# Liu-li Cave, China Speleothem d18O, d13C and Sr/Ca Data Over the Past 6,700 years #----------------------------------------------------------------------- # World Data Service for Paleoclimatology, Boulder # and # NOAA Paleoclimatology Program #----------------------------------------------------------------------- # Template Version 4.0 # Encoding: UTF-8 # NOTE: Please cite original publication, NOAA Landing Page URL, dataset and publication DOIs (where available), and date accessed when using downloaded data. # If there is no publication information, please cite investigator, study title, NOAA Landing Page URL, and date accessed. # # Description/Documentation lines begin with '#' followed by a space # Data lines have no '#' # # NOAA_Landing_Page: https://www.ncei.noaa.gov/access/paleo-search/study/38200 # Landing_Page_Description: NOAA Landing Page of this file's parent study, which includes all study metadata. # # Study_Level_JSON_Metadata: https://www.ncei.noaa.gov/pub/data/metadata/published/paleo/json/noaa-cave-38200.json # Study_Level_JSON_Description: JSON metadata of this data file's parent study, which includes all study metadata. # # Data_Type: Speleothems # # Dataset_DOI: 10.25921/c2db-gj83 # # Science_Keywords: #--------------------------------------- # Resource_Links # # Data_Download_Resource: https://www.ncei.noaa.gov/pub/data/paleo/speleothem/china/zhao2021/zhao2021-llc_iso.txt # Data_Download_Description: NOAA Template File; d18O and d13C Data # #--------------------------------------- # Contribution_Date # Date: 2023-06-20 #--------------------------------------- # File_Last_Modified_Date # Date: 2023-07-05 #--------------------------------------- # Title # Study_Name: Liu-li Cave, China Speleothem d18O, d13C and Sr/Ca Data Over the Past 6,700 years #--------------------------------------- # Investigators # Investigators: Zhao, Jingyao #--------------------------------------- # Description_Notes_and_Keywords # Description: # Provided Keywords: Speleothem, Stable isotopes, 2-kyr shift, Asian summer monsoon #--------------------------------------- # Publication # Authors: Jingyao Zhao, Liangcheng Tan, Yan Yang, Carlos Perez-Mejías, Yassine Ait Brahim, Jianghu Lan, Jian Wang, Hanying Li, Tianli Wang, Haiwei Zhang, Hai Cheng # Published_Date_or_Year: 2021 # Published_Title: New insights towards an integrated understanding of NE Asian monsoon during mid to late Holocene # Journal_Name: Quaternary Science Reviews # Volume: 254 # Edition: # Issue: 15 # Pages: # Report_Number: 106793 # DOI: 10.1016/j.quascirev.2020.106793 # Online_Resource: # Full_Citation: # Abstract: Speleothem records from NE Asia are essential to understand the spatial patterns of the Asian Summer Monsoon (ASM) variability. In this paper, we present a new high-resolution and chronologically well-resolved speleothem record from Liu-li (LL) cave, NE China, through d18O, d13C and Sr/Ca ratio characterizing a dynamic ASM history over the past 6680 years. The LL d18O record shows a long-term trend to higher values, following the North Hemisphere summer insolation (NHSI), with