# Guillotine Cave, Ruakuri Cave Geochemical Data from 76200 to -55 Cal Yr BP #---------------------------------------------------------------------------------------- # World Data Service for Paleoclimatology, Boulder # and # NOAA Paleoclimatology Program #---------------------------------------------------------------------------------------- # Template Version 4.0 # Encoding: UTF-8 # NOTE: Please cite original publication, NOAA Landing Page URL, dataset and publication DOIs (where available), and date accessed when using downloaded data. # If there is no publication information, please cite Investigator, Title, NOAA Landing Page URL, and date accessed. # # Description/Documentation lines begin with # # Data lines have no # # # NOAA_Landing_Page: https://www.ncei.noaa.gov/access/paleo-search/study/40887 # Landing_Page_Description: NOAA Landing Page of this data file's parent study, which includes all study metadata. # # Study_Level_JSON_Metadata: https://www.ncei.noaa.gov/pub/data/metadata/published/paleo/json/noaa-cave-40887.json # Study_Level_JSON_Description: JSON metadata of this data file's parent study, which includes all study metadata. # # Data_Type: Speleothems # # Dataset_DOI: # # Science_Keywords: #----------------------------------------- # Resource_Links # # Data_Download_Resource: https://www.ncei.noaa.gov/pub/data/paleo/speleothem/SISAL-v3/noaa_templates/Whittaker2008-RK05-3.txt # Data_Download_Description: NOAA Template File; RK05-3 Speleothem Geochemical Data # # Related_Online_Resource: https://www.ncei.noaa.gov/access/paleo-search/study/39799 # Related_Online_Description: URL; SISAL v3 Database Landing Page # #----------------------------------------- # Contribution_Date # Date: 2024-09-02 #----------------------------------------- # File_Last_Modified_Date # Date: 2024-12-21 #----------------------------------------- # Title # Study_Name: Guillotine Cave, Ruakuri Cave Geochemical Data from 76200 to -55 Cal Yr BP #----------------------------------------- # Investigators # Investigators: Whittaker, T. E. #----------------------------------------- # Description_Notes_and_Keywords # Description: Data contributed as part of SISAL v3 Global Speleothem Isotope and Trace Element Database (https://doi.org/10.25921/jajq-qg60). Notes from the SISAL database: Vegetation and land use: Evergreen but mostly cleared over the last 100 years. \\ Entity RK05-1, RK05-3 and RK05-4 (SISAL entity_id = 676, 677, 678): Year when the U/Th chemistry was performed assumed to be 2006 based on dates of thesis publication and field work (would not be earlier than 2005). Entity RK-C, RK-A, RK-B, RK05-1, RK05-3 and RK05-4 (entity_id = 360, 674, 675, 676, 677, 678): Age model in original study was linear interpolation between TIMS ages; this update is based on COPRA (Breitenbach et al., 2012) using a PCH spline. #----------------------------------------- # Publication # Authors: Whittaker, T. E. # Published_Date_or_Year: 2008 # Published_Title: High-resolution speleothem-based palaeoclimate records from New Zealand reveal robust teleconnection to