# Guillotine Cave, Ruakuri Cave Geochemical Data from 76200 to -55 Cal Yr BP #---------------------------------------------------------------------------------------- # World Data Service for Paleoclimatology, Boulder # and # NOAA Paleoclimatology Program #---------------------------------------------------------------------------------------- # Template Version 4.0 # Encoding: UTF-8 # NOTE: Please cite original publication, NOAA Landing Page URL, dataset and publication DOIs (where available), and date accessed when using downloaded data. # If there is no publication information, please cite Investigator, Title, NOAA Landing Page URL, and date accessed. # # Description/Documentation lines begin with # # Data lines have no # # # NOAA_Landing_Page: https://www.ncei.noaa.gov/access/paleo-search/study/40887 # Landing_Page_Description: NOAA Landing Page of this data file's parent study, which includes all study metadata. # # Study_Level_JSON_Metadata: https://www.ncei.noaa.gov/pub/data/metadata/published/paleo/json/noaa-cave-40887.json # Study_Level_JSON_Description: JSON metadata of this data file's parent study, which includes all study metadata. # # Data_Type: Speleothems # # Dataset_DOI: # # Science_Keywords: #----------------------------------------- # Resource_Links # # Data_Download_Resource: https://www.ncei.noaa.gov/pub/data/paleo/speleothem/SISAL-v3/noaa_templates/Whittaker2008-GT05-5.txt # Data_Download_Description: NOAA Template File; GT05-5 Speleothem Geochemical Data # # Related_Online_Resource: https://www.ncei.noaa.gov/access/paleo-search/study/39799 # Related_Online_Description: URL; SISAL v3 Database Landing Page # #----------------------------------------- # Contribution_Date # Date: 2024-09-02 #----------------------------------------- # File_Last_Modified_Date # Date: 2024-12-21 #----------------------------------------- # Title # Study_Name: Guillotine Cave, Ruakuri Cave Geochemical Data from 76200 to -55 Cal Yr BP #----------------------------------------- # Investigators # Investigators: Whittaker, T. E. #----------------------------------------- # Description_Notes_and_Keywords # Description: Data contributed as part of SISAL v3 Global Speleothem Isotope and Trace Element Database (https://doi.org/10.25921/jajq-qg60). Notes from the SISAL database: Entity GT05-5 (SISAL entity_id = 326): no age model in original publication. This update is based on COPRA (Breitenbach et al., 2012) using a PCH spline. Actively growing event in 2006CE assumed based on thesis publication and field work dates. #----------------------------------------- # Publication # Authors: Whittaker, T. E. # Published_Date_or_Year: 2008 # Published_Title: High-resolution speleothem-based palaeoclimate records from New Zealand reveal robust teleconnection to North Atlantic during MIS 1-4 # Journal_Name: High-resolution speleothem-based palaeoclimate records from New Zealand reveal robust teleconnection to North Atlantic during MIS 1-4 # Volume: Ph.D. # Edition: # Issue: thesis # Pages: The University of Waikato. # Report_Number: # DOI: # Online_Resource: # Full_Citation: Whittaker, T. E.: High-resolution speleothem-based palaeoclimate records from New Zealand reveal robust teleconnection to North Atlantic during MIS 1-4, Ph.D. thesis, The University of Waikato., 2008. # Abstract: #----------------------------------------- # Publication # Authors: Kaushal, Nikita, Franziska A. Lechleitner, Micah Wilhelm, Khalil Azennoud, Janica C. Bühler, Kerstin Braun, Yassine Ait Brahim, Andy Baker, Yuval Burstyn, Laia Comas-Bru, Jens Fohlmeister, Yonaton Goldsmith, Sandy P. Harrison, István G. Hatvani, Kira Rehfeld, Magdalena Ritzau, Vanessa Skiba, Heather M. Stoll, József G. Szucs, Péter Tanos, Pauline C. Treble, Vitor Azevedo, Jonathan L. Baker, Andrea Borsato, Sakonvan Chawchai, Andrea Columbu, Laura Endres, Jun Hu, Zoltán Kern, Alena Kimbrough, Koray Koç, Monika Markowska, Belen Martrat, Syed Masood Ahmad, Carole Nehme, Valdir Felipe Novello, Carlos Pérez-Mejías, Jiaoyang Ruan, Natasha Sekhon, Nitesh Sinha, Carol V. Tadros, Benjamin H. Tiger, Sophie Warken, Annabel Wolf, Haiwei Zhang, and SISAL Working Group members # Published_Date_or_Year: 2024 # Published_Title: SISALv3: a global speleothem stable isotope and trace element database # Journal_Name: Earth System Science Data # Volume: 16 # Edition: # Issue: # Pages: 1933-1963 # Report_Number: # DOI: 10.5194/essd-16-1933-2024 # Online_Resource: # Full_Citation: # Abstract: Palaeoclimate information on multiple climate variables at different spatiotemporal scales is becoming increasingly important to understand environmental and societal responses to climate change. A lack of high-quality reconstructions of past hydroclimate has recently been identified as a critical research gap. Speleothems, with their precise chronologies, widespread distribution, and ability to record changes in local to regional hydroclimate variability, are an ideal source of such information. Here, we present a new version of the Speleothem Isotopes Synthesis and AnaLysis database (SISALv3), which has been expanded to include trace element ratios and Sr isotopes as additional, hydroclimate-sensitive geochemical proxies. The oxygen and carbon isotope data included in previous versions of the database have been substantially expanded. SISALv3 contains speleothem data from 365 sites from across the globe, including 95 , 85 , 52 , 25 , 29 , and 14 Sr-isotope records. The database also has increased spatiotemporal coverage for stable oxygen (892) and carbon (620) isotope records compared with SISALv2 (which consists of 673 and 430 stable oxygen and carbon records, respectively). Additional meta information has been added to improve the machine-readability and filtering of data. Standardized chronologies are included for all new entities along with the originally published chronologies. Thus, the SISALv3 database constitutes a unique resource of speleothem palaeoclimate information that allows regional to global palaeoclimate analyses based on multiple geochemical proxies, permitting more robust interpretations of past hydroclimate