# Speleothem Stable Isotope Data of the last 200,000 Years from the Black Sea Region #----------------------------------------------------------------------- # World Data Service for Paleoclimatology, Boulder # and # NOAA Paleoclimatology Program #----------------------------------------------------------------------- # Template Version 4.0 # Encoding: UTF-8 # NOTE: Please cite original publication, NOAA Landing Page URL, dataset and publication DOIs (where available), and date accessed when using downloaded data. # If there is no publication information, please cite investigator, study title, NOAA Landing Page URL, and date accessed. # # Description/Documentation lines begin with '#' followed by a space # Data lines have no '#' # # NOAA_Landing_Page: https://www.ncei.noaa.gov/access/paleo-search/study/39063 # Landing_Page_Description: NOAA Landing Page of this file's parent study, which includes all study metadata. # # Study_Level_JSON_Metadata: https://www.ncei.noaa.gov/pub/data/metadata/published/paleo/json/noaa-cave-39063.json # Study_Level_JSON_Description: JSON metadata of this data file's parent study, which includes all study metadata. # # Data_Type: Speleothems # # Dataset_DOI: 10.25921/b84y-cm81 # # Science_Keywords: Dansgaard-Oeschger cycles, Glacial, Interglacial, Heinrich Events, abrupt climate change, centennial resolution #--------------------------------------- # Resource_Links # # Data_Download_Resource: https://www.ncei.noaa.gov/pub/data/paleo/speleothem/asia/turkey/held2024/held2024-so-2.txt # Data_Download_Description: NOAA Template File; So-2 d13C, d18O Data # #--------------------------------------- # Contribution_Date # Date: 2024-02-22 #--------------------------------------- # File_Last_Modified_Date # Date: 2025-02-05 #--------------------------------------- # Title # Study_Name: Speleothem Stable Isotope Data of the last 200,000 Years from the Black Sea Region #--------------------------------------- # Investigators # Investigators: Held, Frederick (https://orcid.org/0009-0009-5101-9987) #--------------------------------------- # Description_Notes_and_Keywords # Description: #--------------------------------------- # Publication # Authors: Held, F., Cheng, H., Edwards, R.L., Tüysüz, O., Koç, K., Fleitmann, D. # Published_Date_or_Year: 2024 # Published_Title: Dansgaard-Oeschger cycles of the penultimate and last glacial period recorded in stalagmites from Türkiye # Journal_Name: Nature Communications # Volume: 15 # Edition: # Issue: # Pages: # Report_Number: 1183 # DOI: 10.1038/s41467-024-45507-5 # Online_Resource: # Full_Citation: # Abstract: The last glacial period is characterized by abrupt climate oscillations, also known as Dansgaard-Oeschger (D-O) cycles. However, D-O cycles remain poorly documented in climate proxy records covering the penultimate glacial period. Here we present highly resolved and precisely dated speleothem time series from Sofular Cave in northern Türkiye to provide clear evidence for D-O cycles during Marine Isotope Stage (MIS) 6 as well as MIS 2-4. D-O cycles are most clearly expressed in the Sofular carbon isotope time series, which correlate inversely with regional sea surface temperature (SST) records from the Black Sea. The pacing of D-O cycles is almost twice as long during MIS 6 compared to MIS 2-4, and could be related to a weaker Atlantic Meridional Overturning Circulation (AMOC) and a different mean climate during MIS 6 compared to MIS 2-4, leading