the exception of the last 2 kyr characterized by a negative d18O excursion. The ‘2-kyr shift’ is evident in NE Asia over the past 2 kyr, originally inferred from the speleothem d18O negative excursion in South China, as well as in many other proxy records from East China, but it merely manifests a flat trend in most of the western East Asian Summer Monsoon (EASM) and Indian Summer Monsoon (ISM) regions, rather than a negative excursion. On multi-centennial to millennial timescales, the intensification of the Tsushima Warm Current (TWC) can amplify rainfall on both sides of the Japan Sea. A close comparison between the monsoon reconstruction and the cultural changes in NE Asia suggests contemporary climatic and cultural regime-shifts, implying an important role of the ASM weakening in the collapse of Neolithic and Early Bronze cultures in this region. #--------------------------------------- # Funding_Agency # Funding_Agency_Name: National Science Foundation of China # Grant: 41888101, XDB40000000, 41731174 #--------------------------------------- # Funding_Agency # Funding_Agency_Name: Guangxi Key Science and Technology Innovation Base on Karst Dynamics # Grant: 42002199 #--------------------------------------- # Site_Information # Site_Name: Liu-li Cave # Location: China # Northernmost_Latitude: 41.02 # Southernmost_Latitude: 41.02 # Easternmost_Longitude: 125.82 # Westernmost_Longitude: 125.82 # Elevation_m: 490 #--------------------------------------- # Data_Collection # Collection_Name: L-LC Isotope # First_Year: 6682.58 # Last_Year: -54.76 # Time_Unit: calendar year before present # Core_Length_m: # Parameter_Keywords: carbon isotopes, oxygen isotopes # Notes: #--------------------------------------- # Chronology_Information # Chronology: Uranium-Thorium # Chronology_Download_Resource: https://www.ncei.noaa.gov/pub/data/paleo/templates/noaa-wds-paleo-uth-terms.csv # Chronology_Download_Description: Uranium-Thorium terms and definitions. # Chronology_Notes: U-Th isotopic data and 230Th dates of stalagmite LL2. Two hiatuses exist at 55- and 116-mm depth from top. Sample LL2-4D discarded from the age-model due to the hiatus located at 55.0 mm. # 238U_Decay_Constant: 1.55125x10-10 (Jaffey et al., 1971) # 234U_Decay_Constant: 2.82206x10-6 (Cheng et al., 2013) # 230Th_Decay_Constant: 9.1705x10-6 (Cheng et al., 2013) # Initial_230Th/232Th: 4.4 +/- 2.2 x10-6 # Initial_230Th/232Th_Method: Values for a material at secular equilibrium, with the bulk earth 232Th/238U value of 3.8. The errors are arbitrarily assumed to be 50%. # Missing_Values: na # Chronology_Table: # samp_id depth_top_mm 238U_ppb 238U_2s_ppb 232Th_ppt 232Th_2s_ppt 230Th_232Th_atom_ppm 230Th_232Th_atom_2s_ppm d234U_meas_permil d234U_meas_2s_permil 230Th_238U_act 230Th_238U_act_2s age_uncorr_BM age_uncorr_2s_yr age_corr_BM age_corr_2s_yr d234U_init_permil d234U_init_2s_permil age_corr_BP1950 age_corr_2s_yr date_used date_type # LL2-1E 1 82.4915330623099 0.242788567626376 554.190205853379 11.4147562484341 7.47109990562017 0.322926717236104 643.183930544115 3.99406992957832 3.04416611137001E-03 