Processing Steps |
- Parameter or Variable: Dissolved Inorganic Carbon; Abbreviation: TCO2; Unit: µmol/kg; Observation type: Profile; In-situ / Manipulation / Response variable: IN-SITUOBSERVATION; Measured or calculated: MEASURED; Sampling instrument: Niskin bottles; Analyzing instrument: Metrohm titrator (794 Basic Titrino); Detailed sampling and analyzing information: Seawater was collected in 500 ml glass bottles for the simultaneous analysis of total CO2 and total alkalinity. The samples were poisoned and stored in the dark in a cold environment. Measurements were performed onboard within a few days following a potentiometric titration method (Edmond, 1970, DSR), using an automated system with a closed cell described by Metzl et al. (2006, DSR). The equivalence point is determined using a non-linear regression method (D.O.E., 1994, eds. ORNL/CDIAC-74).; Replicate information: Deep replicate samples were collected from two different Niskin bottles (1200m or bottom). The mean difference between two deep replicates was 1.3±1.9 µmol/kg (n=9).; Standardization description: Measurements were calibrated using Certified Reference Materials (CRMs); Standardization frequency: Twice a day; CRM manufacturer: Dr. A. Dickson, SIO, University of California; CRM batch number: 111, 119; Preservation method: HgCl2; Preservative volume: 300 µL of saturated solution; Preservative correction: no correction; Uncertainty: 3 µmol/kg; Quality flag convention: WOCE/GLODAP (2 Acceptable, 3 Questionable, 4 Known bad, 9 No data); Method reference: Metzl, N., C.Brunet, Jabaud-Jan A, A.Poisson and B.Schauer, 2006. Summer and winter air-sea CO2 fluxes in the Southern Ocean Deep Sea Res I, 53, 1548-1563, https://doi.org/10.1016/j.dsr.2006.07.006; Researcher name: C. Lo Monaco; Researcher institution: LOCEAN-IPSL, Sorbonne Universite.
- Parameter or Variable: Total alkalinity; Abbreviation: TA; Unit: µmol/kg; Observation type: Profile; In-situ / Manipulation / Response variable: IN-SITUOBSERVATION; Measured or calculated: MEASURED; Sampling instrument: Niskin bottles; Analyzing instrument: Metrohm titrator (794 Basic Titrino); Type of titration: Potentiometric titration; Cell type (open or closed): CLOSED; Curve fitting method: non-linear regression method (D.O.E., 1994, eds. ORNL/CDIAC-74); Detailed sampling and analyzing information: Seawater was collected in 500 ml glass bottles for the simultaneous analysis of total CO2 and total alkalinity. The samples were poisoned and stored in the dark in a cold environment. Measurements were performed onboard within a few days following a potentiometric titration method (Edmond, 1970, DSR), using an automated system with a closed cell described by Metzl et al. (2006, DSR). The equivalence point is determined using a non-linear regression method (D.O.E., 1994, eds. ORNL/CDIAC-74).; Replicate information: Deep replicate samples were collected from two different Niskin bottles (1200m or bottom). The mean difference between two deep replicates was 2.7±3.5 µmol/kg (n=9).; Standardization description: Measurements were calibrated using Certifie Referenced Materials (CRMs); Standardization frequency: Twice a day; CRM manufacturer: Dr. A. Dickson, SIO, University of California; CRM batch number: 111, 119; Preservation method: HgCl2; Preservative volume: 300 µL of saturated solution; Preservative correction: no correction; Uncertainty: 3 µmol/kg; Quality flag convention: WOCE/GLODAP (2 Acceptable, 3 Questionable, 4 Known bad, 9 No data); Method reference: Metzl, N., C.Brunet, Jabaud-Jan A, A.Poisson and B.Schauer, 2006. Summer and winter air-sea CO2 fluxes in the Southern Ocean Deep Sea Res I, 53, 1548-1563, https://doi.org/10.1016/j.dsr.2006.07.006; Researcher name: C. Lo Monaco; Researcher institution: LOCEAN-IPSL, Sorbonne Universite.