most likely to a higher threshold for the occurrence of D-O cycles. #--------------------------------------- # Funding_Agency # Funding_Agency_Name: Swiss National Science Foundation # Grant: PP002-110554/1 #--------------------------------------- # Funding_Agency # Funding_Agency_Name: US National Science Foundation # Grant: NSF 2202913 #--------------------------------------- # Funding_Agency # Funding_Agency_Name: National Natural Science Foundation of China # Grant: NSFC 41888101 and NSFC 42150710534 #--------------------------------------- # Funding_Agency # Funding_Agency_Name: Istanbul Technical University # Grant: ITU-BAP-332491 #--------------------------------------- # Funding_Agency # Funding_Agency_Name: Gary Comer Science and Education Foundation # Grant: CP41 #--------------------------------------- # Site_Information # Site_Name: Sofular Cave # Location: Turkey # Northernmost_Latitude: 41.427778 # Southernmost_Latitude: 41.427778 # Easternmost_Longitude: 31.950139 # Westernmost_Longitude: 31.950139 # Elevation_m: 410 #--------------------------------------- # Data_Collection # Collection_Name: So-2 d13C, d18O Held2024 # First_Year: 59390 # Last_Year: 2690 # Time_Unit: calendar year before present # Core_Length_m: # Parameter_Keywords: carbon isotopes, oxygen isotopes, age control, geochemistry # Notes: #--------------------------------------- # Chronology_Information # Chronology: Uranium-Thorium # Chronology_Download_Resource: https://www.ncei.noaa.gov/pub/data/paleo/templates/noaa-wds-paleo-uth-terms.csv # Chronology_Download_Description: Uranium-Thorium terms and definitions. # Chronology_Notes: U-series dating (230Th) was performed on a multi-collector inductively coupled plasma mass spectrometer (MC-ICP-MS, Thermo-Finnigan-Neptune) at the Department of Geology and Geophysics, University of Minnesota and Institute of Global Environmental Change, Xi’an Jiaotong University. Further 230Th dating on stalagmites So-1 and So-2 was done on a Nu Instruments® MC-ICP-MS at the Geological Institute, University of Bern. # Rejection_Rationale: # 238U_Decay_Constant: # 234U_Decay_Constant: # 230Th_Decay_Constant: # Initial_230Th/232Th: # Initial_230Th/232Th_Method: # Age_Model_Method: # Missing_Values: na # Chronology_Table: # samp_id depth_top_mm 238U_ppb 238U_2s_ppb 232Th_ppt 232Th_2s_ppt Th_ppb Th_uncert_ppb U_ppb U_uncert_ppb 230Th_232Th_atom_ppm 230Th_232Th_atom_2s_ppm d234U_meas_permil d234U_meas_2s_permil 230Th_238U_act 230Th_238U_act_2s 234U_238U_act 234U_238U_act_2s 230Th_232Th_act 230Th_232Th_act_2s 230Th_234U_act 230Th_234U_act_2s age_uncorr_kaBM age_uncorr_2s_ka age_corr_kaBP1950 age_corr_2s_ka notes date_type # So-2-5 60 1.19170512973761 4.74673034495259E-03 383.624182153428 0.538001633640355 1.86830909268937 2.45152585030675E-03 55.1987743021719 0.680491143403596 3.04024632901398E-02 3.59473623965731E-04 3.159 0.092 "Nu Instruments® (Bern)" MC-ICP-MS # So-2-6 107 1.56448910783189 6.46386508950934E-03 377.609351915234 0.524397998736161 2.14658430989204 2.2511891799441E-03 69.7631808504699 0.486735173126021 4.46004567357834E-02 2.62484954768917E-04 4.73 0.083 "Nu Instruments® (Bern)" MC-ICP-MS # So-2-3 318 0.349501752813778 2.6327279570407E-03 244.282244417781 0.33219297348687 2.02129993506169 2.71176288733432E-03 291.016213312311 3.83337129238808 6.81487804751877E-02 7.47828955985516E-04 7.507 0.183 "Nu Instruments® (Bern)" MC-ICP-MS # So-2-1 390 5.42376763453447 3.59907100693825E-02 336.961080137923 