and comparisons with isotope-enabled climate models and other Earth system and hydrological models. The database can be accessed at https://doi.org/10.5287/ora-2nanwp4rk (Kaushal et al., 2024). #----------------------------------------- # Funding_Agency # Funding_Agency_Name: # Grant: #----------------------------------------- # Site_Information # Site_Name:Guillotine Cave # Location:New Zealand # Northernmost_Latitude:-42.3108 # Southernmost_Latitude:-42.3108 # Easternmost_Longitude:172.2178 # Westernmost_Longitude:172.2178 # Elevation_m:130 #----------------------------------------- # Data_Collection # Collection_Name: GT05-5 isotopes Whittaker2008 SISAL v3 # First_Year: 8869 # Last_Year: -55 # Time_Unit: Cal Yr BP # Core_Length_m: # Parameter_Keywords: oxygen isotopes, carbon isotopes # Notes: Contact: Drew Lorrey; Type: unknown; Dist. from entrance (m): NA; Entity Status: current; Depth Reference: from top; Overlying Bedrock Thickness (m): NA; Drip Type: unknown; Drip Height: NA; Drip Water Equilibrium Studies: unknown; Trace Elements Measured: ; Organics Measured: unknown; Fluid Inclusions Measured: unknown; Fabric Studies: unknown; Clumped Isotopes Measured: unknown; Noble Gases Measured: unknown; C14 Measured: unknown; ODL Measurements: unknown; Mg/Ca Measured: no; Type from WOKAM: NA; Vegetation Type: unknown; Land Use: forest; Copernicus lcc: closed forest, evergreen broad leaf; Cover Type: unknown; Host Rock Trace Elements: no; Drip Water Trace Elements: no; Isotope Standard: Vienna-PDB; d18O dripwater carbonate difference: NA; Trace Elements Datafile: no; Trace Elements Metadata File: NA; Cave Map: no; Entity Scan: no #----------------------------------------- # Chronology_Information # Chronology: Uranium-Thorium # Chronology_Download_Resource: https://www.ncei.noaa.gov/pub/data/paleo/templates/noaa-wds-paleo-uth-terms.csv # Chronology_Download_Description: Uranium-Thorium terms and definitions. # Chronology_Notes: Metadata and data from SISAL v3 database. # Rejection_Rationale: # 238U_Decay_Constant: unknown # 234U_Decay_Constant: unknown # 230Th_Decay_Constant: unknown # Initial_230Th/232Th: # Initial_230Th/232Th_Method: # Age_Model_Method: # Missing_Values: NA # Chronology_Table: # date_type depth_top_mm thick_mm samp_id material_dated weight_mg age_uncorr_BM age_uncorr_uncert_pos_yr age_uncorr_uncert_neg_yr date_used 238U_ppb 238U_uncert_ppb 232Th_ppt 232Th_uncert_ppb 230Th_ppt 230Th_uncert_ppb 230Th_232Th_act 230Th_232Th_act_uncert 230Th_238U_act 230Th_238U_act_uncert 234U_238U_act 234U_238U_act_uncert 230Th_232Th_act_init 230Th_232Th_act_init_uncert age_corr_BP1950 age_corr_uncert_pos_yr age_corr_uncert_neg_yr # U/Th unspecified 56 NA NA calcite NA 822 57 57 yes NA NA NA NA NA NA 7.1 NA 0.009 0.001 1.155 0.003 NA NA 598 182 182 # U/Th unspecified 168 NA NA calcite NA 6038 76 76 yes NA NA NA NA NA NA 7.7 NA 0.064 0.001 1.185 0.003 NA NA 4831 1167 1167 # U/Th unspecified 197 NA NA calcite NA 9752 127 127 yes 221 NA NA NA NA NA 17.6 NA 0.103 0.001 1.195 0.002 NA NA 9221 371 371 # Event; actively forming 