- Parameter or Variable: Pressure from CTD sensor; Abbreviation: CTD_PRES; Unit: dbar; Observation type: Profile; In-situ / Manipulation / Response variable: IN-SITUOBSERVATION; Measured or calculated: MEASURED; Sampling instrument: CTD Sea-Bird SBE 911plus; Analyzing instrument: SBE pressure sensor, SN: 0402, calibration: 1-May-2005; Quality flag convention: WOCE/GLODAP (2 Acceptable, 3 Questionable, 4 Known bad, 9 No data); Researcher name: C. Lo Monaco; Researcher institution: LOCEAN-IPSL, Sorbonne Universite.
- Parameter or Variable: Depth calculated from CTD_PRES; Abbreviation: Depth; Unit: m; Observation type: Profile; In-situ / Manipulation / Response variable: IN-SITUOBSERVATION; Measured or calculated: CALCULATED; Calculation method and parameters: calculated from CTD_PRES using the Seabird processing software; Sampling instrument: CTD Sea-Bird SBE 911plus; Analyzing instrument: SBE pressure sensor, SN: 0402, calibration: 1-May-2005; Quality flag convention: WOCE/GLODAP (2 Acceptable, 3 Questionable, 4 Known bad, 9 No data); Researcher name: C. Lo Monaco; Researcher institution: LOCEAN-IPSL, Sorbonne Universite.
- Parameter or Variable: Temperature from CTD sensor; Abbreviation: CTD_TEMP; Unit: degree Celsius; Observation type: Profile; In-situ / Manipulation / Response variable: IN-SITUOBSERVATION; Measured or calculated: MEASURED; Sampling instrument: CTD Sea-Bird SBE 911plus; Analyzing instrument: SBE temperature sensor, SN: 1820, calibration: 23-Apr-2004; Uncertainty: 0.001 degree Celsius.; Quality flag convention: WOCE/GLODAP (2 Acceptable, 3 Questionable, 4 Known bad, 9 No data); Researcher name: C. Lo Monaco; Researcher institution: LOCEAN-IPSL, Sorbonne Universite.
- Parameter or Variable: Salinity from CTD sensor; Abbreviation: CTD_SAL; Unit: psu; Observation type: Profile; In-situ / Manipulation / Response variable: IN-SITUOBSERVATION; Measured or calculated: CALCULATED; Calculation method and parameters: Salinity calculated from conductivity using the Seabird processing software.; Sampling instrument: CTD Sea-Bird SBE 911plus; Analyzing instrument: SBE conductivity sensor, SN: 2706, calibration: 13-Nov-2012; Detailed sampling and analyzing information: CTD data were compared to Meas_Salinity and corrected by +0.018. After correction the mean difference between CTD and measured salinity is -0.003±0.011 (n=71).; Uncertainty: 0.005; Quality flag convention: WOCE/GLODAP (2 Acceptable, 3 Questionable, 4 Known bad, 9 No data); Researcher name: C. Lo Monaco; Researcher institution: LOCEAN-IPSL, Sorbonne Universite.
- Parameter or Variable: Measured Salinity; Abbreviation: Meas_Salinity; Unit: psu; Observation type: Profile; In-situ / Manipulation / Response variable: IN-SITUOBSERVATION; Measured or calculated: MEASURED; Sampling instrument: Niskin bottles; Analyzing instrument: Guidline salinometer; Detailed sampling and analyzing information: Sea water was collected in 150 ml salinity bottles provided by Ocean Scientific International Ltd. Samples were measured at LOCEAN (within 6 months). IAPSO standards were used (provided by Ocean Scientific International Ltd).; Uncertainty: 0.005; Quality flag convention: WOCE/GLODAP (2 Acceptable, 3 Questionable, 4 Known bad, 9 No data); Researcher name: C. Lo Monaco; Researcher institution: LOCEAN-IPSL, Sorbonne Universite.
- Parameter or Variable: Dissolved oxygen from SBE sensor, uncorrected data; Abbreviation: CTD_OXY; Unit: µmol/kg; Observation type: Profile; In-situ / Manipulation / Response variable: IN-SITUOBSERVATION; Measured or calculated: MEASURED; Sampling instrument: CTD Sea-Bird SBE 911plus; Analyzing instrument: SBE Oxygen sensor, SN: 0359, calibration: 12-Nov-2012; Uncertainty: Uncorrected data; Quality flag convention: WOCE/GLODAP (2 Acceptable, 3 Questionable, 4 Known bad, 9 No data); Researcher name: C. Lo Monaco; Researcher institution: LOCEAN-IPSL, Sorbonne Universite.
