# Hoa Huong Cave, Vietnam PCP-Corrected d18O Data from 4-45 ka #----------------------------------------------------------------------- # World Data Service for Paleoclimatology, Boulder # and # NOAA Paleoclimatology Program #----------------------------------------------------------------------- # Template Version 4.0 # Encoding: UTF-8 # NOTE: Please cite original publication, NOAA Landing Page URL, dataset and publication DOIs (where available), and date accessed when using downloaded data. # If there is no publication information, please cite investigator, study title, NOAA Landing Page URL, and date accessed. # # Description/Documentation lines begin with '#' followed by a space # Data lines have no '#' # # NOAA_Landing_Page: https://www.ncei.noaa.gov/access/paleo-search/study/39819 # Landing_Page_Description: NOAA Landing Page of this file's parent study, which includes all study metadata. # # Study_Level_JSON_Metadata: https://www.ncei.noaa.gov/pub/data/metadata/published/paleo/json/noaa-cave-39819.json # Study_Level_JSON_Description: JSON metadata of this data file's parent study, which includes all study metadata. # # Data_Type: Speleothems # # Dataset_DOI: 10.25921/643e-eb71 # # Science_Keywords: sea level, abrupt climate change, Heinrich Events, Last Glacial Maximum, Monsoon, Precipitation Reconstruction, Younger Dryas, Tropics #--------------------------------------- # Resource_Links # # Data_Download_Resource: https://www.ncei.noaa.gov/pub/data/paleo/speleothem/asia/vietnam/patterson2024/patterson2024-hh-1.txt # Data_Download_Description: NOAA Template File; HH-1 d18O Data # #--------------------------------------- # Contribution_Date # Date: 2024-09-16 #--------------------------------------- # File_Last_Modified_Date # Date: 2024-12-19 #--------------------------------------- # Title # Study_Name: Hoa Huong Cave, Vietnam PCP-Corrected d18O Data from 4-45 ka #--------------------------------------- # Investigators # Investigators: Patterson, E.W (https://orcid.org/0000-0002-3575-3374); Skiba, Vanessa (https://orcid.org/0000-0002-0496-120X); Wolf, Annabel (https://orcid.org/0000-0002-2910-874X); Griffiths, Michael (https://orcid.org/0000-0003-4051-7568); McGee, David (https://orcid.org/0000-0002-7329-3428); Du, Xiaojing (https://orcid.org/0000-0001-9709-0732); Pico, Tamara (https://orcid.org/0000-0002-3629-0922); Bùi, Thanh (https://orcid.org/0009-0009-8074-7713); Trần, Mui; Đỗ-Trọng, Quoc (https://orcid.org/0000-0003-3587-6996); Võ, Tri (https://orcid.org/0009-0009-4349-9167); Ðinh, Tri; Ersek, Vasile (https://orcid.org/0000-0001-9730-0007); Goldsmith, Gregory (https://orcid.org/0000-0003-3567-8949); Johnson, Kathleen (https://orcid.org/0000-0003-1291-198X) #--------------------------------------- # Description_Notes_and_Keywords # Description: #--------------------------------------- # Publication # Authors: E.W. Patterson, V. Skiba, A. Wolf, M.L. Griffiths, D. McGee, T. N. Bùi, M.X. Trần, T.H. Ðinh, Q. Đỗ-Trọng, G.R. Goldsmith, V. Ersek, and K.R. Johnson # Published_Date_or_Year: 2024 # Published_Title: Local hydroclimate alters interpretation of speleothem δ18O records # Journal_Name: Nature Communications # Volume: 15 # Edition: # Issue: # Pages: # Report_Number: 9064 # DOI: 10.1038/s41467-024-53422-y # Online_Resource: # Full_Citation: # Abstract: Oxygen isotopes (δ18O) are the most commonly utilized speleothem proxy and have provided many foundational records of paleoclimate. Thus, understanding processes affecting speleothem