. Tiger, Sophie Warken, Annabel Wolf, Haiwei Zhang, and SISAL Working Group members
#   Published_Date_or_Year: 2024
#   Published_Title: SISALv3: a global speleothem stable isotope and trace element database
#   Journal_Name: Earth System Science Data
#   Volume: 16
#   Edition:
#   Issue:
#   Pages: 1933-1963
#   Report_Number:
#   DOI: 10.5194/essd-16-1933-2024
#   Online_Resource:
#   Full_Citation:
#   Abstract: Palaeoclimate information on multiple climate variables at different spatiotemporal scales is becoming increasingly important to understand environmental and societal responses to climate change. A lack of high-quality reconstructions of past hydroclimate has recently been identified as a critical research gap. Speleothems, with their precise chronologies, widespread distribution, and ability to record changes in local to regional hydroclimate variability, are an ideal source of such information. Here, we present a new version of the Speleothem Isotopes Synthesis and AnaLysis database (SISALv3), which has been expanded to include trace element ratios and Sr isotopes as additional, hydroclimate-sensitive geochemical proxies. The oxygen and carbon isotope data included in previous versions of the database have been substantially expanded. SISALv3 contains speleothem data from 365 sites from across the globe, including 95 , 85 , 52 , 25 , 29 , and 14 Sr-isotope records. The database also has increased spatiotemporal coverage for stable oxygen (892) and carbon (620) isotope records compared with SISALv2 (which consists of 673 and 430 stable oxygen and carbon records, respectively). Additional meta information has been added to improve the machine-readability and filtering of data. Standardized chronologies are included for all new entities along with the originally published chronologies. Thus, the SISALv3 database constitutes a unique resource of speleothem palaeoclimate information that allows regional to global palaeoclimate analyses based on multiple geochemical proxies, permitting more robust interpretations of past hydroclimate and comparisons with isotope-enabled climate models and other Earth system and hydrological models. The database can be accessed at https://doi.org/10.5287/ora-2nanwp4rk (Kaushal et al., 2024).
#-----------------------------------------
# Funding_Agency
#   Funding_Agency_Name:
#   Grant:
#-----------------------------------------
# Site_Information
#   Site_Name:Buckeye creek
#    Location: North America>United States Of America>West Virginia
#   Northernmost_Latitude:37.98
#   Southernmost_Latitude:37.98
#   Easternmost_Longitude:-80.4
#   Westernmost_Longitude:-80.4
#   Elevation_m:600
#-----------------------------------------
# Data_Collection
#   Collection_Name: BCC-10_2014 isotopes Springer2014 SISAL v3
#   First_Year: 124036
#   Last_Year: 41604
#   Time_Unit: Cal Yr BP
#   Core_Length_m: 
#    Parameter_Keywords: oxygen isotopes, carbon isotopes
#    Notes:  Contact: Kira Rehfeld; Type: stalagmite; Dist. from entrance (m): 1000; Entity Status: superseded; Depth Reference: from top; Overlying Bedrock Thickness (m): 35; Drip Type: unknown; Drip Height: NA; Drip Water Equilibrium Studies: unknown; Trace Elements Measured: ; Organics Measured: unknown; Fluid Inclusions Measured: unknown; Fabric Studies: unknown; Clumped Isotopes Measured: unknown; Noble Gases Measured: no; C14 Measured: no; ODL Measurements: no; Mg/Ca Measured: no; Type from WOKAM: discontinuous carbonate; Vegetation Type: deciduous; Land Use: forest; Copernicus lcc: closed forest, deciduous broad leaf; Cover Type: unknown; Host Rock Trace Elements: unknown; Drip Water Trace Elements: unknown; Isotope Standard: Vienna-PDB; d18O dripwater carbonate difference: NA; Trace Elements Datafile: no; Trace Elements Metadata File: NA; Cave Map: no; Entity Scan: no