0.503430942474782 2.42134641643103 1.98495691626083E-03 45.8040135521745 0.42468390491258 0.100868401894408 6.75416885720427E-04 10.928 0.275 "Nu Instruments® (Bern)" MC-ICP-MS # So-2-2 480 0.734700583820939 2.4497073234099E-03 361.42750077568 0.556453005922411 2.60415227695826 2.71951823649756E-03 517.574111360281 3.17207214849578 0.133499868540241 7.30047157347303E-04 15.257 0.184 "Nu Instruments® (Bern)" MC-ICP-MS # So-2-12 534 0.604437317487337 3.97964965772348E-03 431.623376741142 0.676882781413919 2.4318401157128 4.56293437980451E-03 882.23982165538 7.05194736764041 0.167545874346996 8.62851406564886E-04 19.518 0.225 "Nu Instruments® (Bern)" MC-ICP-MS # Hiatus 549 Hiatus # So-2-13 626 1.08341588384007 3.69518719042617E-03 364.165851370684 0.538719210048763 2.05565789374234 2.5876395542317E-03 608.882974946889 3.10305705656501 0.291039233833329 1.23863038711919E-03 36.236 0.373 "Nu Instruments® (Bern)" MC-ICP-MS # So-2-14 684 0.535789702879441 3.10153093663032E-03 866.217664565897 1.50801333532495 2.59622121837117 3.94540096980022E-03 3850.47253742621 26.4563414983754 0.29779709837535 1.29945919786414E-03 37.071 0.387 "Nu Instruments® (Bern)" MC-ICP-MS # So-2-4 717 0.408574224953117 3.37614322727911E-03 543.568470037853 0.752444676342592 2.39947716092942 1.82897563747867E-03 3006.56316913378 28.5608930370681 0.307106638725462 1.51876614190071E-03 38.48 0.462 "Nu Instruments® (Bern)" MC-ICP-MS # So-2-15 764 0.353435448852601 2.65514703953855E-03 476.726932730884 0.820445892291343 2.62018228401595 4.18916465946993E-03 3502.1720583529 30.3249750047554 0.322274536735456 1.5807412302183E-03 40.618 0.479 "Nu Instruments® (Bern)" MC-ICP-MS # So-2-16 815 2.1257178708675 0.123027177163341 796.153768954874 1.22568838521435 2.75993175403615 2.22895862628587E-03 1057.47004464798 61.5080741220594 0.33705943031515 2.04030312861961E-03 42.702 0.618 "Nu Instruments® (Bern)" MC-ICP-MS # So-2-17 854 0.799494240672674 1.16261821758419E-02 751.068164080778 1.26374641677483 2.7193987754204 2.87465865558203E-03 2691.78882664205 42.1304082860643 0.344150129867562 2.10605032919492E-03 43.824 0.641 "Nu Instruments® (Bern)" MC-ICP-MS # So-2-18 906 1.4542181237175 0.109798981056827 390.358092547869 0.574818595592814 2.54919698631523 3.05267724829265E-03 733.962482649757 55.5569387984194 0.354011941750109 2.01633112936288E-03 45.33 0.626 "Nu Instruments® (Bern)" MC-ICP-MS # So2-M1 914 443.436308842259 0.511942468146147 1279.36406901803 25.6519069791555 5251.0277229561 105.514605217979 1579.64535729457 2.54813134262341 0.918843487527881 1.61304507952783E-03 45.8098074800138 0.110431634999315 45.7197435269699 0.112398424242218 "Thermo-Finnigan-Neptune (Minnesota; Xi'an)" MC-ICP-MS # So2-M2 945 837.455194108449 1.04425503063239 240.847828964387 4.91315993000669 54046.6202056506 1103.89120658494 1578.95873998879 2.76386095944659 0.942722836421663 1.51717746686622E-03 47.2493680015043 0.110140496990306 47.1863324115704 0.110155775842618 "Thermo-Finnigan-Neptune (Minnesota; Xi'an)" MC-ICP-MS # So2-M3 967 640.998176586986 1.02260624885397 188.831788269779 3.87784975858655 51998.8570019972 1072.10789778391 1513.98941524755 3.78300843142117 0.929065730184733 2.25971832660538E-03 47.9079693070358 0.165653998985749 47.8447808038671 0.165661947943434 "Thermo-Finnigan-Neptune (Minnesota; Xi'an)" MC-ICP-MS # So2-M4 997 459.059441484422 0.575673755783971 439.610183921425 8.85017409243316 14618.2917064707 294.703179262513 1265.50487623765 