North Atlantic during MIS 1-4 # Journal_Name: High-resolution speleothem-based palaeoclimate records from New Zealand reveal robust teleconnection to North Atlantic during MIS 1-4 # Volume: Ph.D. # Edition: # Issue: thesis # Pages: The University of Waikato. # Report_Number: # DOI: # Online_Resource: # Full_Citation: Whittaker, T. E.: High-resolution speleothem-based palaeoclimate records from New Zealand reveal robust teleconnection to North Atlantic during MIS 1-4, Ph.D. thesis, The University of Waikato., 2008. # Abstract: #----------------------------------------- # Publication # Authors: Kaushal, Nikita, Franziska A. Lechleitner, Micah Wilhelm, Khalil Azennoud, Janica C. Bühler, Kerstin Braun, Yassine Ait Brahim, Andy Baker, Yuval Burstyn, Laia Comas-Bru, Jens Fohlmeister, Yonaton Goldsmith, Sandy P. Harrison, István G. Hatvani, Kira Rehfeld, Magdalena Ritzau, Vanessa Skiba, Heather M. Stoll, József G. Szucs, Péter Tanos, Pauline C. Treble, Vitor Azevedo, Jonathan L. Baker, Andrea Borsato, Sakonvan Chawchai, Andrea Columbu, Laura Endres, Jun Hu, Zoltán Kern, Alena Kimbrough, Koray Koç, Monika Markowska, Belen Martrat, Syed Masood Ahmad, Carole Nehme, Valdir Felipe Novello, Carlos Pérez-Mejías, Jiaoyang Ruan, Natasha Sekhon, Nitesh Sinha, Carol V. Tadros, Benjamin H. Tiger, Sophie Warken, Annabel Wolf, Haiwei Zhang, and SISAL Working Group members # Published_Date_or_Year: 2024 # Published_Title: SISALv3: a global speleothem stable isotope and trace element database # Journal_Name: Earth System Science Data # Volume: 16 # Edition: # Issue: # Pages: 1933-1963 # Report_Number: # DOI: 10.5194/essd-16-1933-2024 # Online_Resource: # Full_Citation: # Abstract: Palaeoclimate information on multiple climate variables at different spatiotemporal scales is becoming increasingly important to understand environmental and societal responses to climate change. A lack of high-quality reconstructions of past hydroclimate has recently been identified as a critical research gap. Speleothems, with their precise chronologies, widespread distribution, and ability to record changes in local to regional hydroclimate variability, are an ideal source of such information. Here, we present a new version of the Speleothem Isotopes Synthesis and AnaLysis database (SISALv3), which has been expanded to include trace element ratios and Sr isotopes as additional, hydroclimate-sensitive geochemical proxies. The oxygen and carbon isotope data included in previous versions of the database have been substantially expanded. SISALv3 contains speleothem data from 365 sites from across the globe, including 95 , 85 , 52 , 25 , 29 , and 14 Sr-isotope records. The database also has increased spatiotemporal coverage for stable oxygen (892) and carbon (620) isotope records compared with SISALv2 (which consists of 673 and 430 stable oxygen and carbon records, respectively). Additional meta information has been added to improve the machine-readability and filtering of data. Standardized chronologies are included for all new entities along with the originally published