#-----------------------------------------
# Chronology_Information
#   Chronology: Uranium-Thorium
#   Chronology_Download_Resource:  https://www.ncei.noaa.gov/pub/data/paleo/templates/noaa-wds-paleo-uth-terms.csv
#     Chronology_Download_Description: Uranium-Thorium terms and definitions.
#   Chronology_Notes: Metadata and data from SISAL v3 database.
#   Rejection_Rationale:
#   238U_Decay_Constant: Cheng et al. 2000
#   234U_Decay_Constant: Cheng et al. 2000
#   230Th_Decay_Constant: Cheng et al. 2000
#   Initial_230Th/232Th:
#   Initial_230Th/232Th_Method:
#   Age_Model_Method:
#   Missing_Values: NA
#   Chronology_Table:
#	date_type	depth_top_mm	thick_mm	samp_id	material_dated	weight_mg	age_uncorr_BM	age_uncorr_uncert_pos_yr	age_uncorr_uncert_neg_yr	date_used	238U_ppb	238U_uncert_ppb	232Th_ppt	232Th_uncert_ppb	230Th_ppt	230Th_uncert_ppb	230Th_232Th_act	230Th_232Th_act_uncert	230Th_238U_act	230Th_238U_act_uncert	234U_238U_act	234U_238U_act_uncert	230Th_232Th_act_init	230Th_232Th_act_init_uncert	age_corr_BP1950	age_corr_uncert_pos_yr	age_corr_uncert_neg_yr
#	MC-ICP-MS U/Th	1.25	1	NA	unknown	NA	42760	100	100	unknown	1264.6	1.4	2167	40	NA	NA	7590	150	0.7892	0.0013	2.3501	0.0028	0.816	0.408	42760	100	100
#	MC-ICP-MS U/Th	12.5	1	NA	unknown	NA	51450	130	130	unknown	1694.4	2.1	282	7	NA	NA	93600	2400	0.9448	0.0017	2.4106	0.0024	0.816	0.408	51450	130	130
#	MC-ICP-MS U/Th	24	1	NA	unknown	NA	55420	150	150	unknown	1544.6	2	357	9	NA	NA	70600	1700	0.9906	0.0019	2.3798	0.0025	0.816	0.408	55420	150	150
#	MC-ICP-MS U/Th	31.5	1	NA	unknown	NA	57470	140	140	unknown	1931.5	2.4	190	6	NA	NA	170000	5000	1.014	0.0018	2.3668	0.0022	0.816	0.408	57470	140	140
#	MC-ICP-MS U/Th	41.25	1	NA	unknown	NA	60180	150	150	unknown	2004.8	2.4	468	10	NA	NA	75000	1600	1.0612	0.0018	2.3871	0.0022	0.816	0.408	60180	150	150
#	MC-ICP-MS U/Th	50	1	NA	unknown	NA	62680	140	140	unknown	2127	2.3	268	7	NA	NA	141000	3000	1.0774	0.0017	2.3483	0.0018	0.816	0.408	62680	140	140
#	MC-ICP-MS U/Th	58.25	1	NA	unknown	NA	64850	170	170	unknown	2051.8	2.4	509	10	NA	NA	72300	1500	1.088	0.0018	2.3098	0.0027	0.816	0.408	64850	170	170
#	MC-ICP-MS U/Th	68	1	NA	unknown	NA	66810	160	160	unknown	1877.3	2	128	2.6	NA	NA	269000	6000	1.117	0.0017	2.3187	0.0024	0.816	0.408	66810	160	160
#	MC-ICP-MS U/Th	75	1	NA	unknown	NA	68800	160	160	unknown	1745.9	1.9	137	5	NA	NA	240000	8000	1.145	0.0018	2.3229	0.0019	0.816	0.408	68800	160	160
#	MC-ICP-MS U/Th	82	1	NA	unknown	NA	70790	180	180	unknown	1627	1.9	190	6	NA	NA	164000	5000	1.16	0.0019	2.3043	0.0022	0.816	0.408	70790	