δ18O is crucial. Yet, prior calcite precipitation (PCP), a process driven by local hydrology, is a widely ignored control of speleothem δ18O. Here we investigate the effects of PCP on a stalagmite δ18O record from central Vietnam, spanning 45 – 4 ka. We employ a geochemical model that utilizes speleothem Mg/Ca and cave monitoring data to correct the δ18O record for PCP effects. The resulting record exhibits improved agreement with regional speleothem δ18O records and climate model simulations, suggesting that the corrected record more accurately reflects precipitation δ18O (δ18Op). Without considering PCP, our interpretations of the δ18O record would have been misleading. To avoid misinterpretations of speleothem δ18O, our results emphasize the necessity of considering PCP as a significant driver of speleothem δ18O. #--------------------------------------- # Funding_Agency # Funding_Agency_Name: # Grant: #--------------------------------------- # Site_Information # Site_Name: Hoa Huong Cave # Location: Vietnam # Northernmost_Latitude: 17.5 # Southernmost_Latitude: 17.5 # Easternmost_Longitude: 106.2 # Westernmost_Longitude: 106.2 # Elevation_m: 411 #--------------------------------------- # Data_Collection # Collection_Name: HH-1_d18o # First_Year: 45094 # Last_Year: 4096 # Time_Unit: calendar year before present # Core_Length_m: 3.7 # Parameter_Keywords: oxygen isotopes # Notes: These are the PCP-corrected d18O time series for stalagmite HH-1. The O'neil correction was primarily used for analyses in the published manuscript. #--------------------------------------- # Chronology_Information # Chronology: Uranium-Thorium # Chronology_Download_Resource: https://www.ncei.noaa.gov/pub/data/paleo/templates/noaa-wds-paleo-uth-terms.csv # Chronology_Download_Description: Uranium-Thorium terms and definitions. # Chronology_Notes: From Patterson E. W. et al. Glacial changes in sea level modulated millennial-scale variability of Southeast Asian autumn monsoon rainfall. Proceedings of the National Academy of Sciences 120 e2219489120 (2023). Uranium-Thorium data for Stalagmite HH1. Reported errors for 238U and 232Th concentrations are estimated to be +/-1% due to uncertainties in spike concentration; analytical uncertainties are smaller. # Rejection_Rationale: # 238U_Decay_Constant: 1.55125 x 10-10 yr-1 (Jaffey et al., 1971) # 234U_Decay_Constant: Cheng et al. (2013) # 230Th_Decay_Constant: Cheng et al. (2013) # Initial_230Th/232Th: assume the atomic ratio of 25 +/- 12.5 ppm # Initial_230Th/232Th_Method: # Age_Model_Method: # Missing_Values: na # Chronology_Table: # samp_id depth_top_cm 238U_ppb 238U_2s_ppb 232Th_ppt 232Th_2s_ppt d234U_meas_permil d234U_meas_2s_permil 230Th_238U_act 230Th_238U_act_2s 230Th_232Th_atom_ppm 230Th_232Th_atom_2s_ppm d234U_init_permil d234U_init_2s_permil age_uncorr_BP1950 age_uncorr_2s_yr age_corr_BP1950 age_corr_2s_yr date_used # UU-H2 18.2 139.584078 2.791798 789.9898 15.857833 2727.610404 1.695418 0.14444 0.000615 405.208781 1.67991 2759 2 4290 19 3961 131 yes # UU-H3 44.4 82.134006 1.642684 388.486464 7.824296 2844.934436 1.356008 0.177575 0.000818 596.084149 2.877296 2885 2 5128 24 4848 107 yes # UU-H4 68.7 78.740803 1.574823 168.069403 3.448847 2873.25347 1.558647 0.214989 0.001104 1599.211978 10.588006 2923 2 6186 33 6022 57 yes # UU-H5 95.7 87.240457 1.744811 180.292554 3.705984 2947.083151 1.387908 0.269585 0.00125 2071.162617 13.17572 3011 1 7651 37 7492 57 yes # HH-U33 105.6 98.4 2 166 3 2896.7 2 0.2828 0.0012 