0 NA NA NA NA NA NA NA yes NA NA NA NA NA NA NA NA NA NA NA NA NA NA -56 0 0 #----------------------------------------- # Variables # PaST_Thesaurus_Download_Resource: https://www.ncei.noaa.gov/access/paleo-search/skos/past-thesaurus.rdf # PaST_Thesaurus_Download_Description: Paleoenvironmental Standard Terms (PaST) Thesaurus terms, definitions, and relationships in SKOS format. # ## depth_sample depth,,,millimeter,,speleothems,,,N, ## interp_age age,,,calendar year before present,,speleothems,,,N, ## interp_age_uncert_pos age,,two standard deviations upper bound,calendar year,,speleothems,,,N, ## interp_age_uncert_neg age,,two standard deviations lower bound,calendar year,,speleothems,,,N, ## d18O_measurement delta 18O,calcite,,per mil VPDB,,speleothems,,,N,measurement precision is 0.09 per mil ## d13C_measurement delta 13C,calcite,,per mil VPDB,,speleothems,,,N,measurement precision is 0.05 per mil #----------------------------------------- # Data: # Missing_Values: NA depth_sample interp_age interp_age_uncert_pos interp_age_uncert_neg d18O_measurement d13C_measurement 0.1 -55.6735 0.5687 0.3243 -4.7 -9.07 1 -52.5455 5.6065 3.2311 -5.88 -8.81 2.1 -48.2649 11.5813 6.7562 -5.06 -8.89 3 -44.3939 16.2076 9.6186 -5.48 -9.95 4.1 -39.2196 21.5957 13.0914 -5.01 -8.88 5 -34.629 25.8156 15.9135 -5.16 -9.93 6.1 -28.5895 30.7856 19.3588 -5.01 -9.33 7 -23.3028 34.9429 22.1506 -5.52 -10.08 8.1 -16.4266 39.8255 25.544 -5.04 -8.11 9 -10.4671 43.3485 28.3058 -4.84 -9.26 10.1 -2.7829 47.6545 31.6649 -5.1 -6.77 11 3.8261 51.0915 34.4009 -5.62 -6.87 12.1 12.2897 55.4985 37.7775 -4.89 -7.47 13 19.5248 59.0265 40.4956 -5.08 -7.88 14.1 28.7393 63.1303 43.8055 -5.09 -9.21 15 36.577 66.5124 46.5049 -5.84 -8.28 16.1 46.514 70.4838 49.7945 -5.68 -7.95 17 54.931 73.4895 52.4789 -5.22 -8.31 18.1 65.5617 77.1858 55.7524 -4.91 -8.58 19 74.5346 80.004 58.4256 -5.24 -7.51 20.1 85.8305 83.5798 61.6877 -5.33 -9.5 21 95.3361 86.1968 64.3535 -5.42 -8.77 22.1 107.2686 89.6322 67.6087 -5.6 -8.9 23 117.2833 92.2743 70.2706 -5.64 -7.1 24.1 129.8238 95.3707 73.5234 -5.7 -7.91 25 140.3244 98.0425 76.1853 -5.17 -8.92 26.1 153.4444 100.3753 79.4667 -5.37 -9.94 27 164.4074 102.674 82.1739 -5.82 -7.54 28.1 178.0784 106.226 85.5855 -5.41 -7.98 29 189.4804 108.915 88.529 -5.33 -9.22 30.1 203.6737 111.6317 92.1542 -5.19 -9.55 31 215.4914 113.9433 95.0894 -5.47 -8.53 32.1 230.1785 116.7448 98.5029 -5.11 -6.75 33 242.3885 119.0123 101.2719 -5.74 -9.82 34.1 257.5408 121.432 104.65 -5.2 -7.86 35 270.1198 123.6356 107.4239 -5.25 -7.41 36.1 285.7087 126.0411 110.8275 -5.26 -9.99 37 298.6333 128.4926 113.6242 -5.15 -9.34 38.1 314.6302 130.6424 117.2479 -5.74 -8.89 39 327.877 132.8761 120.2606 -5.62 -7.18 40.1 344.2535 135.0659 123.9739 -5.7 -9.86 42.1 374.5264 140.4424 130.5935 -5.13 -8.4 43 388.3474 142.8839 133.6377 -5.51 -7.91 44.1 405.3971 145.5573 137.3903 -5.24 -8.13 46.1 436.8137 150.7624 144.3182 -5.07 -6.65 47 451.1154 153.3244 147.4129 -5.39 -10.22 48.1 468.7242 155.1664 151.0846 -5.48 -7.84 50.1 501.0767 160.9988 157.8283 -4.99 -8.39 51 515.7656 163.8398 