180	180
#	MC-ICP-MS U/Th	91.25	1	NA	unknown	NA	73530	180	180	unknown	1647.5	1.9	449	10	NA	NA	71200	1600	1.1765	0.0019	2.2719	0.0019	0.816	0.408	73530	180	180
#	MC-ICP-MS U/Th	103	1	NA	unknown	NA	78200	220	220	unknown	1154.4	1.4	712	15	NA	NA	32300	700	1.2093	0.0021	2.2325	0.0022	0.816	0.408	78200	220	220
#	MC-ICP-MS U/Th	112.25	1	NA	unknown	NA	81600	210	210	unknown	1265	1.4	390	9	NA	NA	66300	1500	1.239	0.002	2.2183	0.0018	0.816	0.408	81600	210	210
#	MC-ICP-MS U/Th	125.25	1	NA	unknown	NA	88040	260	260	unknown	1360.4	1.7	337	8	NA	NA	85200	2000	1.28	0.0023	2.1723	0.0022	0.816	0.408	88040	260	260
#	MC-ICP-MS U/Th	130.25	1	NA	unknown	NA	90310	240	240	unknown	1123.7	1.2	351	7	NA	NA	67800	1400	1.283	0.0019	2.1407	0.0023	0.816	0.408	90310	240	240
#	MC-ICP-MS U/Th	137.5	1	NA	unknown	NA	96120	270	270	unknown	734.3	0.8	1499	30	NA	NA	10440	210	1.292	0.0021	2.0698	0.0021	0.816	0.408	96120	270	270
#	MC-ICP-MS U/Th	142.75	1	NA	unknown	NA	98100	300	300	unknown	977.8	1.2	677	14	NA	NA	31000	700	1.302	0.0024	2.0573	0.0023	0.816	0.408	98100	300	300
#	MC-ICP-MS U/Th	146	1	NA	unknown	NA	100010	280	280	unknown	864	1	878	18	NA	NA	21300	400	1.312	0.0021	2.0466	0.0018	0.816	0.408	100010	280	280
#	MC-ICP-MS U/Th	158	1	NA	unknown	NA	105500	300	300	unknown	937.7	1	394	9	NA	NA	52000	1200	1.325	0.0022	1.9989	0.0017	0.816	0.408	105500	300	300
#	MC-ICP-MS U/Th	171	1	NA	unknown	NA	110600	300	300	unknown	684.6	0.8	1474	30	NA	NA	10510	210	1.3732	0.0023	2.0092	0.002	0.816	0.408	110600	300	300
#	MC-ICP-MS U/Th	181.75	1	NA	unknown	NA	115200	400	400	unknown	990.2	1.2	488	9.8	NA	NA	47200	900	1.4092	0.0023	2.0098	0.0023	0.816	0.408	115200	400	400
#	MC-ICP-MS U/Th	188.25	1	NA	unknown	NA	117300	400	400	unknown	756.4	0.8	895	19	NA	NA	19500	400	1.4012	0.0023	1.9781	0.0018	0.816	0.408	117300	400	400
#	MC-ICP-MS U/Th	195	1	NA	unknown	NA	120600	400	400	unknown	853.2	0.9	1389	28	NA	NA	14270	290	1.4085	0.0023	1.956	0.0022	0.816	0.408	120600	400	400
#	MC-ICP-MS U/Th	201	1	NA	unknown	NA	122600	400	400	unknown	928.1	1	893	18	NA	NA	24800	500	1.4456	0.0024	1.9852	0.0022	0.816	0.408	122600	400	400
#	MC-ICP-MS U/Th	207.5	1	NA	unknown	NA	125400	400	400	unknown	861.2	1	1697	30	NA	NA	12260	250	1.4649	0.0023	1.9845	0.0022	0.816	0.408	125400	400	400
#-----------------------------------------
#  Variables
#    PaST_Thesaurus_Download_Resource: https://www.ncei.noaa.gov/access/paleo-search/skos/past-thesaurus.rdf
#    PaST_Thesaurus_Download_Description: Paleoenvironmental Standard Terms (PaST) Thesaurus terms, definitions, and relationships in SKOS format.