- Parameter or Variable: Dissolved oxygen from SBE sensor, corrected data; Abbreviation: CTD_OXY_CAL; Unit: µmol/kg; Observation type: Profile; In-situ / Manipulation / Response variable: IN-SITUOBSERVATION; Measured or calculated: MEASURED; Sampling instrument: CTD Sea-Bird SBE 911plus; Analyzing instrument: SBE Oxygen sensor, SN: 0359, calibration: 12-Nov-2012; Detailed sampling and analyzing information: Oxygen sensor data were corrected with respect to bottle data (Winkler titration) using linear regressions determined for each station. The calibrated oxygen data flagged good agree with the measured oxygen data to within +/-3 µmol/kg (the mean difference is -0.1±1.5, n=132).; Uncertainty: 1 µmol/kg; Quality flag convention: WOCE/GLODAP (2 Acceptable, 3 Questionable, 4 Known bad, 9 No data); Researcher name: C. Lo Monaco; Researcher institution: LOCEAN-IPSL, Sorbonne Universite.
- Parameter or Variable: Dissolved oxygen (Winkler); Abbreviation: Meas_Oxygen; Unit: µmol/kg; Observation type: Profile; In-situ / Manipulation / Response variable: IN-SITUOBSERVATION; Measured or calculated: MEASURED; Sampling instrument: Niskin bottles; Analyzing instrument: Metrohm titrator; Detailed sampling and analyzing information: Sea water was collected in calibrated glass bottles (150-200 ml), stored in the dark, and measured within 3 days. Dissolved oxygen was measured onboard following Winkler’s method with photometric detection (Williams and Jenkinson,1982). Iodate standard solutions provided by Ocean Scientific International Ltd were used as a reference.; Replicate information: Deep replicate samples were collected from two different Niskin bottles (1200m or bottom). The mean difference between two deep replicates was 1.0±0.7 µmol/kg (n=5).; Uncertainty: 1 µmol/kg; Quality flag convention: WOCE/GLODAP (2 Acceptable, 3 Questionable, 4 Known bad, 9 No data); Method reference: Williams, P. J. LeB, and N. W. Jenkinson, 1982. A transportable microprocessor-controlled precise Winkler titration suitable for field station and shipboard use. Limnol. Oceanogr,. 27, 576-585.; Researcher name: C. Lo Monaco; Researcher institution: LOCEAN-IPSL, Sorbonne Universite.
- Parameter or Variable: Silicic acid; Abbreviation: Silicate; Unit: µmol/kg; Observation type: Profile; In-situ / Manipulation / Response variable: IN-SITUOBSERVATION; Measured or calculated: MEASURED; Sampling instrument: Niskin bottles; Analyzing instrument: SEAL Analytical AA3; Detailed sampling and analyzing information: Sea water samples were immediately filtered (0.2 µm) in 20 ml plastic bottles, poisoned with 100 µL of HgCl2 (saturated solution). Samples were measured at LOCEAN following the segmented flow method described by Coverly et al. (2009), except for stations A3 and E measured at LOMIC (Banyuls, France) following the same protocole.; Quality flag convention: WOCE/GLODAP (2 Acceptable, 3 Questionable, 4 Known bad, 9 No data); Method reference: Coverly, S. C., Aminot, A., and R. Kérouel, 2009. Nutrients in Seawater Using Segmented Flow Analysis, In Practical Guidelines for the Analysis of Seawater, Ed. Oliver Wurl, CRC Press, June 2009, doi: 10.1201/9781420073072.ch8.; Researcher name: C. Lo Monaco; Researcher institution: LOCEAN-IPSL, Sorbonne Universite.
- Parameter or Variable: Nitrate + Nitrite; Abbreviation: NOx; Unit: µmol/kg; Observation type: Profile; In-situ / Manipulation / Response variable: IN-SITUOBSERVATION; Measured or calculated: MEASURED; Sampling instrument: Niskin bottles; Analyzing instrument: SEAL Analytical AA3; Detailed sampling and analyzing information: Sea water samples were immediately filtered (0.2 µm) in 20 ml plastic bottles, poisoned with 100 µL of HgCl2 (saturated solution). Samples were measured at LOCEAN following the segmented flow method described by Coverly et al. (2009), except for stations A3 and E measured at LOMIC (Banyuls, France) following the same protocole.; Quality flag convention: WOCE/GLODAP (2 Acceptable, 3 Questionable, 4 Known bad, 9 No data); Method reference: Coverly, S. C., Aminot, A., and R. Kérouel, 2009. Nutrients in Seawater Using Segmented Flow Analysis, In Practical Guidelines for the Analysis of Seawater, Ed. Oliver Wurl, CRC Press, June 2009, doi: 10.1201/9781420073072.ch8.; Researcher name: C. Lo Monaco; Researcher institution: LOCEAN-IPSL, Sorbonne Universite.