2670 12 2963 2 8144 36 8001 51 yes # UU-H6 115.6 77.724744 1.554497 293.13223 5.940552 2658.863354 1.497196 0.277293 0.001232 1167.378854 6.051269 2722 2 8517 39 8272 96 yes # HH-U34 132.2 93.7 1.9 571 11 2806.1 2 0.3089 0.0014 805 4 2877 2 9140 43 8800 142 yes # UU-H7 151.8 102.403091 2.048077 203.405687 4.135713 3130.024144 1.49382 0.391276 0.001514 3127.59759 15.548751 3225 2 10725 43 10574 59 yes # UU-H8 180.4 100.717376 2.014374 457.2045 9.197425 2919.19291 1.668497 0.404525 0.001407 1414.872525 5.093962 3016 2 11728 43 11463 106 yes # UU-H9 206.7 127.946639 2.55898 180.297341 3.73068 3146.118181 1.488982 0.460313 0.001581 5186.451823 31.195687 3260 2 12652 46 12525 54 yes # UU-H10 235.9 128.64541 2.572913 218.287949 4.48804 3016.795747 1.102359 0.48835 0.001632 4569.55314 25.168357 3137 1 13918 49 13777 60 yes # HH1-U25 238 139.582578 2.791707 349.309099 7.019898 3149.523696 1.601262 0.511866 0.001764 3247.546273 11.242209 3277 2 14130 52 13958 72 yes # HH1-U37 238.3 172.785523 3.455791 5549.190458 111.149839 3666.244204 1.949389 0.623799 0.002569 308.389815 1.213479 3816 7 15370 67 14148 582 yes # HH-U16 238.5 114.871932 2.297449 1300.612134 26.100113 3784.466721 1.367737 0.614061 0.002486 861.103441 3.386145 3941 3 14722 63 14257 207 yes # HH1-U26 239 127.763674 2.555291 1293.048976 25.905441 3610.548456 1.462722 0.640281 0.002562 1004.479869 3.724316 3773 3 16002 68 15566 195 yes # HH1-U27 240.5 119.833137 2.396676 359.315008 7.211445 3760.206946 1.444493 0.678878 0.002757 3594.771712 14.228383 3938 2 16456 71 16280 88 yes # HH-U17 242 112.364132 2.24731 468.362745 9.432155 4161.476388 1.817563 0.837556 0.003285 3190.342411 13.182777 4387 2 18870 79 18666 104 yes # HH1-U28 242.8 112.175052 2.243518 572.264851 11.48324 3952.021293 1.725267 0.884986 0.003326 2754.312919 9.968422 4190 2 20931 85 20691 120 yes # HH1-U29 243.6 114.907393 2.298177 360.703248 7.23774 4229.298524 2.344766 1.036135 0.003471 5240.73482 16.605856 4517 3 23391 86 23222 99 yes # HH-U18 243.9 137.456857 2.749385 876.720636 17.640255 3856.652835 2.932317 1.018034 0.003742 2534.22652 9.194199 4135 4 24882 101 24597 147 yes # HH-U19 244.9 130.454187 2.609118 280.501796 5.643406 3223.607845 1.558763 0.921362 0.003574 6803.472002 27.251469 3468 2 26021 111 25868 119 yes # HH-U20 254.7 130.691732 2.613917 508.10675 10.193468 3165.524008 1.982486 0.91815 0.003093 3749.59912 11.637513 3408 2 26322 98 26100 124 yes # HH-U21 260.9 136.063297 2.721292 463.129598 9.295578 2835.204386 1.425544 0.874973 0.00309 4081.4183 13.905973 3062 2 27362 107 27147 129 yes # UU-H11 262.4 122.314372 2.446311 602.41149 12.118812 3057.52825 1.412758 0.94791 0.00299 3055.830475 10.110013 3308 2 28071 98 27804 139 yes # HH1-U30 263.8 120.715433 2.414328 632.289492 12.69062 3202.647202 1.495645 1.003676 0.003768 3042.413583 11.083217 3471 2 28753 120 28481 157 yes # HH-U35 264.7 99.1 2 827 17 3946 2 1.28 0.004 2436 8 4308 3 31389 110 31039 175 yes # HH1-U31 265.2 86.362792 1.727276 385.751419 7.738073 3697.383514 2.297471 1.244198 0.004398 4422.691745 14.623688 4048 3 32231 129 32008 150 yes # HH-U22 266.8 101.213004 2.024302 780.551606 15.653667 3289.696652 1.524774 1.174644 0.003928 2418.348845 7.484169 3613 3 33492 127 33134 192 yes # HH-U23 272 95.908605 1.918196 487.34525 9.782502 3487.629476 2.03034 1.282614 0.004389 4007.69439 13.062782 3849 3 35133 137 34882 164 yes # HH-U24 280.2 121.499293 2.430053 99.255332 2.02979 3008.279569 2.159118 1.202009 0.004542 23361.765054 124.312535 3341 