1.16025034912908E-04 202.181881467642 7.72789931580691 83.1604636454086 84.5522430609261 643.334893147602 3.99795553176426 16.1604636454086 84.5522430609261 yes MC-ICP-MS # LL2-2B 7.5 77.006556297951 0.373726075645352 1939.8911498193 39.629844711537 8.39115569094285 0.439588208776496 733.55896439615 6.23324543200832 1.28205238232108E-02 6.21577496499672E-04 809.046739714682 39.4600549117447 385.65989457767 302.121146804568 734.357771998562 6.27136629265337 319.65989457767 302.121146804568 yes MC-ICP-MS # LL2-2D 16.5 82.3179191491653 0.139659692393259 719.503129351105 14.5215814205142 26.4277402646042 0.744939713847802 608.826905868701 2.55703689476058 1.40098235291116E-02 2.76700714889304E-04 953.246749795309 18.9611649190136 795.18276467142 113.408043934425 610.194680373341 2.57021142801467 729.18276467142 113.408043934425 yes MC-ICP-MS # LL2-4B 19 70.2974780777736 0.276998064179836 1477.65088279924 29.9667530565068 14.815406319051 0.480765746636533 567.406085444472 4.7826358886025 1.88877397835181E-02 4.84229214457829E-04 1321.11269211292 34.2935091191376 930.611891927246 278.362204918371 568.898190222902 4.81599271126981 864.611891927246 278.362204918371 yes MC-ICP-MS # LL2-3D 28 50.2518219356375 6.67203738755031E-02 340.423965732624 6.97984095475906 55.0030024060883 1.56364547331179 476.862984630697 2.32323150743201 2.25989906586963E-02 4.46032459830756E-04 1680.21337369113 33.4994416772558 1546.84534108971 100.098908232383 478.949180541309 2.33731436645918 1480.84534108971 100.098908232383 yes MC-ICP-MS # LL2-7B 34 64.196928408824 0.127418895064022 380.26353981181 7.6758222605167 91.5931588591843 2.70408467985215 496.595048286265 2.44265341094176 3.29054478675532E-02 7.11910718567416E-04 2421.53811712537 53.0667419144729 2306.55541822564 97.0747036283115 499.838047445534 2.4624152910639 2240.55541822564 97.0747036283115 yes MC-ICP-MS # Hiatus-1 55 NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA yes Hiatus # LL2-4D 56 59.8722241984409 0.118641455303657 1348.59844241246 27.1712023228993 35.8278364165252 0.873197624288288 482.550903771196 2.70888904405635 4.89454331060781E-02 6.78179297666376E-04 3654.59343926506 51.8564372753581 3212.97373067873 316.670010286005 486.946188786092 2.76798381698467 3146.97373067873 316.670010286005 no MC-ICP-MS # LL2-5D 64.5 62.414414102017 0.148504751614078 952.342327420116 19.2386316248343 62.8608924000382 1.53847647096299 529.596138422471 3.02408170103188 5.81732145580429E-02 8.15563104422105E-04 4219.24905789358 60.7858323206255 3929.73426207275 213.563117325051 535.502019504453 3.07479016735952 3863.73426207275 213.563117325051 yes MC-ICP-MS # LL2-2E 74.5 49.9182051844863 0.112128729929585 442.830220044577 9.07482631091869 128.477926264256 2.95991957193108 557.557999376733 2.8712572152258 6.91259540919391E-02 7.44009707786416E-04 4937.64409484165 55.0253907268919 4772.5894198595 128.998549423951 565.118288269426 2.91745297881647 4705.5894198595 128.998549423951 yes MC-ICP-MS # LL2-1F 93.5 40.5068778615924 0.104616364019453 202.350002004893 4.32174580628089 255.356633642959 5.83416576550661 