chronologies. Thus, the SISALv3 database constitutes a unique resource of speleothem palaeoclimate information that allows regional to global palaeoclimate analyses based on multiple geochemical proxies, permitting more robust interpretations of past hydroclimate and comparisons with isotope-enabled climate models and other Earth system and hydrological models. The database can be accessed at https://doi.org/10.5287/ora-2nanwp4rk (Kaushal et al., 2024). #----------------------------------------- # Funding_Agency # Funding_Agency_Name: # Grant: #----------------------------------------- # Site_Information # Site_Name:Ruakuri Cave # Location:New Zealand # Northernmost_Latitude:-38.27 # Southernmost_Latitude:-38.27 # Easternmost_Longitude:175.08 # Westernmost_Longitude:175.08 # Elevation_m:80 #----------------------------------------- # Data_Collection # Collection_Name: RK05-3 isotopes Whittaker2008 SISAL v3 # First_Year: 53624 # Last_Year: 6371 # Time_Unit: Cal Yr BP # Core_Length_m: # Parameter_Keywords: oxygen isotopes, carbon isotopes # Notes: Contact: Drew Lorrey; Type: unknown; Dist. from entrance (m): NA; Entity Status: current; Depth Reference: from top; Overlying Bedrock Thickness (m): NA; Drip Type: unknown; Drip Height: NA; Drip Water Equilibrium Studies: unknown; Trace Elements Measured: ; Organics Measured: unknown; Fluid Inclusions Measured: unknown; Fabric Studies: unknown; Clumped Isotopes Measured: unknown; Noble Gases Measured: unknown; C14 Measured: unknown; ODL Measurements: unknown; Mg/Ca Measured: no; Type from WOKAM: NA; Vegetation Type: sparse; Land Use: other (see notes); Copernicus lcc: NA; Cover Type: unknown; Host Rock Trace Elements: no; Drip Water Trace Elements: no; Isotope Standard: Vienna-PDB; d18O dripwater carbonate difference: NA; Trace Elements Datafile: no; Trace Elements Metadata File: NA; Cave Map: no; Entity Scan: no #----------------------------------------- # Chronology_Information # Chronology: Uranium-Thorium # Chronology_Download_Resource: https://www.ncei.noaa.gov/pub/data/paleo/templates/noaa-wds-paleo-uth-terms.csv # Chronology_Download_Description: Uranium-Thorium terms and definitions. # Chronology_Notes: Metadata and data from SISAL v3 database. # Rejection_Rationale: # 238U_Decay_Constant: unknown # 234U_Decay_Constant: unknown # 230Th_Decay_Constant: unknown # Initial_230Th/232Th: # Initial_230Th/232Th_Method: # Age_Model_Method: # Missing_Values: NA # Chronology_Table: # date_type depth_top_mm thick_mm samp_id material_dated weight_mg age_uncorr_BM age_uncorr_uncert_pos_yr age_uncorr_uncert_neg_yr date_used 238U_ppb 238U_uncert_ppb 232Th_ppt 232Th_uncert_ppb 230Th_ppt 230Th_uncert_ppb 230Th_232Th_act 230Th_232Th_act_uncert 230Th_238U_act 230Th_238U_act_uncert 234U_238U_act 234U_238U_act_uncert 230Th_232Th_act_init 230Th_232Th_act_init_uncert age_corr_BP1950 age_corr_uncert_pos_yr age_corr_uncert_neg_yr # U/Th unspecified 29 NA NA calcite NA NA NA NA yes NA NA NA NA NA NA NA NA NA NA NA NA NA NA 7172 279 279 # U/Th unspecified 353 NA NA calcite NA NA NA NA yes NA NA NA NA NA NA NA NA NA NA