3.09617816384419 0.849043176724015 1.39551050271973E-03 48.886395093564 0.127811446242519 48.8149792700711 0.128036917064968 "Thermo-Finnigan-Neptune (Minnesota; Xi'an)" MC-ICP-MS # So2-M5 1015 403.45330877768 0.547587424881725 823.824365538997 16.5239661993419 6841.96499165267 138.136101318965 1238.20444909467 3.51636866578894 0.847337701302447 2.26583686430524E-03 49.5094998695613 0.187570101428419 49.424927846948 0.188302740816621 "Thermo-Finnigan-Neptune (Minnesota; Xi'an)" MC-ICP-MS # So2-M8 1177 847.713591860748 1.23984653888988 705.622478736932 14.1649223644047 23899.3010085765 480.458301023463 1938.39167177042 3.66888033345499 1.20654296485402 2.19425580077969E-03 54.1825306598917 0.147520439178516 54.1150371656063 0.147595698729972 "Thermo-Finnigan-Neptune (Minnesota; Xi'an)" MC-ICP-MS # So2-M9 1226 882.972371318344 2.80249694305239 530.308335789177 10.6610568377986 32000.3993781286 644.437818629105 1804.58573825002 7.01737064029332 1.1656577871541 3.94925237507435E-03 55.073319550623 0.288017577481982 55.0076348901931 0.28801640173854 "Thermo-Finnigan-Neptune (Minnesota; Xi'an)" MC-ICP-MS # So2-M10 1249 1109.57301325217 1.80124080223332 421.784091150215 8.51118739975021 52924.7590715984 1069.57691352065 1909.82220433747 3.81971428292282 1.22019019488434 2.39785269401356E-03 55.6157225251941 0.163149729969521 55.5522405017273 0.163159505780923 "Thermo-Finnigan-Neptune (Minnesota; Xi'an)" MC-ICP-MS # So2-M11 1279 888.080082833038 1.47476906631486 402.397392740221 8.10649085375618 45756.6625158564 923.599900980049 1984.80583262633 4.08810940071946 1.257452819695 2.62340859442616E-03 55.891573267305 0.173150364712966 55.8275441180889 0.173163011551446 "Thermo-Finnigan-Neptune (Minnesota; Xi'an)" MC-ICP-MS # So2-M12 1333 982.183098508879 1.48175169537757 786.503077927219 15.7796151943126 25196.5832734357 506.172137225064 1885.90654711919 3.61261635642396 1.22372534466026 2.22850684845394E-03 56.4001922418411 0.15528708879808 56.3328725862462 0.155352871703245 "Thermo-Finnigan-Neptune (Minnesota; Xi'an)" MC-ICP-MS # So2-M13 1364 1052.66254012672 1.19876354445935 342.618753426002 6.91440584649972 60294.3984459346 1218.55305890664 1787.16225532808 2.55384696169304 1.19023648898911 1.8699684957835E-03 56.9591410404904 0.129301808019534 56.8960207462751 0.129314601201825 "Thermo-Finnigan-Neptune (Minnesota; Xi'an)" MC-ICP-MS # So2-M14 1421 785.531611657457 1.36540078761545 499.088123033807 10.0298423708014 30421.8548322816 612.252220333124 1700.70364322946 3.93601908627977 1.17228602932862 2.39972294533272E-03 58.1881317734981 0.184037637556829 58.1219117855778 0.184070789485639 "Thermo-Finnigan-Neptune (Minnesota; Xi'an)" MC-ICP-MS # So2-M15 1473 981.733751467862 1.59162088574468 391.890526339937 7.90347053392289 46110.8402102188 931.683065054671 1533.77260724187 2.67553536145594 1.11637065003715 2.27481544114936E-03 59.4229348868106 0.172339379216869 59.358739120912 0.17235457697969 "Thermo-Finnigan-Neptune (Minnesota; Xi'an)" MC-ICP-MS #--------------------------------------- # Variables # PaST_Thesaurus_Download_Resource: https://www.ncei.noaa.gov/access/paleo-search/skos/past-thesaurus.rdf # PaST_Thesaurus_Download_Description: Paleoenvironmental Standard Terms (PaST) Thesaurus terms, definitions, and relationships in SKOS format. # # Data variables follow that are preceded by "##" in columns one and two. # Variables list, one per line, shortname-tab-var components: what, material, error, units, seasonality, data