160.8929 -5.52 -8.42 52.1 533.8191 166.7924 164.6649 -5.16 -9 53 548.6666 169.2215 167.7735 -5.29 -8.67 54.1 566.8996 172.147 171.6011 -5.24 -9.22 55 581.8823 174.9664 174.7106 -5.71 -9.76 56.1 600.2671 178.1384 178.4586 -5.5 -7.87 57 615.4424 181.4408 181.3751 -5 -7.14 58.1 634.2355 185.2846 184.3844 -5.38 -7.24 59 649.8163 188.1229 187.047 -5.5 -6.31 60.1 669.1142 191.429 191.2175 -5.17 -6.74 61 685.1156 194.6402 194.1136 -5.05 -6.34 62.1 704.9368 198.4 197.9329 -4.92 -6.31 63 721.3738 200.0887 200.3878 -5.15 -6.95 64.1 741.7367 202.8809 204.1189 -5.09 -6.78 65 758.6244 204.9499 205.8529 -4.96 -6.46 66.1 779.5474 206.8091 209.5984 -4.91 -6.52 67 796.901 208.3472 211.1922 -5.56 -7.79 68.1 818.4025 211.0154 214.7014 -4.96 -6.68 69 836.2369 212.0916 216.8038 -5.55 -6.51 70.1 858.3353 214.4498 219.0212 -5.46 -6.97 71 876.6657 216.8331 222.6911 -5.07 -6.25 72.1 899.3795 216.4538 224.727 -5.24 -5.66 73 918.2209 217.5653 227.5424 -5.25 -5.73 74.1 941.5685 221.905 235.2292 -5.04 -5.36 75 960.936 224.694 239.8014 -4.87 -5.7 76.1 984.9358 231.2103 241.3724 -5.14 -7.1 77 1004.8445 235.2725 242.9199 -5.3 -7.1 78.1 1029.5149 238.3944 245.2339 -5.25 -7.5 79 1049.9798 239.2645 245.6559 -5.29 -7.56 80.1 1075.3394 243.5291 248.7622 -5.27 -7.7 82.1 1122.4426 251.5606 263.8332 -5.02 -7.5 83 1144.0652 256.185 270.8461 -5.63 -7.53 84.1 1170.8582 262.1355 274.5406 -5.46 -8.65 86.1 1220.6195 275.1598 283.2255 -5.82 -7.83 87 1243.4602 280.7352 286.0648 -5.46 -7.45 88.1 1271.7602 288.8588 289.465 -5.07 -6.68 90.1 1324.3137 302.9438 298.7723 -5.36 -8.13 91 1348.4326 310.9961 305.3177 -5.35 -7.11 92.1 1378.3135 318.845 310.9863 -5.24 -6.74 94.1 1433.793 334.5186 318.6622 -5.09 -6.43 95 1459.2505 345.831 324.8254 -5.59 -7.48 96.1 1490.7859 359.8089 330.686 -5.2 -6.75 97 1516.9353 369.4407 337.0829 -5.22 -6.44 98.1 1549.3256 381.0825 343.6136 -5.2 -6.28 99 1576.182 391.8396 351.0499 -5.59 -8.3 100.1 1609.4455 404.1103 359.3266 -5.35 -9.57 102.1 1671.1793 428.1531 372.0193 -5.25 -6.02 103 1699.4949 436.1577 376.7429 -5.6 -7.29 104.1 1734.5603 449.3597 387.6601 -5.56 -8.03 105 1763.6281 458.8334 396.8971 -5.53 -7.22 106.1 1799.6222 471.2936 409.1497 -5.23 -7.98 107 1829.4573 481.4955 417.6744 -5.66 -8.35 108.1 1866.3983 493.9986 427.6153 -5.45 -7.35 109 1897.0157 504.2515 437.0099 -5.46 -6.37 110.1 1934.9222 517.7096 452.0003 -5.32 -7.04 111 1966.3371 530.9977 461.6945 -5.63 -8.25 112.1 2005.2274 542.2743 473.2143 -5.17 -7.33 113 2037.4548 551.0922 483.2816 -5.03 -6.88 114.1 2077.3474 564.8888 490.827 -5.46 -7.55 115 2110.4023 575.5423 497.5824 -5.35 -7.46 116.1 2151.3156 591.036 506.9059 -5.26 -7.16 117 2185.2133 603.6437 519.1706 -5.13 -7.44 118.1 2227.1656 617.7163 530.2715 -5.17 -6.68 119 2261.921 626.6263 539.5134 -5.32 -5.92 120.1 2304.931 639.4554 549.7376 -5.25 -5.76 121 2340.5591 652.4743 555.7666 -5.1 -6.2 122.1 2384.645 666.1681 565.8781 -5.08 -6.15 123 2421.1611 676.5721 577.8804 -5.18 -6.13 124.1 2466.3414 689.2288 594.571 -5.08 -6.83 125 2503.7604 699.5308 608.3511 -5.48 -7.03 126.1 2550.0535 711.1032 623.5606 -6.38 -9.58 127 2588.3906 