NA NA NA NA 19735 448 448 # U/Th unspecified 397 NA NA calcite NA NA NA NA yes NA NA NA NA NA NA NA NA NA NA NA NA NA NA 35512 370 370 # U/Th unspecified 551 NA NA calcite NA NA NA NA yes NA NA NA NA NA NA NA NA NA NA NA NA NA NA 52617 570 570 #----------------------------------------- # Variables # PaST_Thesaurus_Download_Resource: https://www.ncei.noaa.gov/access/paleo-search/skos/past-thesaurus.rdf # PaST_Thesaurus_Download_Description: Paleoenvironmental Standard Terms (PaST) Thesaurus terms, definitions, and relationships in SKOS format. # ## depth_sample depth,,,millimeter,,speleothems,,,N, ## interp_age age,,,calendar year before present,,speleothems,,,N, ## d18O_measurement delta 18O,calcite,,per mil VPDB,,speleothems,,,N,measurement precision is 0.09 per mil ## d13C_measurement delta 13C,calcite,,per mil VPDB,,speleothems,,,N,measurement precision is 0.05 per mil #----------------------------------------- # Data: # Missing_Values: NA depth_sample interp_age d18O_measurement d13C_measurement 0.1 6370.1974 -3.906 -8.568 1 6403.7509 -3.81 -9.09 2.1 6445.1831 -3.69 -9.21 3 6479.5365 -4.11 -8.92 4.1 6521.5239 -3.74 -8.4 5 6555.8773 -3.9 -8.09 6.1 6597.3254 -3.58 -8.31 7 6631.6567 -4.17 -8.72 8.1 6673.6172 -3.76 -8 9 6707.9485 -4.27 -7.78 10.1 6749.885 -3.667 -7.627 11 6783.9229 -3.68 -7.74 12.1 6825.5248 -3.522 -8.187 13 6858.9732 -3.487 -8.073 14.1 6900.3287 -3.602 -8.136 15 6934.7635 -3.69 -8.017 16.1 6976.6577 -3.406 -7 17 7010.3631 -3.519 -6.973 18.1 7051.5585 -3.74 -5.902 19 7085.2639 -3.509 -6.973 20.1 7126.906 -3.545 -6.086 21 7160.613 -3.593 -6.641 22.1 7202.6407 -3.562 -5.838 23 7236.508 -3.391 -6.578 24.1 7276.4456 -3.842 -6.654 25 7309.1219 -3.306 -4.811 26.1 7350.1822 -3.02 -5.431 27 7383.9901 -3.073 -6.883 28.1 7425.8239 -3.735 -8.784 29 7460.5006 -3.653 -8.897 30.1 7502.5137 -3.412 -8.718 31 7536.6887 -3.627 -7.172 32.1 7578.4582 -3.178 -6.052 33 7612.6332 -3.287 -6.244 34.1 7654.4026 -3.425 -6.372 35 7688.5777 -3.563 -5.689 36.1 7730.3974 -3.3 -5.379 37 7764.8813 -3.124 -5.87 38.1 7807.0283 -3.04 -5.715 39 7841.5122 -2.816 -6.015 40.1 7883.6592 -2.809 -5.602 41 7918.1431 -3.01 -6.098 42.1 7960.1216 -3.223 -5.891 43 7994.1275 -3.361 -5.797 44.1 8035.3882 -3.104 -5.991 45 8069.2418 -2.987 -6.442 46.1 8111.0397 -3.056 -6.721 47 8145.3986 -3.098 -6.827 48.1 8186.2535 -2.943 -6.18 49 8220.5523 -3.075 -6.361 50.1 8262.6206 -3.107 -6.468 51 8296.8565 -3.102 -6.82 52.1 8338.611 -3.162 -7.718 53 8372.4033 -3.124 -8.367 54.1 8413.7437 -3.197 -8.972 55 8447.9907 -3.27 -9.516 56.1 8489.8483 -3.338 -9.516 57 8524.0953 -3.306 -9.456 58.1 8565.9529 -3.427 -9.124 59 8600.835 -3.455 -8.544 60.1 8643.3031 -3.34 -8.369 61 8678.0498 -3.116 -8.09 62.1 8720.4069 -2.746 -8.014 63 8754.7245 -2.947 -7.611 64.1 8796.6253 -2.973 -7.302 65 8830.9602 -3.08 -7.415 66.1 8873.5756 -3.352 -7.89 67 8908.4428 -3.394 -7.597 68.1 8951.0117 -3.27 -7.801 69 8985.4312 -3.285 -7.73 70.1 9027.4996 -3.284 -8.648 71 9061.6909 -3.481 -9.094 72.1 9103.3252 -3.844 -9.518 74.1 9179.024 -2.775 -6.941 75 9212.9155 -2.672 -6.97 76.1 9254.3117 -2.553 -7.443 77 9288.1813 -2.539 -7.564 78.1 9329.5775 -2.7 -7.688 79 9363.5349 -2.882 -7.257 80.1 9405.7069 -2.687 -7.518 81 9440.2113 -2.904 -7.326 82.1 9482.3833 -2.609 -7.509 83 9516.8877 -2.62 -7.861 84.1 9559.769 -2.969 -7.358 85 9594.0873 -3.206 -7.947 86.1 9636.0833 -2.875 -8.31 87 9670.4924 -2.587 -8.199 88.1 9712.2177 -2.772 -8.064 89 9746.1449 -2.851 -8.015 90.1 9787.6115 -3.144 -7.252 91 9821.4135 -3.089 -7.435 93 9897.9097 -2.989 -7.471 94.1 9940.1237 -2.894 -8.055 95 9975.0486 -2.491 -8.399 96.1 10016.8395 -2.852 -8.331 97 10051.0321 -2.716 -8.574 98.1 10093.3732 -2.66 -9.026 99 10129.3054 -2.458 -9.265 101 10205.8532 -2.83 -9.293 102.1 10247.5845 -2.971 -9.226 103 10281.9575 -3.03 -8.828 104.1 10323.9689 -3.395 -7.641 105 10358.8171 -3.304 -7.911 106.1 10401.9651 -3.221 -7.56 107 10436.3129 -2.887 -6.135 108.1 10478.5995 -2.815 -6.578 109 10513.1003 -2.84 -9.022 110.1 10555.3845 -2.83 -6.601 111 10589.9536 -2.714 -6.664 112.1 10632.2048 -2.903 -6.566 113 10666.9156 -2.777 -6.328 114.1 10709.2043 -2.661 -6.771 115 10743.5944 -2.811 -6.901 116.1 10785.8456 -2.677 -6.944 117 10820.5342 -2.947 -7.343 118.1 10863.0388 -3.311 -7.577 119 10897.8152 -3.295 -8.248 120.1 10940.4419 -3.58 -8.269 121 10975.5441 -3.202 -6.28 122.1 11018.591 -2.903 -6.687 123 11054.1848 -2.892 -6.88 124.1 11098.0284 -2.898 -6.736 125 11133.552 -2.852 -6.147 126.1 11177.0574 -2.793 -5.386 127 11212.9048 -2.984 -6.6 128.1 11256.0843 -2.948 -7.594 129 11290.5009 -3.143 -9.31 130.1 11333.7565 -3.136 -9.349 131 11368.4841 -3.111 -9.979 132.1 11410.9289 -3.03 -9.93 133 11445.6565 -3.319 -9.023 134.1 11488.4236 -3.041 -8.344 135 11523.8774 -2.973 -8.589 136.1 11567.208 -3.025 -8.68 137 11602.4546 -3.115 -8.701 138.1 11645.5338 -3.113 -9.105 139 11680.7167 -3.558 -10.025 140.1 11723.9221 -3.572 -10.906 141 11758.4507 -3.499 -9.77 142.1 11801.0036 -3.353 -9.004 143 11836.1537 -3.256 -8.857 144.1 11879.8133 -3.361 -9.634 145 11915.4944 -3.511 -10.32 146.1 11957.7007 -3.6 -10.976 147 11992.2331 -3.618 -11.161 148.1 12035.1817 -3.389 -11.188 149 12070.4274 -3.175 -11.384 150.1 12113.5055 -3.331 -10.854 151 12148.7511 -3.243 -10.965 152.1 12191.8292 -3.319 -10.821 153 12227.086 -3.151 -10.665 154.1 12270.9455 -3.182 -10.616 155 12306.5632 -3.199 -9.809 156.1 12349.7596 -3.55 -8.536 157 12384.7185 -2.982 -9.232 158.1 12427.704 -3.064 -9.636 159 12462.7361 -3.351 -10.237 160.1 12504.9493 -3.538 -10.54 161 12539.6924 -3.465 -10.469 162.1 12582.194 -3.578 -10.46 163 12616.7643 -3.27 -10.184 164.1 12659.0169 -3.118 -10.219 165 12694.2644 -3.248 -10.172 166.1 12737.8904 -3.507 -10.2 167 12773.3465 -3.523 -10.425 168.1 12816.3833 -3.498 -10.748 169 12850.7592 -3.418 -10.759 170.1 12894.4221 -3.523 -10.584 171 12930.1684 -3.582 -10.553 172.1 12974.1549 -3.378 -10.794 173 13010.3581 -3.525 -11.107 174.1 13053.253 -3.905 -11.8 175 13088.3489 -3.055 -8.134 176.1 13131.2438 -3.066 -7.561 177 13166.6066 -3.191 -8.903 178.1 13210.3063 -3.127 -7.167 179 13245.5423 -3.136 -6.852 180.1 13288.5134 -3.139 -6.74 181 13324.0823 -3.025 -7.653 182.1 13367.5089 -3.004 -7.578 183 13402.8555 -3.122 -7.788 184.1 