- Parameter or Variable: Nitrite; Abbreviation: Nitrite; Unit: µmol/kg; Observation type: Profile; In-situ / Manipulation / Response variable: IN-SITUOBSERVATION; Measured or calculated: MEASURED; Sampling instrument: Niskin bottles; Analyzing instrument: SEAL Analytical AA3; Detailed sampling and analyzing information: Sea water samples were immediately filtered (0.2 µm) in 20 ml plastic bottles, poisoned with 100 µL of HgCl2 (saturated solution) and stored in the fridge. Samples were measured at LOCEAN following the segmented flow method described by Coverly et al. (2009), except for stations A3 and E measured at LOMIC (Banyuls, France) following the same protocole.; Quality flag convention: WOCE/GLODAP (2 Acceptable, 3 Questionable, 4 Known bad, 9 No data); Method reference: Coverly, S. C., Aminot, A., and R. Kérouel, 2009. Nutrients in Seawater Using Segmented Flow Analysis, In Practical Guidelines for the Analysis of Seawater, Ed. Oliver Wurl, CRC Press, June 2009, doi: 10.1201/9781420073072.ch8.; Researcher name: C. Lo Monaco; Researcher institution: LOCEAN-IPSL, Sorbonne Universite.
- Parameter or Variable: Phosphate; Abbreviation: Phosphate; Unit: µmol/kg; Observation type: Profile; In-situ / Manipulation / Response variable: IN-SITUOBSERVATION; Measured or calculated: MEASURED; Sampling instrument: Niskin bottles; Analyzing instrument: Spectrophotometer; Detailed sampling and analyzing information: Sea water samples were immediately filtered (0.2 µm) in 20 ml plastic bottles, poisoned with 100 µL of HgCl2 (saturated solution) and stored in the fridge. Samples were measured at LOMIC (Banyuls, France) following the segmented flow method described by Coverly et al. (2009).; Quality flag convention: WOCE/GLODAP (2 Acceptable, 3 Questionable, 4 Known bad, 9 No data); Method reference: Coverly, S. C., Aminot, A., and R. Kérouel, 2009. Nutrients in Seawater Using Segmented Flow Analysis, In Practical Guidelines for the Analysis of Seawater, Ed. Oliver Wurl, CRC Press, June 2009, doi: 10.1201/9781420073072.ch8.; Researcher name: C. Lo Monaco; Researcher institution: LOCEAN-IPSL, Sorbonne Universite.
- Parameter or Variable: Chlorophyll-a; Abbreviation: Chla; Unit: µg/l; Observation type: Profile; In-situ / Manipulation / Response variable: IN-SITUOBSERVATION; Measured or calculated: MEASURED; Sampling instrument: Niskin bottles; Analyzing instrument: Hitaschi F-4500 spectrofluorometer; Detailed sampling and analyzing information: Sea water samples were collected in polycarbonate bottles (between 1L and 2L depending on fluorecence data), and immediately filtered on 25mm GF/F Whatman filters (pressure< 200 mbar). Filters were stored at -80°C. Fluorescence was measured at LOCEAN, using a Hitaschi F-4500 spectrofluorometer, after extraction of the filters in 90% acetone, following the method described by Neveux and Lantoine (1993, DSR); Uncertainty: 5% (replicate samples analysis); Quality flag convention: WOCE/GLODAP (2 Acceptable, 3 Questionable, 4 Known bad, 9 No data); Method reference: Neveux, J., and Lantoine, F.: Spectrofluorometric assay of chlorophylls and phaeopigments using the least squares approximation technique, Deep-Sea Res. I, 40(9), 1747-1765, 1993.; Researcher name: C. Ridame; Researcher institution: LOCEAN-IPSL, Sorbonne Universite .
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