722.2295 632.6281 -5.36 -7.2 128.1 2635.8149 738.288 645.6441 -5.24 -7.32 129 2675.0851 752.5835 661.6454 -5.49 -7.96 130.1 2723.6591 770.032 674.8526 -5.56 -9.29 131 2763.8774 783.8599 686.3407 -5.19 -8.73 132.1 2813.6196 799.4157 701.1277 -5.77 -8.01 133 2854.8011 812.0399 713.3475 -5.54 -7.95 134.1 2905.7298 827.334 727.2657 -5.39 -7.31 135 2947.8896 842.1596 736.6386 -5.35 -7.46 136.1 3000.0232 860.8799 750.0297 -5.58 -6.93 137 3043.1765 873.851 763.8306 -5.23 -6.64 138.1 3096.5335 886.4274 780.7049 -5.69 -7.55 139 3140.6952 896.5097 793.965 -5.36 -6.86 140.1 3195.294 908.2978 810.8934 -5.37 -6.81 141 3240.4793 917.1304 824.2164 -5.11 -7.26 142.1 3296.3382 930.1025 840.8167 -5.57 -7.44 143 3342.5621 942.7914 851.3983 -5.48 -8.34 144.1 3399.6997 958.0812 864.3917 -5.7 -8.17 145 3446.9773 967.9213 875.1251 -5.48 -7.76 146.1 3505.412 979.0013 888.1049 -5.43 -8.91 147 3553.7584 987.8045 898.6837 -5.38 -7.91 148.1 3613.5085 998.3186 911.5593 -5.79 -8.59 149 3662.9387 1006.7141 922.0467 -4.81 -6.9 150.1 3724.0228 1016.7148 935.4699 -5.54 -7.42 151 3774.5519 1024.6782 946.4168 -5.84 -8.2 152.1 3836.9883 1034.1356 959.7259 -5.45 -7.82 154.1 3952.4386 1052.6631 983.7098 -5.66 -7.81 155 4005.2107 1061.1847 994.4058 -5.28 -6.32 156.1 4070.4071 1071.3169 1007.3921 -4.96 -6.82 157 4124.3234 1079.3693 1018.2328 -5.66 -8.69 158.1 4190.9273 1088.9129 1033.4784 -5.57 -8.22 159 4246.0029 1096.4711 1045.8559 -5.94 -8.43 160.1 4314.0328 1104.6041 1059.8849 -5.62 -7.99 161 4370.2827 1110.2893 1071.0875 -5.19 -7.84 162.1 4439.7571 1116.9013 1084.8616 -5.25 -7.6 163 4497.1963 1122.3064 1096.3062 -5.35 -7.49 164.1 4568.1335 1129.9283 1110.1614 -5.1 -7.36 165 4626.7772 1134.4006 1121.3853 -5.31 -7.05 166.1 4699.1958 1139.4764 1134.9611 -5.03 -6.28 167 4759.0589 1143.3037 1145.2773 -5.24 -6.57 168.1 4833.0237 1147.5477 1157.0002 -5.39 -5.86 169 4898.653 1147.9856 1164.859 -4.9 -5.95 170.1 4989.3468 1142.2781 1169.0835 -5.07 -5.52 171 5071.7489 1132.7336 1168.158 -5.12 -6.22 172.1 5181.9898 1117.7099 1161.9519 -5.21 -5.33 173 5279.6053 1101.9308 1152.7152 -5.15 -5.96 174.1 5407.4876 1081.8893 1133.7065 -5.09 -5.95 175 5518.7572 1062.7032 1114.2408 -4.92 -5.84 176.1 5662.375 1025.3698 1085.9813 -4.97 -5.93 177 5785.7394 993.395 1059.4447 -5.08 -5.83 178.1 5943.1869 953.4878 1023.1513 -5.02 -5.34 179 6077.087 925.7211 986.3651 -5.16 -6.02 180.1 6246.4583 886.8392 940.7321 -5.09 -5.69 181 6389.3346 848.1976 897.5209 -5.1 -5.5 182.1 6568.7241 797.4967 847.5438 -4.94 -5.48 183 6719.0174 756.0236 806.7815 -5.14 -5.08 184.1 6906.5192 706.6677 755.8022 -4.96 -4.51 185 7062.6701 665.5743 709.1239 -5.14 -5.1 186.1 7256.3784 615.0717 648.1111 -4.93 -4.83 187 7416.8278 567.8342 602.3233 -5 -5.46 188.1 7614.8367 523.4211 561.0224 -4.74 -5.25 189 7778.0252 482.8914 512.6477 -5.02 -5.54 190.1 7978.429 447.3599 459.8965 -4.57 -4.71 191 8142.7973 417.3664 424.513 -4.81 -4.61 192.1 8343.6903 390.0973 381.9592 -4.77 -4.95 193 8507.6791 357.8908 353.2046 -5.22 -5.45 194.1 8707.1553 341.4532 331.6874 -5.2 -5.99 195 8869.2053 333.1593 328.7723 -5.23 -6.03