13446.0568 -2.868 -7.511 185 13481.4034 -2.987 -7.221 186.1 13524.6047 -2.973 -6.819 187 13559.5823 -3.243 -8.623 188.1 13602.7673 -3.178 -8.856 189 13637.7609 -3.117 -8.291 190.1 13681.5672 -3.13 -9.26 191 13717.9954 -3.094 -9.407 192.1 13761.5474 -3.038 -7.946 193 13797.017 -3.078 -8.549 194.1 13840.3687 -3.043 -8.666 195 13876.0878 -3.186 -8.483 196.1 13920.1925 -3.094 -8.946 197 13956.2781 -3.229 -9.062 198.1 14000.3614 -3.138 -9.297 199 14036.2619 -3.103 -8.484 200.1 14079.8897 -2.965 -8.673 201 14115.6774 -2.766 -9.06 202.1 14159.1745 -2.731 -9.441 203 14194.3271 -2.706 -9.458 204.1 14237.6171 -2.524 -9.209 205 14273.281 -2.644 -9.102 206.1 14316.3833 -2.963 -9.194 207 14351.6487 -2.844 -9.433 208.1 14394.751 -2.588 -9.44 209 14430.0164 -2.645 -9.589 210.1 14473.229 -2.742 -10.202 211 14508.7536 -2.652 -9.941 212.1 14552.0631 -2.773 -9.939 213 14587.4983 -2.549 -9.895 214.1 14631.0032 -2.968 -9.192 215 14667.4179 -2.895 -9.277 216.1 14711.5997 -3.168 -9.79 217 14747.5344 -3.067 -10.085 218.1 14791.4547 -3.05 -10.457 219 14827.3894 -3.174 -10.558 220.1 14871.3097 -3.028 -10.58 221 14906.9615 -2.931 -10.243 222.1 14950.8641 -3.185 -10.61 223 14986.4719 -3.089 -9.792 224.1 15029.8612 -2.649 -8.735 225 15065.9195 -2.743 -8.213 226.1 15109.9908 -3.072 -7.791 227 15146.0492 -3.13 -7.561 228.1 15189.909 -2.779 -7.855 229 15225.3212 -2.695 -8.04 230.1 15268.505 -3.076 -8.257 231 15303.8372 -3.145 -8.415 232.1 15347.0211 -2.896 -9.432 233 15382.3533 -2.975 -9.348 234.1 15425.5372 -3.195 -9.649 235 15460.8694 -2.757 -9.436 236.1 15504.0533 -2.979 -9.553 237 15539.311 -3.074 -8.824 238.1 15582.0959 -3.031 -9.284 239 15617.2023 -3.004 -9.291 240.1 15660.2559 -3.049 -8.996 241 15695.4815 -3.038 -9.267 242.1 15738.535 -3.067 -10.254 243 15773.7607 -3.076 -9.55 244.1 15816.8146 -2.866 -9.85 245 15852.3168 -3.271 -9.784 246.1 15895.7083 -3.308 -9.485 247 15931.5037 -3.054 -9.395 248.1 15975.9626 -2.849 -9.261 249 16012.3313 -3.018 -9.14 250.1 16056.5059 -2.498 -8.817 251 16092.1479 -2.592 -8.946 252.1 16135.7102 -3.143 -9.726 253 16171.3522 -3.145 -9.858 254.1 16214.9146 -2.876 -9.735 255 16250.5565 -3.084 -9.561 256.1 16294.5292 -3.524 -9.637 257 16331.0998 -3.241 -9.471 258.1 16375.1932 -3.252 -9.678 259 16411.2359 -3.639 -10.093 260.1 16455.2439 -3.471 -9.344 261 16491.7339 -3.387 -9.24 262.1 16536.0353 -3.427 -9.296 263 16571.8638 -2.584 -9.398 264.1 16615.6543 -2.864 -9.506 265 16651.5766 -3.092 -9.996 267 16732.0175 -3.231 -10.334 268.1 16776.2601 -3.07 -9.956 269 16812.4585 -3.02 -9.417 270.1 16856.7011 -2.826 -8.631 271 16892.8995 -2.656 -8.196 272.1 16937.1421 -2.997 -8.576 273 16973.3405 -2.822 -9.011 274.1 17017.5831 -2.704 -9.683 275 17053.6989 -2.681 -9.449 276.1 17097.5606 -2.513 -9.637 277 17133.4474 -2.63 -9.822 278.1 17177.3091 -2.775 -9.773 279 17213.196 -2.508 -9.81 280.1 17257.1524 -2.478 -9.869 281 17293.1526 -3.041 -9.759 282.1 17337.1387 -2.916 -10.028 283 17372.775 -3.08 -9.761 284.1 17416.5547 -2.578 -9.832 285 17452.4416 -2.536 -9.434 286.1 17496.3032 -2.769 -9.857 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