541.50521159475 2.93289642379974 7.73670287937807E-02 6.58706763888163E-04 5599.11521640951 49.9939205316553 5505.28769302283 83.0112866330738 549.983867499174 2.98160348585429 5438.28769302283 83.0112866330738 yes MC-ICP-MS # LL2-6D 102.5 46.0008604948858 8.74340309820047E-02 316.465264178105 6.4899515852377 188.017775792315 4.45249878750985 511.841456376502 2.88901006580876 7.84500698484664E-02 9.40893146766228E-04 5794.07029885399 72.0776550740691 5662.29410704822 117.741678855168 520.086039462756 2.94062751041081 5596.29410704822 117.741678855168 yes MC-ICP-MS # LL2-3E 106 52.2532880131769 8.59272234665886E-02 424.561019210182 8.63747524494208 159.427305612169 3.50336890822438 462.177513543196 1.88864683739065 7.85639900050492E-02 6.65195045521025E-04 6005.88132480237 52.745718271131 5844.91098149057 125.43430121381 469.864210171949 1.92724823662945 5777.91098149057 125.43430121381 yes MC-ICP-MS # LL2-2F 112 45.6301861995176 0.178529514830209 563.216169575448 11.7406008030289 108.714580875211 2.58355653783893 442.943040079556 4.17568182666933 8.13851186679106E-02 9.81591843985994E-04 6312.93009331872 80.4156377708732 6065.05808621035 192.664860814442 450.589689146407 4.25482687746454 5998.05808621035 192.664860814442 yes MC-ICP-MS # LL2-3F 114 47.5164924063453 0.120739528858102 219.132472407917 4.78027843888264 295.158458609096 7.46348535289107 447.370635999296 2.79392592008092 8.25566249132546E-02 1.0762895311198E-03 6386.01020517417 86.4414141792854 6293.75939097059 108.204258938437 455.387536244065 2.84739073850711 6226.75939097059 108.204258938437 yes MC-ICP-MS # LL2-1G 115 42.7490407628967 0.150697463491285 1064.76932064654 21.9510410906824 58.6475588692717 1.50425812434972 435.181643527048 4.03437037978261 8.85958596604064E-02 1.38740138670565E-03 6927.13992154719 113.468944639268 6423.84191398835 373.425036611147 443.142764712271 4.13463200091878 6356.84191398835 373.425036611147 yes MC-ICP-MS # Hiatus-2 116 NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA yes Hiatus # LL2-4E 116.5 52.2572068641218 0.119316560969496 1430.4006396113 28.852473673945 55.5000983625182 1.19655830027344 434.074835398055 3.00647645985598 9.21381709886564E-02 7.3219181008392E-04 7218.34566172477 61.167569276335 6664.80862868345 396.270623647192 442.316391790704 3.1032344668212 6597.80862868345 396.270623647192 yes MC-ICP-MS # LL2-4F 118 36.8822486116945 0.110136297185843 1326.57731963006 27.0836428572486 44.0693089199613 1.05273758290877 438.340900993914 3.35736160680668 9.61359336908135E-02 1.22619700638308E-03 7518.30595421358 100.61796822212 6792.69644808227 522.969004392445 446.824688124051 3.48529596667492 6725.69644808227 522.969004392445 yes MC-ICP-MS # #--------------------------------------- # Variables # PaST_Thesaurus_Download_Resource: https://www.ncei.noaa.gov/access/paleo-search/skos/past-thesaurus.rdf # PaST_Thesaurus_Download_Description: Paleoenvironmental Standard Terms (PaST) Thesaurus terms, definitions, and relationships in SKOS format. # # Data variables follow that are preceded by "##" in columns one and two. # Variables list, one per