type, detail, method, C or N for Character or Numeric data) # ## depth_mm depth,,,millimeter,,speleothems,,,N, ## age_kaBP age,,,calendar kiloyear before present,,speleothems,,Monte Carlo simulation,N,StalAge Model by Scholz and Hoffmann (2011) ## d13C delta 13C,calcite,,per mil PDB,,speleothems,,isotope ratio mass spectrometry,N, ## d18O delta 18O,calcite,,per mil PDB,,speleothems,,isotope ratio mass spectrometry,N, #------------------------ # Data: # Data lines follow (have no #) # Data line format - tab-delimited text, variable short name as header # Missing_Values: NA depth_mm age_kaBP d13C d18O 2 2.692252 -8.62 -7.34 4 2.722654 -8.81 -7.67 6 2.753415 -9.21 -7.67 8 2.784157 -9.36 -8.09 10 2.812196 -9.45 -8.15 12 2.841331 -9.37 -7.78 14 2.872849 -9.7 -7.92 16 2.904367 -8.97 -7.81 18 2.935885 -9.59 -7.72 20 2.967403 -9.92 -7.98 22 2.992223 -10.01 -7.98 24 3.022419 -9.61 -7.87 26 3.052615 -9.54 -7.85 28 3.082867 -9.4 -7.77 30 3.113766 -10.1 -7.67 32 3.150976 -9.65 -7.8 34 3.181557 -10.02 -7.96 36 3.212139 -9.81 -7.78 38 3.24272 -9.73 -7.89 40 3.273302 -9.7 -7.81 42 3.303883 -10.23 -8.07 44 3.334465 -10.45 -7.95 46 3.360961 -10.25 -7.8 48 3.395628 -10.99 -7.99 50 3.42621 -9.7 -7.48 52 3.456791 -10.46 -7.84 54 3.487373 -10.48 -7.72 56 3.517954 -9.72 -7.59 58 3.548536 -10.03 -7.58 60 3.579117 -10.25 -7.72 62 3.609699 -10.38 -7.47 64 3.640281 -10.25 -7.65 66 3.670862 -10.64 -7.84 68 3.701444 -10.68 -7.75 70 3.732025 -10.37 -7.56 72 3.7627 -10.71 -7.62 74 3.793917 -10.87 -8.05 76 3.825134 -10.06 -7.48 78 3.856351 -9.86 -7.55 80 3.887569 -10.34 -7.56 82 3.917862 -10.04 -7.78 84 3.947746 -10.15 -7.51 86 3.977629 -10.78 -7.8 88 4.007513 -10.78 -7.77 90 4.037841 -10.94 -7.96 92 4.068422 -10.68 -7.56 94 4.099004 -10.01 -7.35 96 4.129585 -9.78 -7.44 98 4.15136 -10.57 -7.92 100 4.166651 -10.12 -7.62 102 4.181942 -9.92 -7.78 104 4.197232 -10 -7.69 106 4.212523 -10.02 -7.75 108 4.227814 -10.27 -7.8 110 4.243013 -10.18 -7.71 112 4.257889 -10.57 -7.88 114 4.272765 -10.05 -7.84 116 4.287641 -10.31 -8.03 118 4.302518 -10.15 -8.12 120 4.317394 -10.05 -7.71 122 4.33227 -9.99 -7.86 124 4.347146 -10.25 -7.79 126 4.362023 -10.33 -7.88 128 4.376899 -10.19 -8 130 4.391775 -9.85 -7.62 132 4.406651 -9.91 -8.1 134 4.421527 -10.35 -7.99 136 4.436404 -10.14 -7.97 138 4.45128 -10.2 -7.9 140 4.466156 -10 -7.64 142 4.481261 -10.09 -7.68 144 4.496478 -9.86 -7.92 146 4.511383 -10.07 -7.87 148 4.526288 -9.85 -7.87 150 4.541193 -10.03 -8.26 152 4.556098 -10.49 -8.08 154 4.571002 -10.63 -8.55 156 4.585907 -10.17 -8.67 158 4.600812 -10.34 -8.25 160 4.615717 -10.71 -8.36 162 4.630622 -10.53 -8.06 164 4.645526 -10.14 -8.04 166 4.660431 -9.84 -7.72 168 4.675336 -9.71 -7.89 170 4.690547 -10.12 -7.9 172 4.706797 -9.52 -7.94 174 4.723046 -9.29 -7.58 176 4.739296 -9.68 -7.91 178 4.755546 -9.93 -7.98 180 4.771795 -9.54 -8.29 182 4.788045 -9.79 -8.11 184 4.802903 -10.26 -7.98 186 4.817564 -10.2 -8.52 188 4.832493 -10.07 -7.98 190 4.848448 -10 -8.05 192 4.863537 -10.11 -8.03 194 4.878626 -9.65 -7.97 196 4.893715 -9.58 -7.75 198 4.908804 -9.9 -8.4 200 4.923893 -9.83 -8.4 202 4.939356 -10.02 -7.99 204 4.955271 -9.52 -8.2 206 4.971185 -9.75 -8.2 208 4.9871 -9.73 -8.35 210 5.003015 -9.51 -8.54 212 5.01893 -9.34 -8 214 5.034845 -9.82 -8.37 216 5.050759 -9.84 -8.08 218 5.066674 -9.45 -8.17 220 5.082589 -9.19 -8.19 222 5.098504 -9.41 -7.99 224 5.114419 -9.78 -7.89 226 5.12997 -10.17 -8.09 228 5.145358 -9.32 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