#
## depth_sample	depth,,,millimeter,,speleothems,,,N,
## interp_age	age,,,calendar year before present,,speleothems,,,N,
## d18O_measurement	delta 18O,calcite,,per mil VPDB,,speleothems,,,N,measurement precision is 0.01 per mil
## d13C_measurement	delta 13C,calcite,,per mil VPDB,,speleothems,,,N,measurement precision is 0.01 per mil
#-----------------------------------------
# Data:
# Missing_Values: NA
depth_sample	interp_age	d18O_measurement	d13C_measurement
0.25	41604	-5.01	0.18
0.75	42188	-5.27	0.62
1.25	42755	-5.24	0.77
1.75	43303	-5.39	1.06
2.25	43834	-5.02	0.37
2.75	44347	-4.97	0.19
3.25	44844	-4.97	0.09
3.75	45324	-5.01	0.33
4.25	45788	-5.09	1.13
4.75	46237	-4.88	1.22
5.25	46670	-5.21	0.07
5.75	47088	-5.34	-0.74
6.25	47491	-5.3	-0.84
6.75	47880	-5.46	-0.96
7.25	48255	-5.35	-0.95
7.75	48617	-5.34	-1.01
8.25	48965	-5.38	-1.06
8.75	49301	-5.26	-1.06
9.25	49624	-5.28	-0.99
9.75	49936	-5.3	-0.98
10.25	50235	-5.44	-1.09
10.75	50523	-5.22	-1.04
11.25	50801	-5.3	-1.08
11.75	51068	-5.32	-1.04
12.25	51324	-5.26	-0.92
12.75	51571	-5.3	-0.83
13.25	51808	-5.2	-0.84
13.75	52037	-5.09	-0.81
14.25	52256	-5.32	-0.88
14.75	52468	-5.28	-0.89
15.25	52672	-5.5	-0.94
15.75	52868	-5.58	-0.8
16.25	53058	-5.53	-0.89
16.75	53241	-5.45	-0.94
17.25	53418	-5.58	-0.97
17.75	53589	-5.81	-1.03
18.25	53755	-5.71	-0.86
18.75	53916	-5.84	-0.66
19.25	54073	-5.83	-0.54
19.75	54226	-5.99	-0.49
20.25	54375	-5.33	-0.72
20.75	54521	-5.81	-0.91
21.25	54665	-5.77	-0.85
21.75	54806	-5.66	-0.88
22.25	54945	-5.69	-0.92
22.75	55083	-5.74	-1.04
23.25	55219	-5.8	-1.14
23.75	55355	-5.7	-1.06
24.25	55491	-5.51	-0.84
24.75	55627	-5.52	-0.68
25.25	55763	-5.66	-0.51
25.75	55898	-5.49	-0.5
26.25	56034	-5.72	-0.41
26.75	56170	-5.29	-0.24
27.25	56306	-5.41	-0.28
27.75	56442	-5.53	-0.4
28.25	56578	-5.61	-1.32
28.75	56714	-5.47	-1.53
29.25	56851	-5.61	-1.62
29.75	56987	-5.76	-1.67
30.25	57124	-5.53	-1.61
30.75	57260	-5.74	-1.66
31.25	57397	-5.72	-1.76
31.75	57534	-5.82	-1.67
32.25	57671	-5.74	-1.67
32.75	57809	-5.83	-1.71
33.25	57946	-5.56	-1.57
33.75	58084	-5.37	-1.63
34.25	58222	-5.71	-1.72
34.75	58360	-5.78	-1.59
35.25	58498	-5.66	-1.55
35.75	58637	-5.75	-1.57
36.25	58776	-5.7	-1.51
36.75	58915	-5.74	-1.57
37.25	59054	-5.57	-1.53
37.75	59193	-5.7	-1.29
38.25	59333	-5.84	-1.4
38.75	59473	-5.57	-1.41
39.25	59614	-5.74	-1.33
39.75	59754	-5.69	-1.2
40.25	59895	-5.82	-1.2