line, shortname-tab-var components: what, material, error, units, seasonality, data type, detail, method, C or N for Character or Numeric data) # ## age age,,,calendar year before present,,Speleothems,,,N, ## DFT depth,,,millimeter,,Speleothems,,,N, distance (millimeter) from the speleothem top ## d13C delta 13C,calcium carbonate,,per mil VPDB,,Speleothems,,,N, ## d18O delta 18O,calcium carbonate,,per mil VPDB,,Speleothems,,,N, #------------------------ # Data: # Data lines follow (have no #) # Data line format - tab-delimited text, variable short name as header # Missing_Values: NA age DFT d13C d18O -54.76 0.1 -3.12 -8.26 -49.51 0.2 -2.79 -7.80 -44.27 0.3 -3.24 -8.13 -39.03 0.4 -3.38 -8.09 -33.79 0.5 -3.26 -7.93 -28.54 0.6 -3.13 -7.69 -23.30 0.7 -2.90 -7.21 -18.06 0.8 -2.71 -7.30 -12.82 0.9 -2.63 -7.50 -7.57 1 -3.08 -7.61 -2.27 1.1 -3.65 -7.72 3.02 1.2 -3.73 -7.89 8.32 1.3 -3.41 -7.73 13.62 1.4 -3.43 -7.47 18.92 1.5 -3.68 -7.50 24.22 1.6 -3.43 -7.28 29.52 1.7 -3.15 -7.23 34.82 1.8 -3.01 -7.33 40.12 1.9 -2.91 -7.40 45.42 2 -3.16 -7.69 50.21 2.1 -2.77 -7.19 55.00 2.2 -2.74 -7.18 59.79 2.3 -2.95 -7.08 64.58 2.4 -3.16 -7.24 69.38 2.5 -3.38 -7.17 74.17 2.6 -3.70 -7.13 78.96 2.7 -3.73 -7.10 83.75 2.8 -3.85 -7.30 88.55 2.9 -3.59 -7.12 93.34 3 -3.87 -7.75 98.82 3.1 -3.89 -7.76 104.31 3.2 -3.53 -7.84 109.79 3.3 -3.16 -7.65 115.27 3.4 -3.46 -7.61 120.76 3.5 -3.59 -7.72 126.24 3.6 -3.41 -7.79 131.73 3.7 -3.28 -7.65 137.21 3.8 -3.05 -7.46 142.69 3.9 -3.19 -7.34 148.18 4 -3.74 -7.46 155.12 4.1 -3.83 -7.33 162.06 4.2 -3.70 -7.35 169.00 4.3 -3.51 -7.22 175.94 4.4 -3.82 -6.59 182.88 4.5 -4.07 -6.63 189.82 4.6 -3.99 -6.83 196.76 4.7 -4.23 -7.50 203.70 4.8 -4.16 -7.23 210.64 4.9 -4.03 -6.96 217.58 5 -3.98 -6.82 223.28 5.1 -3.87 -6.77 228.99 5.2 -3.73 -6.98 234.69 5.3 -3.91 -7.26 240.39 5.4 -4.31 -7.42 246.10 5.5 -4.31 -7.43 251.80 5.6 -4.39 -7.66 257.50 5.7 -4.23 -7.22 263.21 5.8 -3.85 -7.16 268.91 5.9 -3.60 -7.30 274.61 6 -3.53 -7.43 280.52 6.1 -3.61 -7.37 286.43 6.2 -3.70 -7.38 292.34 6.3 -3.73 -7.72 298.25 6.4 -3.93 -7.85 304.16 6.5 -4.17 -7.77 310.07 6.6 -4.09 -7.72 315.98 6.7 -3.73 -7.42 321.89 6.8 -3.76 -7.66 327.80 6.9 -3.92 -7.53 333.71 7 -3.90 -6.80 338.29 7.1 -4.30 -6.67 342.88 7.2 -4.30 -6.87 347.46 7.3 -4.30 -7.31 352.04 7.4 -4.49 -7.47 356.62 7.5 -4.47 -7.35 361.20 7.6 -4.28 -7.68 365.78 7.7 -4.02 -7.70 370.36 7.8 -3.94 -7.59 374.94 7.9 -4.06 -7.79 379.53 8 -3.95 -7.50 384.50 8.1 -4.18 -7.34 389.47 8.2 -4.13 -7.36 394.45 8.3 -3.79 -7.46 399.42 8.4 -3.66 -7.57 404.40 8.5 -3.73 -7.57 409.37 8.6 -3.99 -7.37 414.35 8.7 -4.44 -7.58 419.32 8.8 -5.13 -7.99 424.30 8.9 -5.43 -8.10 429.27 9 -4.30 -7.72 433.52 9.1 -4.28 -7.57 437.78 9.2 -3.88 -7.33 442.03 9.3 -3.91 -7.52 446.28 9.4 -4.17 -7.62 450.54 9.5 -4.19 -7.66 454.79 9.6 -4.23 -7.45 459.04 9.7 -4.33 -7.38 463.30 9.8 -4.63 -7.66 467.55 9.9 -4.97 -7.87 471.81 10 -5.07 -8.07 474.52 10.1 -5.33 -8.12 477.23 10.2 -5.70 -8.03 479.94 10.3 -6.04 -7.94 482.65 10.4 -5.69 -7.93 485.36 10.5 -5.31 -7.95 488.07 10.6 -5.09 -8.14 490.79 10.7 -4.93 -7.92 493.50 10.8 -4.75 -7.50 496.21 10.9 -4.45 -7.49 498.92 11 -3.20 -7.21 503.60 11.1 -3.71 -7.28 508.27 11.2 -3.27 -7.32 512.95 11.3 -2.88 -7.07 517.63 11.4 -3.10 -7.32 522.30 11.5 -2.99 -6.86 526.98 11.6 -3.07 -7.08 531.66 11.7 -3.67 -7.19 536.33 11.8 -4.10 -7.19 541.01 11.9 -4.38 -7.36 545.69 12 -4.56 -7.53 547.64 12.1 -4.76 -7.65 549.60 12.2 -4.89 -7.83 551.56 12.3 -4.68 -7.69 553.51 12.4 -4.71 -7.86 555.47 12.5 -5.02 -8.51 557.42 12.6 -4.41 -7.34 559.38 12.7 -4.64 -7.29 561.33 12.8 -4.54 -7.28 563.29 12.9 -4.63 -7.44 565.25 13 -4.94 -7.77 569.42 13.1 -4.698 -7.517 573.59 13.2 NA NA 577.77 13.3 -5.485 -7.819 581.94 13.4 -5.76 -7.56 586.11 13.5 -5.35 -7.904 590.29 13.6 -5.65 -7.88 594.46 13.7 -5.67 -7.87 598.64 13.8 -5.411 -8.303 602.81 13.9 -5.39 -8.52 606.98 14 -4.343 -8.451 609.20 14.1 -4.80 -8.62 611.42 14.2 -5.14 -8.33 613.64 14.3 -5.63 -8.14 615.86 14.4 -5.95 -8.15 618.08 14.5 -5.84 -8.10 620.30 14.6 -5.82 -7.90 622.52 14.7 -5.87 -7.79 624.74 14.8 -2.93 -7.52 626.97 14.9 -2.55 -7.49 629.19 15 -3.12 -7.67 633.43 15.1 -3.02 -7.79 637.67 15.2 -3.03 -8.00 641.91 15.3 -3.15 -7.89 646.15 15.4 -3.41 -7.91 650.39 15.5 -3.46 -7.74 654.63 15.6 -3.41 -7.48 658.87 15.7 -3.36 -7.74 663.11 15.8 -3.30 -7.64 667.35 15.9 -3.23 -7.51 671.59 16 -3.01 -7.48 675.51 16.1 NA NA 679.44 16.2 -3.29 -7.59 683.36 16.3 -3.41 -7.61 687.29 16.4 -3.48 -7.59 691.21 16.5 -3.58 -7.66 695.14 16.6 -3.55 -7.61 699.06 16.7 -3.48 -7.59 702.99 16.8 -3.22 -7.60 706.91 16.9 -3.10 -7.61 710.84 17 -3.07 -7.56 715.64 17.1 -3.01 -7.60 720.45 17.2 -3.15 -7.98 725.26 17.3 -3.40 -7.93 730.06 17.4 -2.94 -7.47 734.87 17.5 -2.10 -7.23 739.68 17.6 -2.82 -7.72 744.48 17.7 -3.37 -7.63 749.29 17.8 -3.91 -7.63 754.10 17.9 -4.09 -7.54 758.91 18 -3.98 -7.41 766.09 18.1 -4.29 -7.43 773.28 18.2 -4.67 -7.37 780.47 18.3 -4.61 -7.41 787.66 18.4 -4.46 -7.45 794.85 18.5 -4.07 -7.28 802.03 18.6 -3.58 -7.04 809.22 18.7 -3.77 -7.39 816.41 18.8 -4.01 -7.40 823.60 18.9 -4.16 -7.43 830.79 19 -4.51 -7.27 837.34 19.1 -4.58 -7.41 843.90 19.2 -4.47 -7.61 850.46 19.3 -4.22 -7.31 857.01 19.4 -4.07 -7.09 863.57 19.5 -3.65 -7.26 870.13 19.6 -3.43 -7.12 876.68 19.7 -3.49 -7.60 883.24 19.8 -3.45 -7.34 889.80 19.9 -3.54 -7.52 896.35 20 -3.58 -7.51 903.51 20.1 -3.72 -7.48 910.67 20.2 -4.19 -7.63 917.82 20.3 -4.38 -7.72 924.98 20.4 -4.37 -7.62 932.14 20.5 -4.32 -7.51 939.29 20.6 -4.08 -7.41 946.45 20.7 -3.648 -7.401 953.61 20.8 -3.572 -7.384 960.77 20.9 -3.613 -7.491 967.92 21 -4.107 -7.622 976.22 21.1 -4.482 -7.788 984.51 21.2 -4.311 -7.989 992.81 21.3 -4.051 -8.041 1001.10 21.4 -3.708 -7.931 1009.40 21.5 -3.633 -7.935 1017.69 21.6 -3.45 -7.97 1025.99 21.7 -3.78 -7.83 1034.28 21.8 -4.14 -7.74 1042.57 21.9 -3.89 -7.64 1050.87 22 -3.76 -7.31 1082.05 22.33 -3.45 -7.61 1113.23 22.67 -3.36 -7.21 1144.41 23.00 -2.69 -7.18 1169.90 23.25 -2.89 -7.61 1195.39 23.50 -3.47 -7.42 1220.88 23.75 -3.96 -7.77 1246.37 24.00 -2.04 -7.56 1280.56 24.33 -1.39 -7.44 1314.76 24.67 -3.26 -7.69 1348.96 25.00 -1.71 -7.41 1378.41 25.50 -2.15 -7.41 1407.86 26.00 -2.53 -7.30 1430.67 26.50 -3.84 -7.49 1453.48 27.00 -2.67 -7.44 1471.62 27.33 -1.14 -7.34 1489.75 27.67 -1.87 -7.28 1507.88 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