3 37161 162 37058 163 yes # HH-U36 288 125 2 187 4 3014 2 1.221 0.005 12930 50 3352 3 37771 178 37642 181 yes # UU-H12* 289.8 128.294552 2.565983 1295.109038 25.976382 2996.683984 1.813478 1.19884 0.003705 1885.562003 5.267147 3324 3 37173 133 36701 241 NO # HH1-U32 302.8 132.70652 2.654146 620.823093 12.450877 2869.528123 1.819798 1.213557 0.004075 4118.721506 12.938439 3203 3 39140 153 38877 180 yes # UU-H13 315.9 139.174246 2.783593 679.698322 13.665844 2856.096414 1.792541 1.267359 0.004346 4120.21662 14.277793 3208 3 41321 166 41050 194 yes # UU-H14 348.8 135.158122 2.703173 671.652174 13.517842 2670.093418 2.015982 1.281774 0.00391 4095.313969 13.447529 3025 3 44396 162 44113 194 yes # UU-H15 367.8 131.624725 2.632501 223.203909 4.565063 2659.860341 1.257256 1.299055 0.003877 12163.007261 59.141006 3022 2 45252 160 45109 164 yes #--------------------------------------- # Variables # PaST_Thesaurus_Download_Resource: https://www.ncei.noaa.gov/access/paleo-search/skos/past-thesaurus.rdf # PaST_Thesaurus_Download_Description: Paleoenvironmental Standard Terms (PaST) Thesaurus terms, definitions, and relationships in SKOS format. # # Data variables follow that are preceded by "##" in columns one and two. # Variables list, one per line, shortname-tab-var components: what, material, error, units, seasonality, data type, detail, method, C or N for Character or Numeric data) # ## age_yrsBP age,,,calendar year before present,,speleothems,,,N,present defined as 1950 common era. See age model and chronology from Patterson E. W. et al. Glacial changes in sea level modulated millennial-scale variability of Southeast Asian autumn monsoon rainfall. Proceedings of the National Academy of Sciences 120 e2219489120 (2023). ## d18o_uncorrected delta 18O,calcite,,per mil VPDB,,speleothems,,isotope ratio mass spectrometry,N,original d18O data for speleothem HH-1. Same as data from Patterson E. W. et al. Glacial changes in sea level modulated millennial-scale variability of Southeast Asian autumn monsoon rainfall. Proceedings of the National Academy of Sciences 120 e2219489120 (2023). ## d18o_corr_oneil delta 18O,calcite,,per mil VPDB,,speleothems,,isotope ratio mass spectrometry,N,d18O corrected for PCP using fractional factor from O’Neil J. R. Clayton R. N. & Mayeda T. K. Oxygen isotope fractionation in divalent metal carbonates. J. Chem. Phys. 51 5547–5558 (1969). This was the primary corrected used for analyses presented in the manuscript ## d18O_daeron delta 18O,calcite,,per mil VPDB,,speleothems,,isotope ratio mass spectrometry,N,d18O corrected for PCP using fractional factor from Daëron M. et al. Most Earth-surface calcites precipitate out of isotopic equilibrium. Nat. Commun. 10 429 (2019). ## d18o_johnston delta 18O,calcite,,per mil VPDB,,speleothems,,isotope ratio mass spectrometry,N,d18O corrected for PCP using fractional factor from Johnston V. Borsato A. Spötl C. Frisia S. & Miorandi R. Stable isotopes in caves over altitudinal gradients: fractionation behaviour and inferences for speleothem sensitivity to climate change. Clim. Past 9 99–118 (2013). ## d18O_tremaine delta 18O,calcite,,per mil VPDB,,speleothems,,isotope ratio mass spectrometry,N,d18O corrected for PCP using fractional factor from Tremaine D. M. Froelich P. N. & Wang Y. Speleothem calcite farmed in situ: Modern calibration of d18O and d13C paleoclimate proxies in a continuously-monitored natural cave system. Geochim. Cosmochim. 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