40.75	60036	-5.98	-1.17
41.25	60178	-5.82	-1.22
41.75	60319	-5.85	-1.29
42.25	60461	-5.71	-1.39
42.75	60604	-5.8	-1.52
43.25	60746	-5.75	-1.43
43.75	60889	-5.74	-1.25
44.25	61032	-5.55	-1.07
44.75	61175	-5.79	-1.09
45.25	61318	-5.72	-1.16
45.75	61462	-5.69	-1.07
46.25	61605	-5.63	-1.03
46.75	61748	-5.78	-1.09
47.25	61892	-5.55	-0.99
47.75	62035	-5.59	-0.96
48.25	62179	-5.63	-0.94
48.75	62322	-5.6	-1.01
49.25	62466	-5.57	-0.92
49.75	62609	-5.53	-0.86
50.25	62752	-5.57	-0.99
50.75	62896	-5.59	-1.04
51.25	63038	-5.72	-1.07
51.75	63180	-5.69	-0.98
52.25	63321	-5.59	-0.95
52.75	63461	-5.86	-0.89
53.25	63599	-5.79	-0.99
53.75	63736	-5.84	-1.01
54.25	63871	-5.89	-0.96
54.75	64003	-5.62	-0.96
55.25	64134	-5.68	-1.21
55.75	64262	-5.84	-1.36
56.25	64387	-5.64	-1.14
56.75	64509	-5.54	-1.21
57.25	64628	-5.69	-1.38
57.75	64743	-5.89	-1.48
58.25	64855	-5.67	-1.4
58.75	64963	-5.73	-1.33
59.25	65067	-5.68	-1.42
59.75	65168	-5.76	-1.26
60.25	65267	-5.87	-1.11
60.75	65363	-5.77	-1.24
61.25	65458	-5.69	-1.34
61.75	65552	-5.35	-1.4
62.25	65645	-5.39	-1.47
62.75	65738	-5.59	-1.5
63.25	65831	-5.64	-1.47
63.75	65925	-5.58	-1.39
64.25	66020	-5.53	-1.22
64.75	66116	-5.61	-1.01
65.25	66214	-5.49	-0.89
65.75	66316	-5.66	-0.97
66.25	66420	-5.41	-0.96
66.75	66527	-5.44	-0.95
67.25	66639	-5.43	-1
67.75	66754	-5.54	-1.03
68.25	66875	-5.39	-1.04
68.75	67001	-5.3	-1
69.25	67130	-5.31	-1.03
69.75	67264	-5.54	-1.11
70.25	67402	-5.53	-1.14
70.75	67542	-5.37	-1.14
71.25	67686	-5.38	-1.21
71.75	67831	-5.29	-1.27
72.25	67978	-5.22	-1.2
72.75	68127	-5.31	-1.26
73.25	68276	-5.18	-1.44
73.75	68426	-5.33	-1.52
74.25	68576	-5.38	-1.75
74.75	68726	-5.64	-1.77
75.25	68874	-5.47	-1.64
75.75	69022	-5.25	-1.74
76.25	69169	-5.41	-1.86
76.75	69314	-5.16	-1.78
77.25	69459	-5.23	-1.94
77.75	69602	-5.26	-2.07
78.25	69745	-5.24	-2.08
78.75	69887	-5.18	-1.96
79.25	70028	-5.14	-1.79
79.75	70169	-5.08	-1.9
80.25	70308	-5.21	-2.11
80.75	70447	-5.32	-2.18
81.25	70585	-5.45	-2.36
81.75	70722	-5.45	-2.26
82.25	70859	-5.16	-2.24
82.75	70996	-5.14	-2.5
83.25	71132	-5.08	-2.55
83.75	71268	-5.03	-2.7
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95.75	75271	-4.99	-3
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201.75	122879	-4.89	-4.42
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203.25	123417	-4.88	-4.31
203.75	123613	-5.15	-4.48
204.25	123819	-4.92	-4.15
204.75	124036	-5.22	-3.68